Electrochemical behavior of different shelled microcapsule composite copper coatings

Copper/liquid microcapsule composite coatings with polyvinyl alcohol (PVA), gelatin or methyl cellulose (MC) as shell materials were prepared by electrodeposition. The influence of shell materials on the corrosion resistance of the composite coatings in 0.1 M H₂SO₄ was investigated by means of electrochemical techniques, scanning electron microscopy (SEM), and energy dispersion spectrometry (EDS). The results show that the participation of microcapsules can enhance the corrosion resistance of the composite coatings compared with the traditional copper layer. Based on the analysis of electrochemical test results, the release ways of microcapsules were deduced. Gelatin and MC as the shell materials of microcapsules are easy to release quickly in the composite coating. On the contrary, the releasing speed of PVA microcapsules is relatively slow due to their characteristics.     

国内外智慧城市建设关键要素及其耦合研究

基于对智慧城市体系要素的分析,建立其要素耦合的理论分析框架,并对智慧城市建设的关键要素及其耦合关系进行了检验．研究表明,智慧城市需基于自身的基础条件和发展需求进行相匹配的战略定位,并在战略的统领下,通过空间体系的优化、支撑体系的智能化、产业发展的持续化及社会自组织能力的高度化等体系要素的耦合联系和协同互动,最终实现智慧城市的发展和城市竞争力的提升．     

Zircon U-Pb geochronology of basement metamorphic rocks in the Songliao Basin

Zircon LA-ICP MS U-Pb dating of six metamorphic rocks and a metagranite (breccia) from southern basement of the Songliao Basin are reported in order to constrain the formation ages of basement. The basement metamorphic rocks in the Songliao Basin mainly consist of metagabbro (L45-1), amphibolite (SN117), metarhyolitical tuff (G190), sericite (Ser) schist (N103), chlorite (Chl) schist (T5-1), biotite (Bi)-actinolite (Act)-quartz (Q) schist (Y205), and metagranite (L44-1). The cathodoluminesence (CL) images of the zircons from metagabbro (L45-1) and metagranite (L44-1) indicate that they have cores of magmatic origin and rims of metamorphic overgrowths. Their U-Pb isotopic ages are 1808±21 Ma and 1873±13 Ma, respectively. The zircons with oscillatory zoning from amphibolite (SN117) and Chl schist (T5-1), being similar to those of mafic igneous rocks, yield ages of 274 ± 3.4 Ma and 264 ± 3.2 Ma, re-spectively. The zircons from metarhyolitical tuff (G190) and Ser schist (N103) display typical magmatic growth zoning and yield ages of 424 ± 4.5 Ma and 287 ± 5.1Ma, respectively. Most of zircons from Bi-Act-Q schist (Y205) are round in shape and different in absorption degree in the CL images, implying their sedimentary detritals. U-Pb dating yield concordant ages of 427 ± 3.1Ma, 455 ± 12 Ma, 696 ± 13 Ma, 1384±62 Ma, 1649±36 Ma, 1778±18 Ma, 2450±9 Ma, 2579±10 Ma, 2793±4 Ma and 2953±14 Ma. The above-mentioned results indicate that the Precambrian crystalline basement (1808―1873 Ma) exists in the southern Songliao Basin and could be related to tectonic thrust, and that the Early Paleozoic (424―490 Ma) and Late Paleozoic magmatisms (264―292 Ma) also occur in the basin basement, which are consistent with the ages of the detrital zircons from Bi-Act-Q schist in the basement.     

Vanadyl ions binding to GroEL （HSP60） and inducing its depolymerization

Several vanadium compounds have been known for the hypoglycemic and anticancer effects. However, the mechanisms of the pharmacological and toxicological effects were not clear. In this work, we in- vestigated the potential targets of vanadium in mitochondria. Vanadyl ions were found to bind to mi- tochondria from rat liver with a stoichiometry of 244±58 nmol/mg protein and an apparent dissocia- tion constant (Kd) of (2.0±0.8)×10·16 mol/L. Using size exclusion chromatography, a vanadium-binding protein was isolated and identified to be the 60-kDa heat shock protein (HSP60) by mass spectrometry analysis and immunoassays. Additionally, binding of vanadyl ions was found to result in depolymeri- zation of homo-oligomeric HSP60 (GroEL). HSP60 is an indispensable molecular chaperone and in- volved in many kinds of pathogenesis of inflammatory and autoimmune diseases, e.g. type 1 diabetes. Our results suggested that HSP60 could be a novel important target involved in the biological and/or toxicological effects of vanadium compounds.     

