烷氧基稀土钠簇合物SmNa8（O^t Bu）10（OH）的合成及催化性能初探

用定量加入NaOH的方法高产率地合成了烷氧基稀土钠簇合物SmNa8（O^t Bu）10（OH），并对其进行了X射线晶体结构鉴定．此外，将其对芳醛的Tishchenko反应的催化活性进行了初探．     

复合土工膜不同锚固方式的力学特性对比研究

复合土工膜作为一种新型的防渗结构体应用于堆石坝工程，效果突出，但是在土工膜的锚固处容易产生应力集中，出现“端部固定效应”．本文结合国外某工程实例，应用商业软件FLAC3D，采用三维显式有限差分法分别对不同锚固方式情况下复合土工膜的应力、变形进行计算分析．结果表明，采用不同的土工膜锚固方式对其受力有一定的影响，在实际工程中，应采用合适的复合土工膜锚固方式改善土工膜的受力状态，减小“端部固定效应”的影响     

浅述外围护结构的建筑节能技术

外围护结构在建筑节能中起着重要作用,对外围护结构进行合理的设计选择,能极大地降低建筑能耗.文章针对外围护结构,从墙体、屋面、门窗3方面提出了一些提高外围护结构热保温性能的措施,从而改善建筑节能,以供借鉴.     

含有{M[P4Mo6O31]2}夹心型磷钼酸盐构筑块的水溶性多酸化合物的合成与表征

采用水热方法合成了一个新的磷钼酸盐化合物，并通过元素分析、红外、紫外、循环伏安和单晶X射线衍射分析等手段对其进行了表征。单晶结构解析结构表明，该化合物的阴离子{Na[Mo₁₂O₂₄(OH)₆(PO₄H)₂(PO₄H_3/2)₂]}^6- 由2 个{Mo₆P₄O₃₁} 单元和一个八面体配位的金属钠离子共价组装形成，具有夹心型结构。该化合物是目前为止获得的第一个含有孤立M[Mo₆P₄O₃₁]₂ 夹心结构的水溶性多钼磷酸盐。该水溶性化合物将会作为一个基本的反应原料和基本构筑单元合成组装出更多结构新颖、性质丰富的新型多钼磷酸盐。     

Facile construction of novel CoMoO4 microplates@CoMoO4 microprisms structures for well-stable supercapacitors

A simple and controllable strategy has been developed to fabricate CoMoO_4 microplates/CoMoO_4 microprisms(CMCMs) structures on Ni foam via a facile, cost-effective, two-step hydrothermal route. The as-grown 3D architecture exhibited excellent areal capacitance of 4.33 F cm~(-2)at a galvanostatic chargedischarge current density of 50 mA cm~(-2)(6 Ag~(-1)) and outstanding cycle performance with only 2.8%degradation over 6500 cycles in the 3 M KOH solution. The asymmetric all-solid-state supercapacitors based on activated carbon(AC) and CMCMs exhibited much better electrochemical performance than the symmetric counterpart, showing an areal capacitance of 95.22 mF cm~(-2)at the current density of 12 m A cm~(-2)and excellent cycling stability with 92.27% of the initial capacitance after 5000 cycles. These results may provide useful guidelines for materials selection and configuration designs for the novel energy storage devices based on Co Mo O4 components and substrates.     

Abrupt onset of a second energy gap at the superconducting transition of underdoped Bi2212

The superconducting gap--an energy scale tied to the superconducting phenomena--opens on the Fermi surface at the superconducting transition temperature (T(c)) in conventional BCS superconductors. In underdoped high-T(c) superconducting copper oxides, a pseudogap (whose relation to the superconducting gap remains a mystery) develops well above T(c) (refs 1, 2). Whether the pseudogap is a distinct phenomenon or the incoherent continuation of the superconducting gap above T(c) is one of the central questions in high-T(c) research. Although some experimental evidence suggests that the two gaps are distinct, this issue is still under intense debate. A crucial piece of evidence to firmly establish this two-gap picture is still missing: a direct and unambiguous observation of a single-particle gap tied to the superconducting transition as function of temperature. Here we report the discovery of such an energy gap in underdoped Bi2Sr2CaCu2O8+delta in the momentum space region overlooked in previous measurements. Near the diagonal of Cu-O bond direction (nodal direction), we found a gap that opens at T(c) and has a canonical (BCS-like) temperature dependence accompanied by the appearance of the so-called Bogoliubov quasi-particles, a classical signature of superconductivity. This is in sharp contrast to the pseudogap near the Cu-O bond direction (antinodal region) measured in earlier experiments.     

关于一类不定方程有解的一般性结论

用模型论的方法证明了一类不定方程a1xr11 a2xr22 ... anxrnn=bys(其中a1,...,an,b为任意整数,r1,...,rn,s为任意正整数)有解.进一步地,我们用相同的方法解决了一个猜想.     

平面变栅距位相光栅位移传感器的测量精度极限

提出用透射式变栅距位相光栅作位移传感器,用标量衍射理论讨论了这种传感器的测量精度与光栅的起始栅距及栅距变化系数之间的关系,同时用时域有限元差分(FDTD)算法计算了变栅距位相光栅的衍射场,计算结果表明受衍射偏振特性的影响,这种位移传感器的测量精度在理论上存在极限.     

负载型钼氧化物催化剂NH3选择性催化还原NOx

通过浸渍法制备了Mo/TiO2,Mn-Mo/TiO2和Mo-Mn/TiO2三种催化剂,采用X射线衍射(XRD)、比表面积测定(BET)、拉曼光谱(LRS)、原位红外(in situ FT-IR)、扫描电镜(SEM)等技术进行相关的微观表征分析.在模拟氨气选择性催化还原NO的反应条件下(NH3-SCR)对催化剂的脱硝反应...     

大型板装配拼接节点试验研究

提出了装配整体式钢筋混凝土大型板一种新的横向拼接节点构造,对9根新型横向连接预制板试件进行试验研究与承载力分析,量测并分析试件的荷载、挠度及应变,观测试件的裂缝发展情况和破坏过程.试件的破坏形态包括弯曲破坏、受剪破坏及轴向拉伸破坏等形式.试验表明,该新型横向连接节点连接可靠,具有良好的承载能力和延性.对新型横向连接节点...