Complementation in the composition of steel slag and red mud for preparation of novel ceramics

A method for preparing novel ceramics was developed in this study. Different ratios red muds were added to steel slags to optimize the preparation of novel ceramics by a traditional ceramic preparation process. The sintering mechanism, microstructure, and performance were studied by X-ray diffraction techniques, scanning electron microscopy, and combined experiments of linear shrinkage, water absorption, and flexural strength. The results confirmed that red mud can reduce the volumetric instabilities through the complementarity of red mud and ferroalloy slag. The crystal phases in the ceramics are all pyroxene group minerals, including diopside ferrian, augite, and diopside. The flexural strength of the ceramic that contains 40wt% red mud and was prepared at the optimal sintering temperature (1140℃) is greater than 93 MPa; its corresponding water absorption is less than 0.05%.     

Leaching behavior of V,Pb, Cd,Cr, and As from stone coal waste rock with different particle sizes

This paper investigates the leaching behavior of heavy metals (V, Pb, Cd, Cr, and As) from stone coal waste rocks with various particle sizes using dynamic leaching experiments. The results show that the dissolved concentrations of V and As initially increased and then slightly decreased as time progressed and that the dissolved concentrations of Pb, Cd, and Cr were high in the early stage before decreasing. The particle size of the stone coal waste rocks strongly influenced the heavy metal concentration in the leaching solutions. The effects of the particle size of the stone coal waste rocks on the dissolved concentrations of V, Pb, and As decreased in the order fine fraction > medium fraction > coarse fraction, and the effects of particle size on the dissolved concentrations of Cr and Cd decreased in the order medium fraction > coarse fraction > fine fraction and coarse fraction > medium fraction > fine fraction, respectively. The quantities of heavy metals dissolved from the stone coal waste rock with fine particle sizes were observed to decrease in the order V (17104.36 μg/kg) > As (609.41 μg/kg) > Pb (469.24 μg/kg) > Cr (56.35 μg/kg) > Cd (27.52 μg/kg), and the dissolution rates decreased in the order As (2.96%) > Pb (0.93%) > V (0.35%) > Cd (0.25%) > Cr (0.01%). The specific surface area, pore size of the stone coal waste rocks, and chemical forms of heavy metals also influenced the release of heavy metals from the stone coal waste rocks. Kinetic analysis showed that the dissolution of heavy metals fundamentally agreed with the rate equation controlled by the shrinking core model. The results of this study are expected to serve as a reference for the evaluation of heavy metals contamination from stone coal waste rocks.     

Microstructural characterization and oxidation resistance of multicomponent equiatomic CoCrCuFeNi-TiO high-entropy alloy

CoCrCuFeNi-TiO was prepared by arc melting of the pure elements and Ti₂CO powder under an Ar atmosphere. Both CoCrCuFeNi and CoCrCuFeNi-TiO alloys are composed of a face-centered cubic (fcc) solid solution, whereas the alloys of CoCrCuFeNi-TiO are basically composed of an fcc solid solution and TiO crystals. The microstructures of CoCrCuFeNi-TiO are identified as dendrite and interdendrite structures such as CoCrCuFeNi. The morphology of TiO is identified as an equiaxed crystal with a small amount of added Ti₂CO. By increasing the amount of Ti₂CO added, the TiO content was dramatically increased and part of the equiaxed crystals changed to a dendrite structure. A test of the oxidation resistance demonstrates that the oxidation resistance of CoCrCuFeNi-TiO is better than that of CoCrCuFeNi. However, as the TiO content increases further, a corresponding decrease is observed in the oxidation resistance.     

