La掺杂对SrTiO_3纳米颗粒光催化性能的影响

采用高温固相反应法,向SrTiO_3中掺杂不同含量La制备光催化剂,通过XRD、SEM、UV-Vis等手段对其结构和形貌进行表征,并以罗丹明B(RhB)为模拟污染物,研究掺杂不同含量La所制催化剂对RhB的光催化降解能力的影响,从而评价所制催化剂的光催化性能。结果表明,随着掺La含量的增加,所制催化剂的晶体结构从SrTiO_3的立方晶系逐步向La_2Ti_2O_3的单斜晶系转变;La掺杂使得所制催化剂的禁带宽度减小、对紫外光的吸收阈值增大,使其光催化性能得到显著提升;掺La含量越高,所制催化剂的光催化性能越好。     

金属露天矿帮坡角变化对最终境界影响

基于正锥排除法基本原理优化南芬露天矿最终境界,研究上盘帮坡角变化对最终境界开采形态、矿岩量等影响.根据南芬露天矿不同时期采场生产现状,设置相关技术经济参数,对矿山进行初始境界优化;按照0.5°步长逐步提升上盘帮坡角,优化不同上盘帮坡角条件下的最佳境界.研究表明,随着帮坡角变陡,最终境界地表范围逐渐缩小,底部尺寸变大或者向下延伸;不同帮坡角加陡方案得到的最终境界,矿岩量可能增大或者减小,总成本也可能增加,但利润值增大.     

C3N4/ZnO复合材料可见光下的甲醛光电气敏性能

以水热法合成的ZnO纳米棒花为载体,将C_3N_4定量负载在其表面,制备C_3N_4/ZnO复合材料.由于C_3N_4与ZnO的能级匹配,可有效促进其光生电荷的分离,降低光生电荷复合率,显著提高载流子浓度,使其光电流明显增加.C_3N_4与ZnO质量比为2%的样品(2%C_3N_4/ZnO)性能最佳,其光电流在370 nm处可达120μA,为纯ZnO的2.4倍.在室温可见光下,2%C_3N_4/ZnO样品对HCHO的光电气敏响应值可达122%,比纯ZnO高4倍左右.结果表明,适量C_3N_4的负载有效延长了光生电荷的寿命,使ZnO材料在可见光区对HCHO气体表现出高效的光电气敏性能.     

剩余类环上多项式的同余性质

设Z/p~nZ是模p~n剩余类环.本文证明了U={f(x)∈Z/p~nZ[x]|f(a)≡0(modp~n),■a∈Z}是自由生成的Z/p~nZ-模,给出了它的一组基,还证明了商环(Z/p~nZ[x])/U是有限环,并通过这组基确定了商环(Z/p~nZ[x])/U中的元素个数.     

Multifunctional artificial nacre via biomimetic matrix-directed mineralization

Natural nacre, one of the most studied biological structural materials with delicate hierarchical structures and extraordinary performance, has inspired the design and fabrication of artificial structural ceramics with high fracture toughness. However, to meet the diverse requirements of different applications, future structural materials must be multifunctional with superior mechanical properties, such as strength, hardness, and toughness. Herein, based on the matrix-directed mineralization method for producing biomimetic structural materials, we introduce nanoparticles with different inherent functions into the platelets of artificial nacre via the co-mineralization of aragonite and the nanoparticles. Besides their enhanced mechanical properties, the obtained artificial nacre materials also exhibit different functions depending on the type of the nanoparticles. To extend the versatility of this strategy, the effects of nanoparticles of different sizes and zeta potentials on mineralization are also analyzed. This universal strategy can be applied to the fabrication of other types of functionalized biomimetic structural ceramics that have potential applications in various fields, such as biomedical science.     

松塔水电站及供水发电洞工程地质条件分析与评价

在工程地质资料的基础上,对山西省松塔水电站及供水发电洞工程地质条件进行了分析和评价。     

含糖聚合物的研究现状与进展

综述了含糖乙烯基单体的合成、含糖聚合物的"活性"/可控自由聚合以及含糖聚合物在生物医药领域中的应用.含糖聚合物因其优良的生物相容性、亲水性和靶向性等功能,赋予含糖聚合物作为智能人造材料尤其在生物和生物医药等领域具有各种特殊用途,今后含糖聚合物的研究将集中于含糖聚合物的结构控制以及聚合物的实际应用性能的开发上.     

Exact inference for two exponential populations with competing risks data

In a reliability comparative test, the joint censoring model is usually adopted to evaluate the performances of units with the same facility. However, most researchers ignore the pos- sibility that there is more than one factor for the failure when a test unit fails. To solve this problem, we consider a joint Type-II hybrid censoring model for the analysis of exponential competing failure data. Based on the maximum likelihood theory, we compute the maximum likelihood estimators （MLEs） of parameters and then obtain the condition ensuring MLEs existence for every unknown parameter. Then we derive the conditional exact distributions and corresponding moment properties for parameters by the moment generating function （MGF）. A Monte-Carlo simulation is conducted to compare the performances of different ways. And finally, we conduct a numerical example to illustrate the proposed method.     

循环网络模拟技术在土石方工程中的应用

土石方工程由于施工过程的复杂及受到众多随机因素的影响,很难用人工方法精确计算各道路的行车及排队情况,确定各道路的等级以及施工机械设备的数量。采用循环网络模拟技术,用挖、装、运、卸等仿真节点来模拟实际施工的相应过程,建立能反映土石方实际开挖过程的仿真模型。仿真得出的一系列施工参数为辅助管理人员做出决策提供参考依据。某工程中的成功应用表明,此方法快捷、便利,值得深入研究并推广应用。