甘氨酸在电沉积铁铬合金中的作用

研究不同浓度甘氨酸对电沉积铁铬合金过程的影响,分析了甘氨酸在电沉积过程中的作用.加入甘氨酸后,可得到优良的镀层,而不含甘氨酸时,镀层中夹杂铬的化合物,造成镀层质量低劣.甘氨酸浓度为0.4～0.8 mol·L-1时,镀层中铬含量较稳定.甘氨酸的加入使得阴极极化增加,电位负移.在此镀液中,甘氨酸与Fe(Ⅱ)络合,使其析出电位负移,达到铁铬共沉积的目的.     

一种碳酸盐岩流体替换新方法

针对碳酸盐岩的基质矿物类型非单一且孔隙结构复杂多变的特点,提出一种适用于碳酸盐岩的流体替换方法。以常规Gassmann方程为基础,采用流体因子分析的基质矿物体积模量反演方法和碳酸盐岩岩石物理模型的孔隙结构反演方法,得到岩石基质矿物的体积模量,并考察复杂孔隙结构的影响,实现碳酸盐岩的流体替换。岩石物理测试分析数据和实际测井资料的计算结果均证明了新方法的正确性和有效性。     

正交胶合竹板单面火损后力学性能试验研究

为研究正交胶合竹板单面火损后的力学性能,通过对12块试件进行承载力试验,分析了不同火损时长、不同阻燃处理方式对正交胶合竹板炭化性能和残余承载力的影响.结果表明,相同阻燃处理方式下正交胶合竹板的炭化程度随火损时长增加而增加,残余承载力随火损时长增加而降低.当火损时长相同时,不同阻燃处理方式下正交胶合竹板的炭化速度由高到低...     

A novel method for improving cerussite sulfidization

Evaluation of flotation behavior, solution measurements, and surface analyses were performed to investigate the effects of chloride ion addition on the sulfidization of cerussite in this study. Micro-flotation tests indicate that the addition of chloride ions prior to sulfidization can significantly increase the flotation recovery of cerussite, which is attributed to the formation of more lead sulfide species on the mineral surface. Solution measurement results suggest that the addition of chloride ions prior to sulfidization induces the transformation of more sulfide ions from pulp solution onto the mineral surface by the formation of more lead sulfide species. X-ray diffraction and energy-dispersive spectroscopy indicate that more lead sulfide species form on the mineral surface when chloride ions are added prior to sulfidization. These results demonstrate that the addition of chloride ions prior to sulfidization can significantly improve the sulfidization of cerussite, thereby enhancing the flotation performance.     

承钢高炉炉缸沉积物矿相的研究

针对承钢高炉在冶炼炼钒钛矿过程中炉缸中生成大量沉积物，影响高炉顺行这一情况，对承钢高炉沉积物进行了矿物组成和矿相分析，结合承钢生产具体情况，提出减少承铜高炉炉缸沉积物的措施。     

铜铁共催化烯烃串联加成/环化合成异喹啉二酮

发展了一种铜/铁协同催化的N-烯丙酰基苯甲酰胺串联加成/环化/偶联合成叔烷基化异喹啉二酮的反应.在廉价金属Cu/Fe协同催化作用下,烷基偶氮试剂介导N-丙烯酰基-N-烷基氯代苯甲酰胺发生串联加成/环化,区域选择性地切断C-Cl键而发生进一步交叉偶联,以41%~78%的产率合成了一系列远端双重α-官能团化叔烷基取代的异喹啉二酮骨架.该反应首次利用卤代苯甲酰胺去芳构化而形成的超共轭自由基为偶联体与偶氮试剂发生交叉偶联,选择性地在碳-卤键位置构建碳（叔）-碳键.此偶联策略将为深入拓展叔烷基-芳基交叉偶联提供新的思路.     

Anthropogenic ocean acidification over the twenty-first century and its impact on calcifying organisms

Today's surface ocean is saturated with respect to calcium carbonate, but increasing atmospheric carbon dioxide concentrations are reducing ocean pH and carbonate ion concentrations, and thus the level of calcium carbonate saturation. Experimental evidence suggests that if these trends continue, key marine organisms--such as corals and some plankton--will have difficulty maintaining their external calcium carbonate skeletons. Here we use 13 models of the ocean-carbon cycle to assess calcium carbonate saturation under the IS92a 'business-as-usual' scenario for future emissions of anthropogenic carbon dioxide. In our projections, Southern Ocean surface waters will begin to become undersaturated with respect to aragonite, a metastable form of calcium carbonate, by the year 2050. By 2100, this undersaturation could extend throughout the entire Southern Ocean and into the subarctic Pacific Ocean. When live pteropods were exposed to our predicted level of undersaturation during a two-day shipboard experiment, their aragonite shells showed notable dissolution. Our findings indicate that conditions detrimental to high-latitude ecosystems could develop within decades, not centuries as suggested previously.     

自抗扰精密跟踪运动控制器的设计

为了提高非圆车削中快速伺服刀架的跟踪精度和抗干扰性,研制了一种自抗扰控制器。通过对执行机构建模分析,将模型中的非线性部分归结为系统的内扰,将加工过程中切削力干扰归结为系统外扰,设计出相应的扩张状态观测器,对系统内、外扰的总和做出实时估计和补偿。仿真实验表明,自抗扰控制性能优于传统的PID控制。通过DSP(digital signal processor)编程,将自抗扰控制器应用于非圆车削。切削加工试验结果表明,自抗扰控制具有良好的控制品质,快速伺服刀架跟踪精度控制在±5μm以内。     

面向对象语言Transframe及其环境MagicFrame

论述了目前的软件开发中存在的两个问题：①现有的高级语言对各种高级计算模型支持的不足;②快速原型开发和高质量产品开发之间的矛盾,针对上问题,设计了一种新的面向对象语言Ｔｒａｎｓｆｒａｍｅ并研制了它的开发环境ＭａｇｉｃＦｒａｍｅ．Ｔｒａｎｓｆｒａｍｅ语言具有的参数化的动态类、名的一般模型、类与函数概念的统一、成员类继承和代理等多种机制为构造各种领域模型提供了有力的支持。基于Ｔｒａｎｓｆｒａｍｅ的开发环     

一类不确定性决策问题的变权分析方法

以灰色系统理论和模糊数学为基础,探讨了多属性决策问题中所包含的不确定性可以用灰色模糊数表示的情况,提出了基于灰色模糊信息的多属性决策的概念.利用分析方法和技巧,融合变权和熵权误差分析法,构建了灰色模糊多属性决策问题的算法,直接由灰色模糊决策矩阵确定变权的基础权重和上确界,使算法在理论上更加严谨可靠,为不确定型多属性决策方法研究提供了一条新思路.给出的算例说明了算法的可行性.