需求侧全球碳排放强度的度量及分解

利用非竞争型投入产出表提出了需求侧的全球完全碳排放强度度量方法,建立了经济体维度和最终需求类型维度变化的贡献率分解模型,以及包含碳排放系数、中间投入技术结构、增加值系数和最终需求4类影响因素的结构分解模型,分析了1998-2007年全球主要经济体和代表性国家的碳排放强度变化.结果表明:全球完全碳排放重心向发展中国家转移,完全增加值重心在发达国家,完全碳排放强度下降主要贡献仍来自欧盟和北美自贸区.各国消费的完全碳排放强度均小于出口和投资的完全碳排放强度,并带动了整体完全碳排放强度的下降。碳排放系数仍是促进需求侧碳排放强度下降的主导因素,其他3类因素对不同国别不同类型的完全碳排放强度影响效果不一,其中在出口的完全碳排放强度中表现出更为显著的国别差异.     

储层含油性识别中ANN和GA融合的模糊规则提取

提出一种基于ANN和GA融合的自学习自适应的模糊规则提取算法,用来对油层进行识别.其方法是:首先运用人工神经网络(ANN)对训练样本进行有导师学习,网络的输入是测井属性,输出表达为网络权值和输入的函数Ψk=f(xi(WG1)ij,(WG2)jk)(其中:Ψk代表含油性类别Ck的判别函数;C1为干层;C2为水层;C3为差油层;C4为油层).然后,以Ψk作为遗传算法(GA)中的适应度函数提取对应于类别Ck的模糊规则.最后,通过某油田oilsk81和oilsk83油井的实证研究表明,该方法能够有效地识别储层的含油性.     

电荷掺杂和C1掺杂聚吡咯、聚呋喃、聚噻吩的导电性理论研究

利用Gaussian 03程序包中的密度泛函理论在B3LYP/6-31G(d)水平下,对未掺杂、电荷掺杂和C1掺杂的聚吡咯、聚呋喃、聚噻吩进行几何全优化,并对它们的几何结构、自旋密度、自然键轨道(NBO)、前线轨道能进行了理论分析.结果表明,电荷掺杂能使聚合物键长趋于平均化,其极子分布几乎遍及了整个分子链而C1原子掺杂对聚合物的影响主要集中在与C1原子相邻的C原子上,极子分布局域在C1原子附近的大约7个碳原子上,掺杂能够明显增强仃电子共轭性,降低能隙,从而增强导电性.     

润叶加料工序料液有效利用率的计算方法

为在生产过程中实现对料液有效利用率进行在线监测,把握料液有效利用率的实际情况,寻找提高料液有效利用率的方法,通过对润叶加料入口物料状态、料罐料液状态及润叶加料出口物料状态进行研究,分析出口流量、流量稳定时间、料液实际质量、加料前物料质量、含水率以及生产时间的关系,建立了润叶加料料液有效利用率的计算方法,并将该方法计算得到的有效利用率与1, 2–丙二醇作为标记物的方法进行F检验。结果表明:料液有效利用率的计算值与测量值之间差异无统计学意义(P>0.05),计算结果可代表实测值。该方法可应用于料液有效利用率的在线监测,为润叶加料工序的工艺优化,设备缺陷改进,过程料液吸收情况等提供数据支持。     

基于剔除拟合的股骨头修复建模

提出了一种可以获得目标病例健康时股骨头模型的新建模方法.通过CT扫描获得髋骨部位的序列断层图像,利用一种精确的自动分割方法提取图像中的髋臼轮廓.针对髋臼的特殊结构,使用辐条式采样法得到髋臼凹面的空间坐标点集.剔除坐标点集中的误差采样点.采用闭合形式解的最小二乘法拟合原始股骨头球面模型.通过对2例不同坏死程度的男性患者进行修复实验,证明此方法可以良好地还原坏死的股骨头模型,既为骨科临床中的精确手术定位提供了理论模型,又为针对个体化制造的人工假体生产提供了新的实践方法.     

OFDM系统LS信道估计中的最优导频设计

针对设置有保护频带的OFDM系统,基于等间隔导频(UPPTS)设计方法,在保证最小二乘(LS)信道估计均方误差(MSE)最小的前提下,计算了系统允许存在的最大保护频带宽度,给出了初始导频位置的选择范围,通过调整导频序列的初始位置,使导频序列有效避开保护频带.仿真实验结果表明,当导频序列的初始导频落入本文所给出的导频位置选择范围之内时,系统给出了更高的信道估计精度和更低的误码率,进一步验证了算法的有效性和优越性.