Synthesis of glucoside compounds of ferrocenyl phenols and their antianemic activity

Six glucoside compounds have been synthesized by means of phase-transfer catalytic method and deacetylation from the starting material ferrocene. Their structures have been confirmed by elementary analysis, IR,¹HNMR and MS. The antianemic activities of some compounds have also been tested. Results indicate that these glucoside compounds possess the antianemic activities and therefore, the further study is well worth making. Supported by the foundation of Wuhan Metropolis Commission of Science and Technology Liu Huiying: born in 1937, Professor     

Ab initio calculation of structure and Raman and Infrared spectra of Trifluoromethylthiosulphenyl Chloride

The molecular model of Trifluoromethylthiosulphenyl Chloride, CF₃SSCl, was presented.Ab initio method was used to calculate the structure and Raman and Infrared spectra. The results show that CF₃SSCl possess stereoscopic structure ofC ₁ symmetry with a torsional angle of 94.2°. The potential energy distribution and isotope replacement methods were applied to determine the vibrational assignment. The vibrational frequencies and corresponding modes of the molecule were obtained. The calculated vibrational frequencies are in good agreement with experiments. Supported by the National Natural Science Foundation of China Zou Xianwu: born in Apr, 1938, Professor     

The strong cooperativity of dioxygen binding by dicobalt (II) diporphyrin compounds in nonaqueous solution at room temperature

Thermodynamic data were determined for the reversible binding of O₂ to two compounds of dicobalt(II) di(meso-tetra-phenyl)porphyrin derivatives with different lengths of diamidoaliphatic bridge (abbreviated to Co₂PP₈ and Co₂PP₄) in N,N-dimethylformamide at room temperature. The partial pressure of dioxygen necessary for half-oxygenation (P _1/2) and hill coefficient (n) at 298 K were determined as follows:P _1/2=54.2 kPa,n=2.0 for Co₂PP₈ andP _1/2=6.8 kPa,n=1.8 for Co₂PP₄, respectively. The rate equations of reversible oxygen binding by Co₂PP₈ were determined and the reaction path was proposed. The results of ther-modynamic and kinetic studies indicate that there exists strong cooperative effect during oxygenation of the compounds. The ESR observation reveals that the dioxygen complexes formed in the solutions are of superoxo (Co-O ₂ ⁻ ) type. Supported by the Research Foundation of the State Education Commission of China Zhou Xiaohai: born in 1962, Ph.D. Associate professor