Boosting photocatalytic Suzuki coupling reaction over Pd nanoparticles by regulating Pd/MOF interfacial electron transfer

Palladium-catalyzed C-C coupling reactions are of significant importance, but they often require harsh conditions. Herein, we report an interface-regulated photocatalytic Suzuki coupling reaction over Pd nanoparticles supported on a metal-organic framework (MOF), ZIF-8. Two Pd/MOFs were synthesized, Pd_PVP/ZIF-8 and Pd/ZIF-8, which have similar Pd sizes and loading amounts, except that the former contains poly(vinylpyrrolidone) (PVP) as a surfactant. The diffuse-reflectance infrared Fourier transform of CO adsorption (CO-DRIFT) indicates that Pd/ZIF-8 represents a more negative electronic state of Pd than Pd_PVP/ZIF-8. In the photocatalytic Suzuki coupling reaction between iodobenzene and phenylboronic acid, Pd/ZIF-8 exhibits excellent performance (99.1% yield), much better than that of Pd_PVP/ZIF-8 (57.9% yield). Moreover, Pd/ZIF-8 is highly stable and shows broad substrate scope for this reaction. The superior activity of Pd/ZIF-8 can be attributed to sufficient electron transfer between the MOFs and Pd nanoparticles in the absence of an interfacial surfactant. This work provides new insights into a Pd-catalyzed C-C coupling reaction involving photocatalysis and interfacial electron transfer.     

基于响应面和NSGA-II的AGV系统多目标优化配置

AGV（automated guided vehicle）系统对于制造系统的生产柔性和生产效率具有重要作用,由于AGV系统具有许多的变量且有动态性、随机性特点,其优化配置比较复杂。提出了一种将系统仿真、数学解析和多目标优化相结合的方法,对AGV系统进行了优化配置;运用离散事件仿真模拟AGV系统运行,利用敏感性分析分离设计变量,采用析因试验和响应面方法拟合多目标优化数学模型,基于非支配解排序多目标遗传算法求解多目标优化解。通过AGV系统实例,证明了该方法的有效性,可为制造系统和物流仓储领域中AGV系统的优化配置提供一种有效的系统性分析方法。     

Long-Time Behavior and Density Function of a Stochastic Chemostat Model with Degenerate Diffusion

This paper considers a stochastic chemostat model with degenerate diffusion. Firstly, the Markov semigroup theory is used to establish sufficient criteria for the existence of a unique stable stationary distribution. The authors show that the densities of the distributions of the solutions can converge in L¹ to an invariant density. Then, conditions are obtained to guarantee the washout of the microorganism. Furthermore, through solving the corresponding Fokker-Planck equation, the authors give the exact expression of density function around the positive equilibrium of deterministic system. Finally, numerical simulations are performed to illustrate the theoretical results.

     

Discovering non-terminating inputs for multi-path polynomial programs

This paper investigates the termination problems of multi-path polynomial programs （MPPs） with equational loop guards. To establish sufficient conditions for termination and nontermination simultaneously, the authors propose the notion of strong/weak non-termination which under/over- approximates non-termination. Based on polynomial ideal theory, the authors show that the set of all strong non-terminating inputs （SNTI） and weak non-terminating inputs （WNTI） both correspond to tile real varieties of certain polynomial ideals. Furthermore, the authors prove that the variety of SNTI is computable, and under some sufficient conditions the variety of WNTI is also computable. Then by checking the computed SNTI and WNTI varieties in parallel, termination properties of a consid- ered MPP can be asserted. As a consequence, the authors establish a new framework for termination analysis of MPPs.     

广义不确定分布参数系统变结构控制

研究了一类广义不确定分布参数系统的综合问题,由广义不确定分布参数系统的特点,直接给出了变结构控制的设计方法。设计过程简单,控制易于实现,且给出了实例     

Optimum design of equivalent accelerated life testing plans based on proportional hazards-proportional odds model

The optimum design of equivalent accelerated life testing plan based on proportional hazards-proportional odds model using D-optimality is presented.The defined equivalent test plan is the test plan that has the same value of the determinant of Fisher information matrix.The equivalent test plan of step stress accelerated life testing(SSALT) to a baseline optimum constant stress accelerated life testing(CSALT) plan is obtained by adjusting the censoring time of SSALT and solving the optimization problem for each case to achieve the same value of the determinant of Fisher information matrix as in the baseline optimum CSALT plan.Numerical examples are given finally which demonstrate the equivalent SSALT plan to the baseline optimum CSALT plan reduces almost half of the test time while achieving approximately the same estimation errors of model parameters.     

Target estimation using MIMO radar with multiple subcarriers

This paper analyzes the effect of waveform parameters on the joint target location and velocity estimation by a noncoherent multiple input multiple output (MIMO) radar transmitting multiple subcarriers signals. How the number of subcarriers influences the estimation accuracy is illustrated by considering the joint Cramer-Rao bound and the mean square error of the maximum likelihood estimate. The non-coherent MIMO radar ambiguity function with multiple subcarriers is developed and investigated by changing the number of subcarriers, the pulse width and the frequency spacing between adjacent subcarriers. The numerical results show that more subcarriers mean more accurate estimates, higher localization resolution, and larger pulse width results in a worse performance of target location estimation, while the frequency spacing affects target location estimation little.     

基于双库协同机制的KDD*及其软件实现

在KDD(基于数据库的知识发现 )的基础上 ,提出了KDD的开放系统—KDD 的总体结构 ;探讨了其关键技术—双库协同机制的理论基础与实现技术 ;介绍了因果关联规则的统计归纳的发掘方法。初步演示试验的结果表明 ,KDD 这类新型构造是有效与可行的。     

单向关闭三部件串-并联可修系统的可靠性

研究了单向关闭先坏先修三部件串-并联可修系统的可靠性,在假定部件1的失效分布服从可变参数为λ(λ0)的指数分布条件下,利用补充变量法,得到了该系统的瞬时可用度和稳态可用度、系统的可靠度、系统的瞬时和稳态故障频度.     

要素市场一体化对地区全要素生产率的影响

通过测算2011—2020年省级地区的资源错配方向发现,落后地区的资源配置过度,而发达地区处于资源配置不足的状态,因此要素市场一体化意在改善资源错配的现状,提高落后地区边际生产率,并发挥集聚效应促进先进地区全要素生产率的提高。由此,基于我国2008—2019年30个省份的省际面板数据构建计量模型验证该理论假说,结果表明,要素市场一体化在促进先进地区生产率提高的同时,也有助于通过要素的流出对落后地区产生促进作用。作用机制分析显示,促进技术进步与技术效率的提高是要素市场化提升全要素生产率的机制。