水平井分段压裂过程对水泥环完整性影响

水平井分段压裂过程中出现的套管损坏和水泥环完整性问题日益引起关注。目前研究的重点包括地层滑移、套管和水泥环受力等,而对分段压裂过程造成影响的研究较少。为了建立水平井分段压裂水泥环完整性计算模型和方法,首先,利用有限元软件建立有限元模型,得到水平井分段压裂过程中水泥环弹性区和塑性区分布;其次,利用离散元模型分析有限元中得到的塑性变形区域,获取塑性变形区域内水泥环的微裂纹数量;最后,依据水泥环塑性区分布和微裂缝数量得到水泥环的完整性评价。研究表明,除了套管和水泥环刚度比、套管偏心率和水泥环缺陷对水泥环完整性有影响,水平井的压裂段数的影响也较为明显。随着套管和水泥环刚度比增加,水泥环完整性增强;套管偏心率增加和水泥环存在缺陷降低水泥环完整性;水平井压裂段数越多,水泥环完整性降低。     

扶手椅型单壁碳纳米管氮烯环加成异构体结构和性质的理论研究

用AM1方法研究了(3，3)、(4，4)、(5，5)和(6，6)扶手椅型单壁碳纳米管(ASWCNTs)以及其氮烯环加成异构体的结构和性质，并重点讨论了这些异构体之间的转化关系．POAV分析表明，扶手椅型单壁碳纳米管的直径越大，张力就越小，“一“共轭作用也越强．     

Potential Dependence of the Raman Spectra and the Study of Adsorption Model for 4, 4-Bipyridine on A Silver Electrode

The study of the adsorption properties and adsorption model of molecules or ions on substrates is an important part of surface enhanced Raman scattering (SERS) experimental investigations. In this paper, we will present the findings of our research work with regard to the potential dependence of the SERS spectra for 4, 4' -bipyridine (bpy) on the silver electrode and the adsorption model for bpy adsorbed on the silver electrode surface. We find the intensities of the SERS spectra with all Raman shifts can be changed by changing the applied potentiat and reach maxima when the applied potential is ca. -0.70 V (Vs. SCE). The experimental study also indicates that the pyridine ring of bpy adsorbs directly on the silver electrode surface via the N-atom.     

四面体中著名不等式的统一和加强

本文在证明了Ｐｏｌｙａ－Ｓｚｅｇｏ不等式向四面体推广所得的两种形式等价的同时，统一证明了四面体中的一些著名不等式，并加强了这些不等式。     

Molecular basis of photoprotection and control of photosynthetic light-harvesting

In order to maximize their use of light energy in photosynthesis, plants have molecules that act as light-harvesting antennae, which collect light quanta and deliver them to the reaction centres, where energy conversion into a chemical form takes place. The functioning of the antenna responds to the extreme changes in the intensity of sunlight encountered in nature. In shade, light is efficiently harvested in photosynthesis. However, in full sunlight, much of the energy absorbed is not needed and there are vitally important switches to specific antenna states, which safely dissipate the excess energy as heat. This is essential for plant survival, because it provides protection against the potential photo-damage of the photosynthetic membrane. But whereas the features that establish high photosynthetic efficiency have been highlighted, almost nothing is known about the molecular nature of the dissipative states. Recently, the atomic structure of the major plant light-harvesting antenna protein, LHCII, has been determined by X-ray crystallography. Here we demonstrate that this is the structure of a dissipative state of LHCII. We present a spectroscopic analysis of this crystal form, and identify the specific changes in configuration of its pigment population that give LHCII the intrinsic capability to regulate energy flow. This provides a molecular basis for understanding the control of photosynthetic light-harvesting.     

平封头与壳体连接圆角处的局部应力

根据板壳理论的分析及采用有限元对多个算例的计算结果，提出平封头与圆柱壳体连接处的应力集中系数可以表示为３个无量纲参量的函数，并绘出相应曲线，可供设计参考．按照应力分类的观点，该处应力为一次应力与二次应力之和，应控制在３（σ）以下．     

公文汉译英的顺应性研究

本文以公文汉译英为研究对象,以顺应论为依据,结合公文的翻译和顺应论研究,从词汇层级、句法层次、语境层次考察公文的特点;以V erschueren的顺应论和认知一致原则为基础,从交际语境和语言结构差异的角度对影响公文翻译的各种不同但又相互联系的语境因素进行探讨。通过对原文和译文的差异比较,说明译者为促成认知一致,在公文翻译过程中应如何顺应这些语境因素(语言语境与交际语境):顺应受众的心理世界、社交世界、物理世界以及顺应目的语的语言现实。     

TiO_2微粒光催化降解二苄基砜

以半导体TiO2为催化剂,对二苄基砜（ASO2A）进行光催化降解,研究降解二苄基砜的反应条件,讨论了TiO2为催化剂降解ASO2A的实质,初步确定反应机理．     

Functionalized graphene oxide based on p-phenylenediamine as spacers and nitrogen dopants for high performance supercapacitors

p-Phenylenediamine （PPD） functionalized graphene oxide （GO） materials （PPDG） were prepared through a one-step solvothermal process and their appli-cation as supercapacitors （SCs） were studied. The PPD is not only as the spacers to prevent aggregating and re-stacking of the graphene sheets in the preparing process but also as nitrogen sources to obtain the nitrogen-doped graphene. The structures of PPDG were characterized by Fourier transformed infrared spectroscopy （FT-IR）, X-ray diffraction spectroscopy （XRD）, Raman spectroscopy and X-ray photoelectron spectroscopy （XPS） and the results show that the nitrogen-doped graphene was achieved with nitrogen content as high as 10.85 at.%. The field emission scanning electron microscopy （FE-SEM） and high resolu-tion transmission electron microscopy （HR-TEM） have confirmed that the morphologies of PPDG were looselayered with less aggregation, indicating that PPD mole-cules, as spacers, effectively prevent the graphene sheets from restacking during the solvothermal reaction. The special loose textures make PPDG materials exhibit excellent electrochemical performance for symmetric SCs with superior specific capacitance （313 F/g at 0.1 A/g）, rate capability and cycling stability. The present synthesis method is convenient and may have potential applications as ultrahigh performance SCs.