Synthesis of kalsilite from microcline powder by an alkali-hydrothermal process

The properties of aluminosilicate kalsilite have attracted the interest of researchers in chemical synthesis, ceramic industry, biofuels, etc. In this study, kalsilite was hydrothermally synthesized from microcline powder in a KOH solution. The microcline powder, rich in potassium, aluminum, and silicon, was collected from Mountain Changling in Northwestern China. The effects of temperature, time, and KOH concentration on the decomposition of microcline were investigated. The kalsilite and intermediate products were characterized by means of wet chemistry analysis, X-ray Diffraction (XRD), infrared spectrometry (IR), 29Si magic angle spinning nuclear magnetic resonance (29Si MAS NMR), 27Al MAS NMR, and scanning electron microscope (SEM). With increasing temperature, the microcline powder transforms into a metastable KAlSiO₄ polymorph before transforming further into pure kalsilite. A mixture of both kalsilite and metastable KAlSiO₄ polymorph is obtained when the hydrothermal reaction is carried out within 2 h; but after 2 h, kalsilite is the predominant product. The concentration of KOH, which needs to be larger than 4.3 M, is an important parameter influencing the synthesis of kalsilite.     

刚性1,2,4,5-四对甲苯基苯的晶体结构

合成了未引入功能基团的四取代苯类主体分子刚性1,2,4,5-四对甲苯基苯,并用X射线单晶衍射法解析了其晶体结构.晶体属单斜晶系,P1空间群, a=1.0033(6)nm, b=1.1200(7)nm, c=1.1644(7)nm, α=74.63(3)°, β=97.82(2)°, γ=74.98(3)°, V=1.2160(1)nm3, Z=2, Mr=438.58, Dc=1.198g·cm-3, μ(MoKα)=0.067mm-1, F(000)=468,对6109个独立衍射点的最终偏离因子R=0.0580.化合物分子没有对称性,4个对甲基苯环与中心苯环所成二面角分别为49.0°,-40.2°,-43.7°和52.9°.用B3LYP/6-31G**方法对该化合物分子进行了计算,结果表明优化的刚性四对甲苯基苯分子具有C2对称性     

物价收费管理信息系统的设计与实现

使用Delphi 6.0作为前端开发工具,选择InterBase或Access作为后端数据库,设计一个物价收费管理信息系统,该系统由收费许可证管理系统、收费年审统计系统和收费目录及文件查询系统三个子系统组成.该系统已经应用于广西物价局收费处和广西所有的县市物价部门,以及数千个物价收费单位.实际应用表明,该系统安全性高、透明性强、工作效率高.     

REM算法的改进

在分析REM算法和最优化流控模型的基础上,改用非线性优化理论的变尺度算法计算链路影子价格,从而改进了REM算法.模拟实验表明,改进后的REM算法队列十分平稳,收敛速度比原来的算法快,适用于高带宽网络.     

拟线性抛物型偏微分方程组解的振动性

利用Green定理和微分不等式,研究一类拟线性抛物型偏微分方程组 ((e)ui(x,t))/((e)t)=ai(t)Δui(x,t)+∑sk=1aik(t)Δui(x,ρk(t))-pi(x,t)ui(x,t)-∑mj=1fij[t,x,uj(x,σ(t))],i=1,2,...,m解的振动性,获得该类方程组在两类不同边值条件((e)ui(x,t))/((e)N)+gi(x,t)ui(x,t)=0,(x,t)∈(e)Ω×R+,i=1,2,...,m和ui(x,t)=0,(x,t)∈(e)Ω×R+,i=1,2,...,m所有解振动的若干充分条件 limt→∞ inf∫tσ(t)q(s)exp∫sσ(s)p(r)drds>(1)/(e).     

