延期时间对高台阶抛掷爆破效果的影响

为了研究高台阶抛掷爆破合理的延期时间,基于相似材料模型试验,运用有限元软件ANSYS模拟不同排间毫秒延期的抛掷爆破模型.试验和计算结果表明:从增加最远抛距和减少大块率的角度出发,当排间毫秒延期时间小于或等于2 ms时,后排孔爆炸的一部分能量用来给第1排孔爆破的碎块做功,第1排孔碎块的抛距增加,且第1排炮孔的大块率也减少;从有利于改善单元在x、y、z三个方向的应力叠加效果来看,第2排炮孔的延期时间宜定于1.27~2.04 ms之间.由于确定模型尺寸和原型尺寸的几何相似比1:50,故推荐矿山高台阶抛掷爆破的排间延期时间为63.5~102.0 ms.      

综合传动装置悬置系统刚度灵敏度分析与振动能量解耦

基于综合传动装置悬置系统6自由度耦合振动模型,利用灵敏度分析方法,计算悬置系统各阶固有振动频率关于各悬置各方向刚度的灵敏度,确定影响某一方向振动的关键橡胶刚度,为改善系统某一方向的振动提供理论依据.以系统各方向振动解耦率作为目标函数,综合考虑传动轴激励、人体承受振动敏感区域及各向振动耦合状况来确定优化约束条件,进行刚度参数最优化,得到的悬置系统各方向最优刚度值可用于改善悬置系统隔振性能.针对某一传动系统振动恶化的情况,采用刚度灵敏度分析与振动能量解耦综合方法,对悬置系统进行设计.最后利用台架振动试验结果验证悬置系统优化设计的有效性.      

Synthesis and luminescence properties of Mn4+-dopant Ca14Zn6Ga10−xAlxO35 solid solution

Mn~(4+)-activated oxide phosphors,owing to their desirable spectral features,eco-friendly and low cost,are emerging as a new class of non-rare-earth red phosphors for warm white LEDs.However,these phosphors possess low photoluminescence quantum efficiency excited by blue chip currently.Herein we report an isostructural solid solution of Ca_(14)Zn_6Ga_(10-x)Al_xO_(35):0.15Mn~(4+)(0≤x≤10)synthesized by a traditional solidstate reaction route.The microstructure and luminescent performance of this red-emitting phosphor are investigated in detail with the aids of X-ray diffraction,diffuse reflection spectra,photoluminescence spectra/decay/QE,and temperature-dependent PL/QE measurements.Blue shift of energy peaks of~4A_2→~4T_1and~4A_2→~4T_2transition is illustrated by the Tanabe–Sugano diagram and the configurational coordinate diagram.The crystal field strength(Dq)and the Racah parameters(B and C)are carefully calculated to estimate the nephelauxetic effectβrespectively.Particularly we achieve external and internal quantum efficiencies as high as26.1%and 40.3%for Ca_(14)Zn_6Ga_6Al_4O_(35):0.15Mn~(4+)excited by 466 nm,the highest one ever reported in Mn~(4+)activated oxide phosphors under the similar condition.     

Nanoengineering of amino - functionalized mesoporous silica nanospheres as nanoreactors

Selective functionalization of mesoporous silica nanospheres (MSNs) is crucial for nanoengineering of MSNs. Herein, we have combined “surface-protected etching strategy” and “cationic surfactant assisted etching strategy” to prepare functionalized MSNs with externally attached amino groups. The externally attached NH2 groups endow the catalysts with excellent catalytic performance for nitroaldol reaction between nitromethane and benzaldehyde. In addition, those NH2-MSNs can also be used to support gold nanoparticles, which display very good catalytic performance for reduction of 4-nitrophenol. It can be envisioned that the synthesis protocol developed in this work could also be extended to nanoengineered MSNs, which provides opportunities for nanoreactors design.     

