Synthesis and Characterization of Porphyrin-Trisbenzimidazole Dinucleating Ligand and Its Heterodinuclear Complex as CcO Active Site Model

A new dinucleating ligand having two metal-binding sites has been designed and synthesized as model ligand for Cytochrome c Oxidase. The corresponding heterodi-nuclear complex, as an active site model of Cytochrome c Oxidase, consisting of a porphyrinatocobalt compound covalently linked with a copper derivative of tris(2-benzimidazylmethyl) amine bearing three benzimidazole ligands for copper was synthesized and spectroscopically characterized. The spectra data suggest that there are interactions between the cobalt and copper coordination units. The cobalt is coordinated to four central nitrogens of the porphyrin and the copper has pentaco-ordinate geometry with the four tertiary amine nitrogens and a chloride.     

Shift visual cryptography scheme of two secret images

A new visual cryptography scheme of two secret images, which is named the shift visual cryptography of two secret images, is given. The compound function family of a general construction model is also introduced. The uniqueness and validity of this model are proved, and the minimum rows and columns for realizing the scheme are obtained. Compared with visual cryptography of one secret image, the shift visual cryptography scheme can share two secret images with the same size of pixels expansion without losing the contrast. It has randomness and various forms, and furthermore, we can also visually recover two secret images even if the two shares are different in form and color.     

Initial organic geochemical investigation on Late Neoproterozoic-Early Cambrian sediments in the Yangtze region, China

Totally 19 samples of typical Upper Proterozoic-Lower Cambrian sedimentary rocks were collected and analyzed for an organic geochemical investigation. Almost all these rocks have high TOCs, super-maturities and similar biomarker distribution. As an exception, however, the Sinian Nantuo Tillite shows much lower TOCs and little phytane and pristane in comparison with those in other strata, which implies a very faint photosynthetic process, and a restricted euphotic zone and quite limited sunlight within the sedimentary water column during the Sinian glaciation age in the western Yangtze region providing an evidence for palaeo-oceanic environment of the Neoproterozoic Snowball Earth age.     

电视胸腔镜下微创脊柱侧弯前路松解术的初期临床结果

探讨电视胸腔镜在严重脊柱侧弯前路松解中的应用价值,并对其初期临床结果进行分析.2001年11月-2002年8月,共11例严重脊柱侧弯患者接受电视胸腔镜下前路松解,均为女性,特发性胸椎脊柱侧弯,年龄14～17岁.冠状面Cobb角90°～100°,Risser征+++～++++,松解范围T5～T12,松解节段5～7.术后行牵引二周再行后路TSRH矫形内固定术.术中出血量为100～150mL,手术时间180～220min,术后引流量520～650mL,引流时间48～96h,二期后路手术矫正率平均为58%.电视胸腔镜下脊柱侧弯的前路松解在不影响矫形手术效果的同时,能减少组织损伤,降低感染可能,减轻术后疼痛,缩短病人的康复时间.     

论FDI对西部制度变迁的影响及对策

本文首先对我国西部地区利用FDI的现状进行了描述 ,然后运用回归分析的方法分析了FDI和制度变迁的关系 ,指出FDI是影响区域制度变迁的重要因素 ,FDI在区域分布上的不均衡严重制约着西部地区制度变迁的进程。西部地区应该加快体制改革的步伐 ,改善投资环境 ,吸引FDI ,进而通过FDI带动西部地区制度变迁的进程 ,最终形成FDI和制度变迁相互推动、相互促进的良性循环。     

高科技企业竞争的网络特征及其对策

本文从提高我国高科技企业持续创新能力的现实需要出发 ,在对高科技产业核心资源和市场特性分析的基础上 ,从网络效应角度具体分析了其竞争的网络特征 ,最后从培育核心能力 ,实施网络作战等方面提出了在网络竞争环境下 ,提升高科技企业竞争优势的具体对策。     

Triassic U-Pb age for zircon from granites in the Tonghua area and its response to the Dabie-Sulu ultrahigh-pressure collisional orogenesis

Single-grain zircon U-Pb dating was carried out to constrain the emplacement timing of granitic plutons at Chaxinzi, Xiaoweishahe and Longtou in the Tonghua area, south of Jilin Province. The results show that these plutons formed in the Triassic with ages of 203—217 Ma. Geological and geochemical characteristics indicate that the plutons are composed of quartz diorite and granite. The former was derived from partial melting of mafic lower crust, whereas the latter originated from thickened crust with garnet as the residue in the source. It appears that protoliths of these two types of granitits are different although they have the same emplacement age. Considering that these plutons are petrologically different from the coeval granites in the Xingmeng (Xing‘an-Mongolian) to Jihei (Jilin-Heilongjiang) orogenic belt in the north, it is suggested that their formation was related to the Dabie-Sulu ultrahigh-pressure collisional orogenesis since their ages are only 10—20 Ma younger than timing of the ultrahigh-pressure metamorphism, but comparable to that of the first rapid exhumation of the ultra-high-pressure metamorphic rocks and the emplacement of the post-collisional granites.     

Evolution of the South China Sea and monsoon history revealed in deep-sea records

As the third summary report of ODP Leg 184 to the South China Sea (SCS), this paper discusses the evolution of the East Asian monsoon and the SCS basin. A multi-proxy approach, involving geochemistry, micropale-ontology, pollen and other analyses, was adopted for reconstructing the evolutionary history of the East Asian monsoon, which was characterized by a series of paleo-climate events especially at 8, 3.2, 2.2 and 0.4 Ma. The new record indicates similar stages in the development of the East and South Asian monsoons, with an enhanced winter monsoon over East Asia being the major difference. The rich spectrums of monsoon variability from the southern SCS also reveal other characteristic features of the low latitude ocean. Evidence for the evolution of the SCS includes the hemipelagic Oligocene sediments, implying the existence of deep water environments during the early seafloor spreading stage of the SCS basin. The four major unconformities and some remarkabl ediagenetic features in upper Oligocene deposits indicate the strongest tectonic events in the region. From a careful comparison of lithologies and sedimentation rates, we conclude that the prominent differences in sedimentary environments between the southern and northern SCS were established only by ～3 Ma.     

多媒质区域介质子网格时域有限差分法

介绍了应用于多媒质区域电磁问题的介质子网格时域有限差分法．该方法在保证精度的前提下，节省了大量计算时间及计算机内存，尤其在处理多媒质界面方面具有很大的优势．     

老年人住宅建筑设计的新思考

针对老年人生活行为特征和老年人对住宅建设及住宅功能的需求，阐述了老年住宅建筑设计的原则，提出了老年住宅建筑设计的要点，强调了住宅建筑设计要以人为本和以老年人为核心的设计思想。