Photocatalytic property of TiO2 sensitized by different crystal phase CdS

TiO2 samples sensitized by different crystal phase CdS(CT) are synthesized by hydrothermal process at different reaction temperature. The samples are characterized by X-ray diffraction(XRD), transmission electron microscopy(TEM), and UV-Vis diffuse reflectance(UV-Vis). The XRD result reveals that the crystal phase of CdS is transformed from cubic phase to hexagonal phase with the increase of hydrothermal reaction temperature(120-160 ℃). The absorption edge of CT is extended from 498 nm to 546 nm. The photocatalytic degradation of rhodamin B(RhB) in aqueous solution is used to evaluate the photocatalytic activity of CT. With the increase of the preparation temperature, the photocatalytic activity of CT becomes stronger. The degradation rate of RhB by CdS/TiO2 at 160 ℃(CT-160 ℃)reaches 78%.     

基于热传导理论的钢管混凝土拱肋界面脱空的定性识别

针对钢管混凝土拱肋的界面脱空损伤对拱桥承载力的影响,以及现有检测方法的不足,提出了一种新的钢管混凝土界面脱空的无损检测方法。该方法以外壁分布式测温为基础,利用钢管、混凝土、空气三种材料的温度特性的不同确定脱空是否存在及脱空的位置．通过数值模拟与试验结果的互相对比,验证该方法的有效性与可行性．     

Promotion of Hras-induced squamous carcinomas by a polymorphic variant of the Patched gene in FVB mice

Mice of the C57BL/6 strain are resistant to the development of skin squamous carcinomas (SCCs) induced by an activated Ras oncogene, whereas FVB/N mice are highly susceptible. The genetic basis of this difference in phenotype is unknown. Here we show that susceptibility to SCC is under the control of a carboxy-terminal polymorphism in the mouse Ptch gene. F1 hybrids between C57BL/6 and FVB/N strains ((B6FVB)F1) are resistant to Ras-induced SCCs, but resistance can be overcome either by elimination of the C57BL/6 Ptch allele (Ptch(B6)) or by overexpression of the FVB/N Ptch allele (Ptch(FVB)) in the epidermis of K5Hras-transgenic (B6FVB)F1 hybrid mice. The human Patched (PTCH) gene is a classical tumour suppressor gene for basal cell carcinomas and medulloblastomas, the loss of which causes increased signalling through the Sonic Hedgehog (SHH) pathway. SCCs that develop in PtchB6+/- mice do not lose the wild-type Ptch gene or show evidence of increased SHH signalling. Although Ptch(FVB) overexpression can promote SCC formation, continued expression is not required for tumour maintenance, suggesting a role at an early stage of tumour cell lineage commitment. The Ptch polymorphism affects Hras-induced apoptosis, and binding to Tid1, the mouse homologue of the Drosophila l(2)tid tumour suppressor gene. We propose that Ptch occupies a critical niche in determining basal or squamous cell lineage, and that both tumour types can arise from the same target cell depending on carcinogen exposure and host genetic background.     

决定晶体硅太阳电池工作状态的独立参量的确定

从晶体硅太阳电池功率全微分方程出发,结合开路电压和功率随温度、日照变化的实验事实,研究 影响晶体硅太阳电池工作状态的各参量的独立性。从数学上确定出其独立变量为日照强度、电池温度和负载, 并得出了串联内阻是温度的函数的结论。串联内阻的实验数据验证了理论分析结果的正确性。     

结合过完备字典与PCA的小样本语音情感识别方法

针对稀疏表示识别方法需要大量样本训练过完备字典且特征冗余度较高的问题,提出了结合过完备字典学习与PCA降维的小样本语音情感识别算法.该方法首先用PCA降维方法将特征降维,再将处理后的特征用于过完备字典训练与稀疏表示识别方法,从而给出了语音情感特征的稀疏表示方法,并确定了新算法的具体步骤.为验证其有效性,在同等特征维数下,将方法与BP、SVM进行比较,并对比、分析语音情感特征稀疏化前后对语音情感识别率、时间效率以及空间效率的影响.试验结果表明,所提出方法的识别率比SVM与BP高;与采用稀疏化前的特征相比,稀疏化后的特征向量更便于处理,平均识别率提高约15%,时间效率提高近原来的1/2,空间效率提升近原来的1/3.     