The hidden disintegration of cluster heterogeneity in Fe-based glass-forming alloy melt

The evolution of liquid metal at high temperature is known much less than their solid states. This is partially due to that the message concerning clusters, metastable phase or heterogeneity in liquid is usually too slight to be traced. Here, we shed some light on the nature of structural evolution of Fe-based glass-forming alloy during overheating process by the investigation of high-temperature melt viscometry and first principles simulations. It was found that a structural transition around 1400 ℃ occurred in the melts of initial homogeneous ingot, heterogeneous ingot and amorphous ribbons jointly, and was confirmed by the results from differential scanning calorimeter(DSC), and ab initio molecular dynamics(AIMD). Combining these results with Fe-Si-B ternary phase diagram and the melting characteristics of Fe-B compounds, it is safe to conclude that the disintegration of Fe_2B type clusters to Fe_3B-type clusters leads to the observed transition. These results offer a significant reference for the preparation and property control of Fe-based amorphous alloys.     

多发性硬化症患者DTI图像定量化分析

提出了一种联合体素和白质图谱的磁共振扩散张量成像(DTI)方法,明确了多发性硬化症(MS)患者脑白质中受损区域的位置和严重程度.通过计算受检者脑白质区域内各体素中水分子扩散的各向异性指数(FA)和平均扩散率(MD),找出MS患者组和健康对照组(HC)之间FA和MD存在显著性差异的体素及分布情况.结果表明,与HC组相比,MS组FA值在胼胝体体部、压部和双侧放射冠上部等11个脑区有显著性降低;MD值在胼胝体体部、压部和右侧内囊后肢等22个脑区有显著性升高,为临床MS诊断和治疗提供了更有效的参考价值.     

The complexity and on-line algorithm for automated storage and retrieval system with stacker cranes on one rail

This paper considers an on-line scheduling and routing problem concerning the automated storage and retrieval system from tobacco industry. In this problem, stacker cranes run on one common rail between two racks. Multiple input/output-points are located at the bottom of the racks. The stacker cranes transport bins between the input/output-points and cells on the racks to complete requests generated over time. Each request should be accomplished within its response time. The objective is to minimize the time by which all the generated requests are completed. Under a given physical layout, the authors study the complexity of the problem and design on-line algorithms for both one-stacker-crane model and two-stacker-crane model. The algorithms are validated by instances and numerical simulations.     

基于认知灵活理论的《化学教师技能》网络课程设计与开发

《化学教师技能》是高等师范院校教师教育课程体系中十分重要的课程,在认知灵活性理论指导下,探讨了《化学教师技能》网络课程开发的理论基础、设计依据、模块功能和开发技术,并开发了“教、学、练、评”为一体的教学平台,可以解决当前化学教师技能学习资源不足的问题,成为课堂教学的有益补充,有效提高教学水平.     

从安全发展视角看煤老板的历史命运

煤老板是私营煤矿主的代名词,他们在市场经济发展的一个特殊过程中出现,也起到过特殊的历史作用。由于造成安全事故,破坏生态环境,引起官煤勾结的腐败现象,在新一轮煤炭资源整合中,他们中的一部分将彻底退出历史舞台,一部分将转变为煤矿企业的股东。针对为煤老板辩护、反对煤炭资源整合的论点,本文分析了煤老板产生的历史过程,从安全视角探讨了煤炭资源整合的必要性和煤老板退出历史舞台的历史必然性,指出规模过小、安全技术低下,是矿难频发的重要原因,只有通过资源整合重组,使煤矿企业做大做强,才能够从根本上遏制矿难,实现安全发展。     

PP-ST-DVB纤维氯甲基化与胺化反应研究

通过三甲基氯硅烷(TMCS)在聚丙烯接枝苯乙烯-二乙烯苯(PP-ST-DVB)纤维上的氯甲基化及胺化反应制得一种强碱离子交换纤维新材料,通过红外光谱(FT-IR)、扫描电镜(SEM)与元素分析等手段对各步产物结构与功能基含量进行了分析和表征,并重点考察了各种因素对氯甲基化反应的影响。结果表明:氯甲基化PP-ST-DVB纤维中的氯质量分数达12.62%,经胺化所得强碱性离子交换纤维的交换容量可达2.7mmol/g。这种强碱性离子交换纤维的绿色合成工艺具有反应温和及环境友好的优点。