树枝状有机电致发光材料近期研究进展

本文简要介绍了近期树枝状分子在有机电致发光材料领域中的拓展情况,总结了目前已经取得的一些令人振奋的研究成果,从中了解树枝状分子在该研究领域所特有的优势,并进一步展望了树枝状分子未来的研究前景。     

A model of calcium signaling and degranulation dynamics induced by laser irradiation in mast cells

Recent experiments show that calcium signaling and degranulation dynamics induced by low power laser irradiation in mast cells must rely on extracellular Ca^2＋ influx. An analytical expression of Ca^2＋ flux through TRPV4 cation channel in response to interaction of laser photon energy and extracellular Ca^2＋ is deduced, and a model characterizing dynamics of calcium signaling and degranulation activated by laser irradiation in mast cells is established. The model indicates that the characteristics of calcium signaling and degranulation dynamics are determined by interaction between laser photon energy and Ca^2＋ influx. Extracellular Ca^2＋ concentration is so high that even small photon energy can activate mast cells, thus avoiding the possible injury caused by laser irradiation with shorter wavelengths. The model predicts that there exists a narrow parameter domain of photon energy and extracellular Ca^2＋ concentration of which results in cytosolic Ca^2＋ limit cycle oscillations, and shows that PKC activity is in direct proportion to the frequency of Ca^2＋ oscillations. With the model it is found that sustained and stable maximum plateau of cytosolic Ca^2＋ concentration can get optimal degranulation rate. Furthermore, the idea of introducing the realistic physical energy into model is applicable to modeling other physical signal transduction systems.     

微生物谷氨酰胺转胺酶对大豆分离蛋白凝胶性的影响

利用Streptoverticillium sp.CJ3033菌株发酵得到发酵液,经过滤、离心、冷冻浓缩、乙醇沉淀和冷冻干燥后,制得的谷氨酰胺转胺酶粗酶作用于大豆分离蛋白,利用物性分析仪研究了MTG对大豆分离蛋白形成凝胶的特性及持水性的作用.通过二次回归正交组合设计的方法研究了MTG的添加浓度、作用时间、处理温度对SPI凝胶形成及保水性的影响,结果显示:MTGase对大豆分离蛋白有显著改善作用,在51℃、反应1.5 h、酶浓度9.82 U/g时,SPI的凝胶强度最大,达74.95 g/mm2;在49℃、反应1.3 h、酶浓度7.78 U/g时,SPI的持水率为96.47%.     

Removal of NO<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript> by radical injection

Removal of NOx(DeNOx, NOx is the total of NO and NO2) from flue gas by radical injection has been investigated .the discharge characteristics were examined and the steady streamer corona was acquired hy adjusting the nozzle gases properly. It was Found that an increase in the voltage resulted in a decrease in the NO concentration and the concentration of the NO2 increased at tow voltages but decreased as the voltage rose to a certain level. The DeNOx efficiency increased as the applied voltage rose and reached a maximum of 70% when the voltage approached the breakdown voltage. The hypothetical mechanism of NOx removal suggested that the radicals formed in the discharge process converted the NO and NO2 into acidic species. The Monte Carlo method was used to calculate the rate coefficients and the productivity of the radicals, and then the concentrations of both NO and NO2 and the DeNOx effielencies were calculated with chemical kinetics. The calculated DeNOx efficiencies were coalparable with the experimental DeNOx efficiencies at low voltages, but were lower at high voltages.     

