β-谷甾醇酯化反应过程中的反相高效液相色谱分析

应用反相高效液相色谱法对β-谷甾醇与琥珀酸酐酯化反应过程中的分析测定进行了研究. 色谱测定采用Hypersil ODS反相柱(4.6 mm×150 mm,5 μm), 流动相为色谱纯甲醇,流速为0.7 mL*min-1, 检测波长为210 nm, 恒溶剂洗脱. 实验结果表明,β-谷甾醇及其酯化产物β-谷甾醇琥珀酸单酯在色谱上均有响应并达到基线分离;采用面积归一法能够快速测定β-谷甾醇酯化反应过程中各组分的含量和β-谷甾醇酯化反应的摩尔转化率.     

桉木抽出物的主要化学组成及结构类型的初步研究

采用化学分析和光谱和分析相结合的方法，对不同树种和树龄桉木抽出物的主要化学组成及结构类型进行初步研究，结果表明：桉木出物主要集中于心材；树龄越大，抽出物越多；幼龄材的抽出物较少，适宜于制浆造纸桉木的颜色主要是由多酚类化合物引起的。存放过久的桉木中的抽出物大变成黄粉，既不溶于水，也不溶于丙酮，只溶于稀碱或亚硫酸钠。在制浆前采用稀碱或亚硫酸钠预处理桉木是必要的。桉木多酚类化合物以水单宁为主，属鞣花酚类     

以微核测定研究湘江底泥重金属—铜的含量对鱼类血细胞的毒性影响

本文以微核测定研究湘江底泥铜含量对鱼类血细胞的毒性作用。结果表明用铜处理3个月的第四组鳙鱼的总微核率与对照组有显著差别,即第四组鳙鱼血细胞核染色体有显著的损伤。     

构造分布条件矩的收敛速度

给出F属于吸引场Φα和Ψα时X*～F*(x)=1-xp(1-F(x))的条件矩E((X*-t)q|X*>t)的收敛速度.     

Leptomeningeal metastasis from central nervous system tumors: A study of classification and stage in the spinal canal of 58 patients

Leptomeningeal metastasis (LM) is caused by the spread of malignant tumor cells into the subarachnoid space.However,classification and staging of LM in the spinal canal is rare in the literature.The authors reviewed the records of 58 Chinese patients with LM for clinical features,neuroimaging,and treatments.Gadolinium-enhanced magnetic resonance imaging (MRI) of brain and spinal cord were performed in all patients.Removal of intracranial tumors was performed in all patients and diagnoses were confirmed by histology.The study group consisted of 58 patients,with 29 cases presenting with intraspinal symptoms.Of the 58,8 patients underwent intraspinal tumor removal,8 received radiotherapy alone,9 received chemotherapy alone,and 34 patients received combined radiochemotherapy.We classified LM into 3 types:type L or leptomeninges LM,is subdivided into 2 subtypes (subtype LI and LII (a,b)),type N or nerve root LM is subdivided into 2 subtypes (subtype NI and NII (a,b)),and type M or mixed-type LM.We also divided LM into stages of I-IV according to the symptoms and the volume of the tumor based on spinal axial MRI.Type LI LM often occurs in patients with intracranial and intraspinal tumors found simultaneously.Patients who receive surgery for intracranial tumors may present with type N LM.Surgery is suitable for patients with NI LM and LIIb LM in stages III-IV,presenting with severe spinal symptoms.The prognosis is better for type N LM than type L LM.     

Present status and future prospect of design of Pt–cerium oxide electrodes for fuel cell applications

In the research field of proton exchange membrane fuel cells, the design of electrocatalytic activities on Pt-oxide promoter in the anode side has attracted attention for improvement of CO tolerance of Pt in anode side and a lowering of large over-potential loss of the oxygen reduction reaction on the cathode in the fuel cells. In the Pt-oxide promoter series, Pt–CeOx/C is one of the unique systems. It is because the unique behavior of CeOx such as electrochemical redox reaction between Ce3t and Ce4t in the anodic and cathodic reactions of fuel cell is observed. The present short review gives an overview of the recent works for improvement of the CO tolerance of Pt in the Pt–CeOx/C anodes and enhancement of the oxygen reduction reaction activity on Pt in the Pt–CeOx/C cathodes for fuel cell application. To show the design paradigm for fabrication of high quality Pt–CeOx/C electrodes, the authors re-introduced parts of our research results to highlight the important role of interface structure of Pt–CeOx based on the ultimate analysis results. The usefulness of the combined approach of microanalysis and the processing route design is presented.     

Origin软件在光学实验数据处理中的应用

在光学实验中利用Origin软件对实验数据进行线性和非线性拟合与处理,对比常规方法得到的实验结果,通过分析可以得知使用该软件具有快捷、直观、准确的特点,有效地避免了手工处理所带来的误差.利用Origin软件的统计功能,辅之以统计学的原理,可提高对大量数据的分析能力和异常数据的甄别能力.结果表明:Origin软件适合在光学实验使用,为实验数据的处理开辟了一条新的途径.     

苏北地区的空间梯度分析

从经济联系强度的角度出发,运用城市中心性、经济联系总强度与隶属度模型,探讨苏北地区的空间范围．根据熵值法确定徐州为苏北的中心城市,以徐州为中心划分出核心圈层与外围圈层;根据经济联系强度、隶属度等对苏北地区28个县市进行了空间重构,初步将苏北地区划分为3大区域,并结合相关分形理论对其进行验证．结果表明,徐州城区、丰县、沛县、睢宁、新沂、邳州、宿迁城区、连云港城区、沭阳、东海、泗阳、泗洪、赣榆、灌云14县市构成了以徐州城区为中心的徐宿连区;淮安城区、灌南、涟水、盱眙、洪泽、金湖、响水7县市构成了以淮安城区为中心的淮安区;盐城城区、射阳、建湖、阜宁、东台、滨海、大丰7县市构成了以盐城城区为中心的盐城区．     

保险粉(Na_2S_2O_4·2H_2O)在废漂定液的提银及再生中的应用

叙述了保险粉对废漂定液的提银及再生原理、操作方法;指出再生漂定液返回彩扩店后的冲印效果和新鲜药液一样。     

虚拟现实技术在电子设计与测试中的应用

简介了一种虚拟现实技术在电子设计与测试中的应用实例,简述了以计算机为平台,用“虚拟仪器、虚拟元器件”实现电子设计与测试自动化的操作环境与操作过程,并给出了仿真实验结果图３,参３