五倍子单宁酸中没食子酸的去除及其含量测定

单宁酸是五倍子提取物中的主要成分,被广泛应用于医药、食品、日化等方面.但由常规方法制备的单宁酸中常含有没食子酸杂质,影响产品的品质和应用.为了提高五倍子单宁酸提取物的纯度,以单宁酸为原料、没食子酸含量为考察指标,采用简单易得的无机碱(碳酸氢钠)选择性去除没食子酸,对单宁酸的提纯工艺进行优化.对优化后的工艺进行放大实验,...     

Pt-SnO2/C电催化剂异型直接乙醇燃料电池的性能

以掺杂石墨粉的中间相碳微球(MCMB/G)烧结管为阴极支撑体,采用浸涂工艺分别制备了扩散层和催化层,通过在其外表面包裹Nafion 117膜制得管状异型阴极并组装成异型直接乙醇燃料电池,采用水热乙二醇制备了适用于直接乙醇燃料电池的阳极电催化剂,并通过XRD,TEM和EDS等技术对其进行了表征.采用线性循环伏安曲线、交流阻抗等测试手段,对Pt-SnO2/C电催化剂异型直接乙醇燃料电池进行了性能测试,并考察了温度、氧气流量等对电池极化性能的影响.结果表明:异型电池阻抗大于传统的平板电池,但其活化后电池阻抗明显下降;较高的氧气流量和较高的工作温度有利于提高电池性能;60℃条件下,Pt-SnO2/C电催化剂异型直接乙醇燃料电池功率密度达到8.5 mW·cm-2.     

Longitudinal surface cracks of thin slabs

Based on the production practice of medium carbon thin slabs in the CSP plant, the reasons and influencing factors for the formation of longitudinal cracks were investigated, and some industrial measures were taken to eliminate the cracks. The results show that the efficient solutions to reduce longitudinal cracks are improving the performance of the mold powder, stabilizing the mold heat flux, and maintaining a proper taper of the mold during casting. Proper pouring temperature and secondary cooling also play important roles in preventing longitudinal surface cracks.     

原位VC颗粒弥散强化304不锈钢的组织与性能

为了改善奥氏体不锈钢的力学性能,采用原位铸造法制备出VC颗粒弥散强化304不锈钢基材料,并研究了VC颗粒的加入对304不锈钢的显微组织和性能的影响.研究结果表明,原位VC颗粒在铸态组织中呈现2种形貌:沿晶界呈长条状分布的颗粒和在晶内均匀分布的亚微米尺寸的等轴状颗粒.TEM结果表明,在热处理过程中有纳米尺寸的VC颗粒析出.原位合成VC颗粒的加入,使304不锈钢的室温及高温强度均得到显著提高,但在一定程度上降低了其塑性和冲击韧性.与母合金304不锈钢相比,采用原位合成工艺引入VC颗粒后,在温度为650℃、应力为100 MPa的条件下,强化钢的抗蠕变性能得到大幅度改善.     

Fluid/melt inclusions in Cenozoic mantle xenoliths from Linqu,Shandong Province,eastern China: Implications for asthenosphere-lithosphere interactions

Fluid and melt inclusions in mantle xenoliths are thought as direct samples to study mantle liquids. Here we apply Raman mi- crospectroscopy and microthermometry to fluid/melt inclusions in lherzolite xenoliths in Qiaoshan basalts, a Miocene volcano in Linqu, Shandong Province, eastern China. These inclusions include (1) early CO2 fluid inclusions, (2) early carbonate melt inclu-sions, (3) late CO2 fluid inclusions, and (4) late silicate melt inclusions. Among the early CO2 fluid inclusions, most consist of...     

不同结构竹浆纱线的应力松弛性能研究

以2个Maxwell并联的四元件模型为基础,利用波尔兹曼叠加原理建立纱线应力松弛变化过程的理论方程,并分别对竹浆紧密纺、赛络纺和喷气涡流纺(MVS)纱线进行应力松弛实验.基于应力松弛理论模型,利用非线性回归拟合法求得纱线应力松弛的回归方程,分析了3种不同结构竹浆纱线的应力松弛机制.实验结果表明,理论值与实测值具有良好的相关性,所用模型可以预测不同结构竹浆纱线的松弛性能.在消耗各纱线断裂伸长30%形变的情况下,竹浆紧密纱应力松弛现象最严重,赛络纱次之,喷气涡流纱最小.     

复合固体超强酸催化剂SO2-4/ZrO2-Al2O3-WO3的制备及表征

采用沉淀浸渍法制备复合固体超强酸催化剂SO2-4/ZrO2-Al2O3-WO3,运用Hammett指示剂法、FT-IR、XRD、SEM、TGA和BET等对相应的催化剂进行表征,并研究了陈化温度、焙烧温度、浸渍液浓度等制备条件以及Al2O3、WO3等不同金属氧化物的引入对SO2-4/ZrO2的影响.结果表明,低温陈化的试样具有较强的酸性和催化活性,添加Al2O3可增大催化剂的比表面积和酸度值,引入WO3有利于酸性的增强.复合固体催化剂SO2-4/ZrO2-Al2O3-WO3 的最佳制备方案是, 陈化温度为-10 ℃、m(Al2O3)/m(ZrO2)为3.5、m(WO3)/m(ZrO2)为1、浸渍液(NH4)2SO4浓度为1.0 mol·L-1、焙烧温度为500 ℃.该催化剂用于乙酸正丁酯的合成,其酯化率达到98.5%.     

Multi-pollutants simultaneous removal from flue gas

The multi-stage humidifier semi-dry flue gas cleaning technology, the CRS plasma flue gas cleaning technology and oxidative additive flue gas cleaning technology were investigated for multi-pollutants removal. The semi-dry flue gas cleaning technology using multistage humidifier and additive can improve oxidation and absorption, and it can achieve high multi-pollutants removal efficiency. The CRS discharge can produce many OH radicals that promote NO oxidation. Combining NaOH absorption can achieve high deSO2 and deNOx efficiencies. It is very fit of the reconstruction of primary wet flue gas desulfurization (WFGD). In addition, Using NaClO2 as additive in the absorbent of WFGD can obtain very high removal efficiency of SO2 and NOx.     

“校中厂,厂中校”校企合作人才培养模式的探索和实践

我国高等职业技术教育以服务社会主义现代化建设和经济社会发展为目标,着力培养适应经济社会发展需要的高素质技能型专门人才。在高职院校的办学中,校企合作、工学结合是促进学校专业建设、课程建设、师资队伍建设、实训基地建设和提高人才培养质量的有效途径。本文就黄冈职业技术学院"校中厂,厂中校"校企合作的人才培养模式,从含义、措施、问题和人才培养四个方面来加以阐述和交流。