Research on object-oriented SOC design methodology

The growing complexity of System on Chip （SOC） requres a system level specicanon and design approach. High-level languages such as C＋＋/SystemC can play multiple roles in system design as target languages. There are many practical problems in the application of object-oriented methods for this goal. Based on the analysis of traditional and system-level design methodology, a new object-oriented SOC design methodology with object-oriented design patterns is proposed, which emphasizes high-level design and verification. Aiming at the final goal of developing design patterns specific to SOC design, the reuse of design patterns in SOC systems and the capability of new SOC design patterns are discussed. With the illustration of some concrete examples of SOC design patterns, the application of object-oriented design methodology in the SOC design process is presented.     

深部地层取心层裂机理研究

在深部高地应力地层中取心,岩心层裂(饼化)是一种常见的工程现象。岩心层裂和岩体的物性、力学性质以及原地应力密切相关。为研究钻井取心过程中岩心层裂现象的机理,结合川西南部地区Ａ井和B井取心过程中的岩心层裂现象,考虑岩石矿物组分与岩石脆性指数的关系,基于应力集中的非均匀岩石拉伸破坏模型,给出了岩心层裂现象产生的判据,采用理论计算和数值模拟方法对饼化现象进行了验证。研究结果表明：脆性矿物含量越高,岩石脆性越强,越易生成裂缝;岩心套取是一个卸载水平方向最大主应力的过程,卸载速度越快,损伤处的附加拉应力越大,且对应被激活损伤的尺寸就越小,当附加拉应力大于岩石抗拉强度时,会出现岩心层裂现象,随着取心的继续此过程将重复地发生下去。     

通南高沙土区河道岸坡生态治理模式研究

针对通南高沙土区河道水土流失及其硬质化治理引起的生态环境问题,提出从生态修复的角度对河道岸坡采取生态治理的思路.针对硬质化岸坡的生态修复,提出了包括植被岸坡覆盖技术、种植池式垂直绿化驳岸修复技术、景观净污型混凝土组合砌块护岸、活枝捆生态挡土墙垂直驳岸技术、坡面打洞及回填技术等多种方案;针对自然河道岸坡的生态整治,提出了包括植物护岸、木桩植被复合护岸、石笼净水复合护岸、生态袋护岸、植物工程复合护岸等多种方案;并对各种方案的特点、优缺点及其适用类型进行了对比分析,为通南高沙土区河道的生态治理技术选择提供参考依据.     

Effect of Dy substitution on the microstructure and magnetic properties of nanograin Nd-Fe-B single-phase alloys

Nanocrystalline single-phase alloys with the nominal compositions (at%) of Nd_12.3-xDy_xFe_79.7Zr_0.8Nb_0.8Cu_0.4B_6.0 (x=0, 0.5, 1.5, and 2.5) were prepared by melt-spinning and subsequent annealing. X-ray diffraction analysis shows that the as-spun ribbons were mainly composed of the amorphous phase. A slight content of Dy stabilizes the amorphous phase during annealing treatment. The grain size becomes smaller and the coercivity of the annealed ribbon is gradually improved with the increase of Dy content. Excessive Dy is harmful to the remanence. It is found that no intergranular phase exists between the grains by high-resolution transmission electron microscopy, and the grain boundaries are crystallographically coherent in the optimally annealed sample. The optimum magnetic properties of remanence (J_r=1.09 T), coercivity (H_ci=1048 kA/m), and maximum magnetic energy product ((BH)_m=169.5 kJ/m3) are obtained from the x=0.5 ribbon in a post heat-treated state (700℃, 10 min).     

酶解双醛淀粉固定化脲酶的酶学性质

采用酶解双醛淀粉固定化脲酶,并对相应的固定化脲酶的性质进行了研究.扫描电镜分析表明,酶解双醛淀粉固定化脲酶后,载体之间形成较大的团状.研究发现:酶解双醛淀粉固定化脲酶量达到24.3%;酶解双醛淀粉固定化脲酶的最适pH值为6.0,最适作用温度为70℃;固定化脲酶具有很好的储存稳定性和较高的米氏常数,且重复使用10次后的活力仅下降约25%.说明酶解双醛淀粉能有效固定化脲酶,是一种高效的固定化酶载体.