The v-v energy transfer of highly vibrationally excited states (I)

The relaxation of the highly vibrationally excited CO (v = 1–8) by CO₂ is studied by timeresolved Fourier transform infrared emission spectroscopy (TR FTIR). 193 nm laser photolysis of the mixture of CHBr₃ with O₂ generates the highly vibrationally excited CO(v) molecules. TR FTIR records the intense infrared emission of CO(v→v-1). The vibrational populations of each level of CO(v) have been determined by the method of spectral simulation. Based on the evolution of the time resolved populations and the differential method, 8 energy transfer rate constants of CO(v = 1–8) to CO₂ molecules areobtained: (5.7±0.1), (5.9±0.1), (5.2±0.2), (3.4±0.2), (2.4±0.3), (2.2±0.4), (2.0±0.4) and (1.8±0.6) (10¹⁴ cm³ · molecule⁻¹ · s⁻¹), respectively. A two-channel energy transfer model can explain the feature of the quenching of CO(v) by CO². For the lower vibrational states of CO, the vibrational energy transfers preferentially to the u³ mode of CO² For the higher levels, the major quenching channel changes to the vibrational energy exchange between CO(v→v-1) and the u¹ mode of CO².     

Almost periodic solution to singular systems

The problems about the almost periodic solution to singular systems are studied. The criterion that the singular systems have almost periodic solutions is obtained. At the same time, the applied example is given.     

单向耦合映象格子的时空混沌同步

用主动－被动分拆方法实现了单向耦合映象格子系统的时空混沌同步,从理论上给出步范围,并从数值实验上得到验证。该法具有高度保密性,且信号可以完全恢复,特别适用于混沌保密通讯 。     

高效液相色谱法测定血伤宁中的乌头碱含量

用ＨＰＬＣ法测定血伤宁中乌头碱的含量．在ＯＤＳ柱上,以甲醇（Ｖ）∶水（Ｖ）∶三乙胺（Ｖ）（７０∶３０∶０．１）作流动相,流速１．０ｍＬ／ｍｉｎ,检测波长为２４０ｎｍ,平均回收率９０．６０％,变异系数１．２５％．     

Neuropeptide Y receptors in a protozoaStylonychia mytilus

Radio ligand binding assays(RLBA) were used to study neuropeptide Y (NPY) receptors in a protozoa Stylonychia mytilus. The experimental results showed that 2-3×10+3/mL Stylonychia cells incubated in Pringsheim solution which contained 3H-NPY could specifically bind 3H-NPY and concomitantly present saturable characteristic. This suggested that Stylonychia possessed some specific binding sites for NPY. Scatchard transformations of binding assay for the NPY receptors at 25℃ are compatible with the specific activity of 42.47 fmol/10+3 cells and the binding equilibrium constant of 0.113 nmol/L. The data of 125I-NPY binding assay to the membrane protein extract of Stylonychia indicated that there was a significant difference between the amount of total bound and nonspecific bound of 125I-NPY. This result indicated that NPY receptors were probably localized mainly on the cell membrane.     

CAD系统中面向对象用户界面的设计与研究

介绍铁路站场ＣＡＤ系统中面向对象用户界面的设计与研究,该系统用户界面的设计充分分考虑了铁路站场ＣＡＤ系统的特点和工程应用,采用面向对象的方法与技术,实现了一个高度图形化和交互式,适用于铁路站场设计工作需要的图用户界面。     

一维抛物型偏微分方程 Padé 逼近的并行算法

一维抛物型偏微分方程可以用精细积分方法精确求解．当精细积分中的矩阵指数函数用它的Ｐａｄé逼近格式来代替时,可以得到一系列由简到繁,精度由低到高的差分格式,因而便于根据实际计算的需要进行选取．Ｐａｄé逼近格式的求解主要包括矩阵运算和线性方程组的求解．利用Ｐａｄé逼近格式对应的方程组系数矩阵为带状矩阵的特点,把原来在整个区域上求解的问题转化为分区域求解,从而实现了Ｐａｄé逼近的并行算法．算例的结果表明该方法具有较高的并行性和计算效率     

补偿扰动的PWM逆变器无差拍控制

提出了两种ＰＷＭ逆变器的改进无差拍控制算法．这两种算法根据ＰＷＭ逆变器的状态方程,分别采用直接补偿扰动和最优预见控制技术,利用未来信息决定当前的控制输入．使用ＭＡＴＬＡＢ软件对这两种算法进行了仿真．结果表明,当存在随机扰动及电路参数变化时,所提出的两种算法的控制效果均比不考虑补偿扰动的无差拍算法有较大改善．因此,该两种控制算法能够有效地抑制电路参数变化引起的或来自外部的扰动,使输出电压能很好地跟踪参考电压,控制响应快,鲁棒性好．     

多客户VOD视频服务器的研究

描述了基于通用工作站的ＶＯＤ（ＶｉｄｅｏＯｎＤｅｍａｎｄ）视频服务器支持多客户并发访问的原理,提出了一个利用时间片轮询的调度算法来给多客户提供视频服务,并给出了一个基于客户／服务器结构的ＶＯＤ视频服务器的结构及其初步实现．实验结果证明了调度算法的有效性和正确性．     

TS分子筛的催化氧化性能研究：Ⅲ.苯酚氧化制苯二酚

研究了自合成的钛硅分子筛（ＴＳ－１）对Ｈ２Ｏ２氧化苯酚制苯二酚反应的催化活性。对反应的温度、时间、催化剂用量、酚：Ｈ２Ｏ２等因素进行了考察：在催化剂用量为苯酚的１０％、酚：Ｈ２Ｏ２（ｍｏｌ）为３：１时,经５７℃／６ｈ反应,Ｈ２Ｏ２的转化率和对产物苯二酚的利用率可达９０％和８０％,还观察到,分子筛的晶粒大小对苯酚的氧化活性影响较大,大晶粒催化剂的内表面利用率较低,从而影响催化活性。