Cobalt doped titanate nanotubes: Synthesis and properties

Cobalt oxide doped titanate nanotubes are synthesized with a simple hydrothermal treatment of mixed Co_3O_4 and TiO_2 powders. The formed tubular nanostructure, chemical composition,and the elemental distribution are analyzed using TEM, BET, FTIR, XRD, and XPS. The electrocatalytic activity towards oxygen evolution reactions and photodegradation against Rhodamine B are investigated. It has been found out that the oxygen evolutions starts at 0.8 V and reaches 0.98 mA ·cm~(–1) at 1.4 V vs. SCE. For photodegradation of Rhodamine B, the concentration decreased to 24% after 1 h irradiation using the sample with a mass percentage of 5% cobalt. The results demonstrate that the cobalt oxide doped titanate nanotubes are good candidates as electrocatalysts and photocatalytic materials.     

基于微博文本的个性化兴趣关注点及情绪变迁趋势研究

随着社交网络的快速发展,人们可利用微博平台发表、分享自己的观点以及抒发某种情绪,进而产生了大量针对不同话题的博文和情绪信息,但传统的文本挖掘算法在处理这些短小且具富含个性化情感信息的微博文本方面有所欠缺。在此提出一种基于微博文本的特征权重计算方法,可据此得到博主在不同时间段的关注点,通过情绪分类,分析用户在不同时间段内的情绪变迁情况。实验结果证明此方法具有一定的可行性。     

基于GEO-SLOPE软件的煤矿密集区典型危岩形成机理分析

贵州省凯里市龙场镇渔洞村岔河组老山新村同一位置先后2次发生崩塌灾害,崩塌堆积体灾害导致5人死亡,掩埋6栋房屋,转移安置21户79人。本文针对其高陡斜坡为缓倾坡内上硬下软型,下卧软层薄,采空区距离陡崖面较远的具体特征,通过geo-slope分析软件,结合现场测绘实际情况,建立地质模型并对其进行数值模拟分析,分析其形成机理。     

基于生成对抗网络的无载体信息隐藏

提出了一种基于生成对抗网络的无载体信息隐藏方法.发送方用伪装图像和Improved Wasserstein GAN生成一张与秘密图像相同的图像,发送方发送伪装图像,接收方收到伪装图像后用生成器生成和秘密图像视觉上相同的图像.与现有的信息隐藏方法相比,该方法不需要修改载体,能够有效地抵抗隐写分析工具的检测,能够达到秘密信息安全传输的目的.     

竞争环境下ODM厂商自有品牌的市场进入策略分析

在经济全球化背景下,越来越多的原始设备制造商(original equipment manufacturer, OEM)开始考虑创建自有品牌以实现向原始设计制造商(original design manufacturer, ODM)部分角色的转变.显然,ODM是否创建自有品牌进入市场会对相关企业及供应链产生重要影响.本文针对ODM与OEM构成的二级供应链系统,在不同博弈理论框架下分析了ODM自有品牌的市场进入策略及对OEM和供应链系统的影响.研究表明ODM的市场进入能有效缓解供应链的双重边际效应,但该效应会随着OEM渠道成本优势的扩大而减弱.而当OEM的渠道成本足够低时,ODM的市场进入可能对OEM也是有利的,此时ODM与OEM可实现"双赢".最后,将模型拓展至Nash讨价还价和Bertrand价格竞争情形,分析并验证了结论的鲁棒性.     

以木聚糖为抗菌剂的木质地板抗菌性能

随着生活水平的提高,人们越来越重视室内家居环境的健康、环保问题.因此,研究、开发抗菌实木地板具有现实意义.采用贴膜法检测抗菌地板的抗菌性能:以木聚糖为抗菌剂,用8%浓度溶液浸泡杨木单板,接种一定数量的大肠杆菌和金色葡萄球菌.经过一段时间培养后,检测地板细菌数量.结果表明:经过木聚糖溶液处理的地板对大肠杆菌和金色葡萄球菌的抗菌率为73.58%和90.09%,抗菌等级达到Ⅱ级.     

In situ backscattered electron imaging study of the effect of annealing on the deformation behaviors of Ni electroformed from additive-free and saccharin-containing sulfamate solutions

The Ni samples were electroformed from additive-free(AF) and saccharin-containing(SC) sulfamate solutions, respectively. In situ backscattered electron(BSE) imaging, electron backscatter diffraction(EBSD), and electron-probe microanalysis(EPMA) were used to investigate the effect of annealing on the deformation behaviors of the AF and SC samples. The results indicate that columnar grains of the as-deposited AF sample had an approximated average width of 3 μm and an approximated aspect ratio of 8. The average width of columnar grains of the as-deposited SC sample was reduced to approximately 400 nm by the addition of saccharin to the electrolyte. A few very-large grains distributed in the matrix of the SC sample after annealing. No direct evidence indicated that S segregated at the grain boundaries before or after annealing. The average value of the total elongations of the SC samples decreased from 16% to 6% after annealing, whereas that of the AF samples increased from 18% to 50%. The dislocation recovery in grain-boundary areas of the annealed AF sample was reduced, which contributed to the appearance of microvoids at the triple junctions. The incompatibility deformation between very-large grains and fine grains contributed to the brittle fracture behavior of the annealed SC Ni.     

Facile synthesis of flake-like dihydrate zinc oxalate particles

Monodispersed dihydrated zinc oxalate(ZnC_2O_4·2H_2O) particles with characteristic morphology were synthesized by aging a mixed solution of zinc nitrate(Zn(NO_3)_2) and sodium oxalate(Na_2C_2O_4) in the presence of a citrate ligand, with an average flat size of approximately 10–15 μm. The important parameters, including the solution pH values and the concentration of the zinc ions and citrate ligand, were investigated using a series of experiments. It is verified that the citrate ligand significantly affects the morphology of zinc oxalate particles, probably via its multiple roles of chelating, dispersing, and selective absorption. Thermodynamic equilibrium of the distribution of zinc species in an aqueous solution of Zn(Ⅱ)-citrate-oxalate-H_2O was estimated to explain the experimental results and to clarify the size and morphological evolution mechanism of the precipitated particles.