分散式钢棒混凝土柱非线性数值模拟研究

 针对实腹式型钢混凝土柱施工难度大、造价高的特点,文中基于核心区钢骨含钢量相同的原则给出了一种低工程造价、低施工难度的分散式钢棒核心钢骨混凝土柱,初步试验已验证两种柱的力学性能相近,该论文则是更深入地研究这种新型截面柱的抗震性能。通过考虑材料本构关系的非线性以及P-Δ效应,应用有限元软件（ABAQUS）建立分散式钢棒核心钢骨混凝土柱的非线性有限元模型,开展轴压比、含钢率、混凝土强度以及核心钢棒屈服强度等对分散式钢棒核心钢骨混凝土柱荷载位移曲线、水平极限承载力及延性系数影响的研究,结果表明：分散式钢棒核心钢骨混凝土柱水平极限承载力受轴压比和混凝土强度的影响明显,而含钢率和核心钢棒屈服强度对水平极限承载力影响很小;延性系数是一个比较敏感的指标,受各种因素的影响均较明显。     

高校开设少数民族体育项目的可行性研究

文章通过文献资料法、逻辑判断法、归纳总结法、数理统计法,从少数民族体育与高校体育的互补性来阐述高校开设少数民族体育的可行性;又从课程改革、体育全球化、大学生民族教育的缺失等多角度对高校体育教育与少数民族体育运动发展的相关性、互补性进行了分析研究,旨在促进我国高校体育教育事业的发展.     

Effect of light response on the photocatalytic activity of BiOCl x Br1−x in the removal of Rhodamine B from water

BiOClxBr1-x catalysts were synthesized through an alcoholysis method and characterized by X-ray diffraction （XRD）, transmission electron microscopy （TEM）, high-resolution transmission electron microscopy （HRTEM）, and diffuse reflectance spectroscopy （DRS）. The as-prepared photocatalysts were found to be tetragonal crystal structure and lamellar plate morphology. Their band gaps were between 3.44 and 2.83 eV. The effect of light response on the photocatalytic activity of BiOClxBrl-x was investigated by degradation of Rhodamine B （RhB）. Complete removal of RhB from water was realized under simulated sunlight irradiation for 50 min with BiOC10.5Br0.5. Mechanism studies showed that photo- generated holes and superoxide anion radicals played important roles in RhB photodegradation. The results of chemical oxygen demand （COD） confirmed RhB mineralization. The effect of light response on the activity of BiOClxBr1-x was further investigated under monochromatic light irradiation, and BiOCl0.5Br0.5 catalyst exhibited the highest activity. Furthermore, BiOC10.5Br0.5 exhibited high stability, suggesting its practical application for the removal of RhB pollutant from water.     

Human embryonic stem cells-derived endothelial cell therapy facilitates kidney regeneration by stimulating renal resident stem cell proliferation in acute kidney injury

Endothelial cell therapy has been implicated to enhance tissue regeneration and vascularization in ischemic kidney. However, no published study has yet examined direct effects of endothelial cell treatment in kidney recovery. This study investigated the therapeutic efficacy of endothelial cells in a mouse model with acute kidney injury (AKI). Thus, human embryonic stem cells-derived endothelial cells (hESC-ECs) labeled with a reporter system encoding a double fusion reporter gene for firefly luciferase (Fluc) and green fluorescent protein (GFP) were characterized by Fluc imaging and immunofluoresence staining. Cultured hESC-ECs (1×106) were injected into ischemic kidney shortly after AKI. Survival of the transplanted hESC-ECs was monitored in vivo from day 1 to 14 after endothelial cell transplantation and potential impact of hESC-EC treatment on renal regeneration was assessed by histological analyses. We report that a substantial level of bioluminescence activity was detected 24 h after hESC-EC injection followed by a gradual decline from 1 to 14 d. Human ESC-ECs markedly accelerated kidney cell proliferation in response to ischaemia-induced damage, indicated by an elevated number of BrdU+ cells. Co-expression of Sca-1, a kidney stem cell proliferation marker, and BrdU further suggested that the observed stimulation in renal cell regeneration was, at least in part, due to increased proliferation of renal resident stem cells especially within the medullary cords and arteriole. Differentiation of hESC-ECs to smooth muscle cells was also observed at an early stage of kidney recovery. In summary, our results suggest that endothelial cell therapy facilitates kidney recovery by promoting vascularization, trans-differentiation and endogenous renal stem cell proliferation in AKI.     

Recent progress in immobilization of late-transition-metal complexes with diimine ligands for olefin polymerization

Late-transition-metal(LTM) catalysts are a family of very flexible ethylene polymerization catalysts because their catalytic performance can be easily adjusted by modifying the ligand structure.Their less oxyphilicity character,which may promote the production of copolymers from ethylene and polar comonomers,is another aspect that attracts much attention in both academic and industrial fields.The immobilization of LTM catalysts on spherical supports is a crucial step prior to their use in the industrial processes of gas-phase or slurry polymerizations.This paper reviews recent developments in supported LTM catalysts for olefin polymerization,and summarizes loading methods and mechanisms of the immobilization of LTM catalysts on inorganic,organic,and inorganic-organic materials,and the effects of immobilization on catalytic activity,polymerization mechanism,and polymer morphology.