连续变量问题全局优化的模拟退火法

本文针对过程系统连续变量优化问题中普遍存在的多峰现象, 探索了应用模拟退火法求解其全局最优解。文中根据连续变量问题的特性, 提出了一种相邻状态的产生函数和迭代方案, 并分析了模拟退火过程的起始温度、终止温度以及降温速度等参数对优化计算的影响, 给出了这些参数的适宜区域, 通过三个例题的计算, 将模拟退火法与传统优化方法一梯度法进行了对比分析, 结果表明该法能够有效地解决传统的确定型优化方法所不能奏效的全局优化问题。     

基于密度可达的聚类隐私保护模型

针对面向聚类的数据隐私发布问题,基于密度可达邻域的概念,提出一种面向聚类的隐私保护模型PPC(r,ε,h).该模型通过要求隐藏后所有数据记录在ε内密度可达(r相关)的近邻数不小于h,以避免可能出现的近邻攻击.进一步提出密度可达安全邻域概念,对不满足模型要求的邻域,采用平移近邻的数据隐藏方法进行处理,保证发布后数据集满足模型约束.并利用邻域价值和邻域相似性的概念,对平移过程进行优化.理论分析和实验结果表明,基于PPC(r,ε,h)隐私模型设计的数据隐藏方法,能有效维持原数据集中数据点在各聚簇中的分布,且兼顾了发布后数据的聚类可用性和数据安全性.     

不同屋面雨水径流中PAHs污染特性对比分析

对南京市典型沥青屋面、瓦屋面径流中PAHs含量进行了9场降雨事件的现场取样监测,对比分析了2种不同屋面径流中PAHs的EMC值及其各组分的浓度,并对其初期效应及影响因素进行了分析和探讨.结果表明,沥青屋面径流PAHs污染较严重,其平均浓度为4 261.7 ng/L,而瓦屋面径流PAHs平均浓度仅为351.2 ng/L.沥青屋面、瓦屋面径流中PAHs均以4环组分为主,沥青屋面径流中3环组分占较大含量,而瓦屋面径流中5环和6环PAHs浓度仅次于4环PAHs.大多数降雨事件中总PAHs及各组分均存在较显著的初期效应;前期晴天数对PAHs在屋面的累积影响最大,瓦屋面径流PAHs含量受降雨强度影响较大,而沥青屋面径流PAHs含量受降雨量影响较大.     

Ultrafast polarization optical switch constructed from one-dimensional photonic crystal and its performance analysis

All-optical switch with the ultrafast optical switching rate is a key device in the next generation optical network. In this article, we propose a polarization switch with ps switching time, which is constructed from one-dimensional resonant photonic crystal （1D RPC）. The model of switch operating at 1.5 μm is established based on the optical stark effect （OSE）. We calculate the performance indices of the switch and the influences of errors of periods and refractive index on the performance characteristics.     

A comparative study of magnetic properties between whole cells and isolated magnetosomes of <Emphasis Type="Italic">Magnetospirillum magneticum</Emphasis> AMB-1

The magnetic properties of magnetosome magnetite are of interdisciplinary interest because magnetosomes are potential carriers of natural remanent magnetization and paleoenvironment, as well as novel nano-biomaterials in biotechnological and biomedical applications. We carried out magnetic and electron transmission microscopy analyses of fresh Magnetospirillum magneticum AMB-1 whole cells and isolated magnetosomes. Results revealed that AMB-1 synthesized single-domain magnetite magneto-somes, which are arra...     

广西河池市重金属污染现状分析与治理对策

广西河池市的重金属污染在长期的矿山开采、冶炼、加工以及工业化进程中累积形成,水环境污染、大气环境污染、固体废弃物污染和土壤污染问题日趋严峻,重金属污染事件呈高发态势。这主要是因为河池市的重金属产业结构不合理,环保基础工作薄弱,涉重重点企业的清洁生产低率,同时河池市的重金属污染涉及的行业和部门较多,历史旧帐较多,管理、监察和监测的水平严重滞后,所以河池市的重金属污染防治工作的重点应该定位为“以防为主,治理为辅,防治结合”的方针,深入开展重金属污染调查,合理规划产业布局,全力推进重金属污染减排工作,推行重点企业清洁生产,同时,还要强化重金属污染监察、监测能力建设,做好宣传教育工作,提高全民对重金属污染的防治意识。