超声波浸渍法制备MnOx/TiO2催化剂低温选择性催化还原NO

采用超声波浸渍法、传统浸渍法和溶胶凝胶法制备了一系列的MnOx/TiO2催化剂,采用X射线衍射(XRD)、比表面积测定(BET)、原位红外(in situ FT-IR)、高分辨率扫描电镜(HRTEM)程序升温还原(TPR)等技术进行表征,同时在模拟氨气选择性催化还原NO的反应条件下( NH3-SCR)对催化剂的低温反应...     

昆翅在飞行中的动态形变

通过理论模化途径研究昆翅在飞行中的动态形变机制.设计翅气动力试验平台,验证翅准静态形变影响气动力的"柔性楔形效应"理论解释.探讨昆翅的变刚度特性表明,弦向刚度分布规律符合二项式函数时具有优越性和现实性,进而指出昆姻结构的变刚度特性是产生高升力的基本条件.建立了柔性翅的简化力学模型,通过坐标变换法求解在气动力和惯性力共同...     

热处理条件对IrO2-pH电极性能的影响

在700℃炉冷、870℃空冷和炉冷三种热处理条件下,制备了氧化铱pH微电极,并对比了微电极的线性范围及响应时间.结果表明:热处理条件对Ir氧化物膜的均匀性有很大影响,进而影响其开路电位的稳定性及响应速度.700℃炉冷和870℃空冷制得的电极氧化膜表面粗糙,孔隙率不均匀并伴随有裂纹;而870℃炉冷条件下制得的电极具有表面氧化膜均匀、响应时间短以及线性好等优点.铱氧化物的形成机理是Ir丝被空气中的O2氧化,而高温Li2CO3起到一种溶剂的作用.铱氧化物电极的H+响应是由于电极表面水合氧化铱与溶液中H+发生化学反应,反应为Ir4+与Ir3+之间的转变.     

退火温度对ZnO薄膜晶体管电特性的影响

针对非晶硅和有机薄膜晶体管的低迁移率问题,以高纯Zn为靶材,反应磁控溅射沉积、且在不同温度下退火的ZnO薄膜作为半导体活性层,成功地制备出基于ZnO材料的薄膜晶体管(ZnO-TFT),研究了退火温度对ZnO -TFT电特性的影响.结果表明:ZnO- TFT的载流子迁移率随退火温度的升高而明显增大,700℃退火的样品迁移...     

基于遗传算法的直觉模糊C均值聚类算法

 针对一般直觉模糊C均值聚类算法在寻优过程中易陷入局部最优解的问题,利用遗传算法具备全局寻优的优点,提出了一种基于遗传算法的直觉模糊C均值聚类算法。在该算法中聚类中心为直觉模糊数,这使得遗传过程中个体信息变得复杂,进而增大了约束问题的处理难度。本文对产生的个体采用适时分段的归一化方法,很好地解决了该问题。仿真结果表明该算法所得聚类结果不仅准确而且更为细致。     

两种基于苯并咪唑衍生物配体的新型铱(Ⅲ)配合物的合成及发光性能研究

合成了新型配体N-异丙基-2-苯基苯并咪唑(bi)和N-异丙基-2-(4-氟苯基)苯并咪唑(fbi),并用它们与三氯化铱和乙酰丙酮反应,制备了相应的环金属铱(Ⅲ)配合物发光材料(bi)2Ir(acac)和(fbi)2lr(acac)(acac=乙酰丙酮).对其结构用1H NMR和元素分析方法进行了表征,研究了配合物的UV-vis,荧光光谱及电化学性质.两种材料的最大发光波长分别位于514 nm和493nm.电化学研究表明,在苯环上引入氟原子后,配合物的HOMO和LUMO间能隙增大(分别为O.12 eV和0.15 eV),与最大发光波长蓝移结果吻合.     

Erratum to: <Emphasis Type="Italic">In vitro</Emphasis> induction of mouse meningeal-derived iPS cells into neural-like cells

The authors report that incorrect figures were included as Figures 4 and 5 in the original publication of this paper. This error occurred during the figure editing process of the publishing company. This information should have been presented as follows:     

Serine/threonine protein phosphatases in DNA damage response

DNA damage response (DDR) is among the most important of the mechanisms that maintain genome stability which, when destabilized, predisposes organs to cancer. Reversible phosphorylation mediated by protein kinases and protein phosphatases regulates most, if not all, cellular activities, including DDR. Protein kinase inhibitors have become the main focus of targeted therapy and anticancer drug development. However, our limited knowledge of protein phosphatase function is compromising our capacity to develop therapeutic agents against phosphatases. In this review, we summarize the roles of serine/threonine protein phosphatases involved in DDR and propose that in situ dephosphorylation of phosphoproteins by protein phosphatases, instead of proteasome-mediated degradation of phosphoproteins, is mainly employed by cells.     

Development of cryogenically-cooled low noise amplifier for mobile base station receivers

A new circuit model for designing and manufacturing an S-band low noise amplifier(LNA) with the software,Advanced Design System(ADS),is introduced in this paper.The proposed model involves shunted impedance at the grid to achieve a stable LNA without measuring the S-parameters of transistors at low temperatures.The LNA was measured over the operation band of 2.2-2.3 GHz,which has input and output standing wave ratios below 1.2.The noise figure of the manufactured LNA was about 0.2 dB and the gain was above 22 dB,which indicated that our LNA worked well at 77 K.     

Entransy dissipation minimization for optimization of heat exchanger design

In this paper,by taking the water-water balanced counterflow heat exchanger as an example,the entransy dissipation theory is applied to optimizing the design of heat exchangers.Under certain conditions,the optimal duct aspect ratio is determined analytically.When the heat transfer area or the duct volume is fixed,analytical expressions of the optimal mass velocity and the minimal entransy dissipation rate are obtained.These results show that to reduce the irreversible dissipation in heat exchangers,the heat exchange area should be enlarged as much as possible,while the mass velocity should be reduced as low as possible.