Effect of melting temperature on microstructural evolutions,behavior and corrosion morphology of Hadfield austenitic manganese steel in the casting process

In this study, the effect of melting temperature on the microstructural evolutions, behavior, and corrosion morphology of Hadfield steel in the casting process is investigated. The mold was prepared by the sodium silicate/CO₂ method, using a blind riser, and then the desired molten steel was obtained using a coreless induction furnace. The casting was performed at melting temperatures of 1350, 1400, 1450, and 1500℃, and the cast blocks were immediately quenched in water. Optical microscopy was used to analyze the microstructure, and scanning electron microscopy (SEM) and X-ray diffractrometry (XRD) were used to analyze the corrosion morphology and phase formation in the microstructure, respectively. The corrosion behavior of the samples was analyzed using a potentiodynamic polarization test and electrochemical impedance spectroscopy (EIS) in 3.5wt% NaCl. The optical microscopy observations and XRD patterns show that the increase in melting temperature led to a decrease of carbides and an increase in the austenite grain size in the Hadfield steel microstructure. The corrosion tests results show that with increasing melting temperature in the casting process, Hadfield steel shows a higher corrosion resistance. The SEM images of the corrosion morphologies show that the reduction of melting temperature in the Hadfield steel casting process induced micro-galvanic corrosion conditions.     

Mineral-phase evolution and sintering behavior of MO-SiO2-Al2O3-B2O3 (M=Ca,Ba) glass-ceramics by low-temperature liquid-phase sintering

In this work, network former SiO₂ and network intermediate Al₂O₃ were introduced into typical low-melting binary compositions CaO·B₂O₃, CaO·2B₂O₃, and BaO·B₂O₃ via an aqueous solid-state suspension milling route. Accordingly, multiple-phase aluminosilicate glass-ceramics were directly obtained via liquid-phase sintering at temperatures below 950℃. On the basis of liquid-phase sintering theory, mineral-phase evolutions and glass-phase formations were systematically investigated in a wide MO-SiO₂-Al₂O₃-B₂O₃ (M=Ca, Ba) composition range. The results indicate that major mineral phases of the aluminosilicate glass-ceramics are Al₂₀B₄O₃₆, CaAl₂Si₂O₈, and BaAl₂Si₂O₈ and that the glass-ceramic materials are characterized by dense microstructures and excellent dielectric properties.     

基于免疫网络理论的永磁同步电机控制

摘 要：PID控制器有着广泛的应用,其参数也有多种智能调整方法。本文分析了免疫系统的免疫网络理论,提出了一种用免疫网络理论调整PI控制器的策略,并用于永磁同步电机的直接转矩控制的调速系统,以克服电阻变化引起磁链控制器输出不准确,影响控制精度的问题。该策略计算简单,在永磁同步电机定子电阻变化较大情况下,仍具有高控制精度。仿真结果验证了这一免疫网络理论控制策略的有效性,并与一般PI控制和采用遗传算法的PI控制的效果进行了比较。     

超高性能混凝土板加固足尺钢筋混凝土梁抗剪性能

为进一步研究超高性能混凝土(ultra-high-performance concrete, UHPC)预制板加固钢筋混凝土(reinforced concrete, RC)梁的抗剪性能,开展了3根足尺RC梁的试验研究,包含1根对比梁和2根UHPC预制板加固梁,关注UHPC板及其内嵌CFRP板条对RC梁抗剪性能的影响。试验结果表明：试验梁均发生受剪破坏,但加固梁的承载力、刚度和延性均明显提高,其中,因内嵌CFRP板条提高了UHPC板的抗裂性能,极限荷载及对应位移分别提高了30.8%和28.5%;螺杆力学锚固发挥了侧向约束作用和销栓作用,在一定程度上提高了UHPC板的贡献。同时,通过建立非线性有限元模型对试验梁进行了数值分析,模拟结果与试验结果吻合度高,表明模型所选的本构关系及相关参数合理,可用于预测UHPC板加固RC梁的全过程受力行为。     

水平电偶源频率域电磁测深全区视电阻率的直接算法

利用水平电偶源激发的电磁场，提出了直接精确计算全区视电阻率的方法．计算和分析结果表明，该方法的结果在远区等价于卡尼亚电阻率，在近区和过渡带则明显地改善了卡尼亚电阻率的非波区场畸变，从而能更好地接近基底的真电阻率，更形象地反映了地下介质的垂向电性变化．     

输气管道的蒸气云爆炸灾害的风险分析

重点分析了输气管道的蒸气云爆炸灾害的发生条件、爆炸机理和危害。采用TNT当量法和复合能量法对蒸气云爆炸造成人员伤害和财产破坏的后果进行了计算，通过计算可以预测蒸气云爆炸灾害发生时，任意点处的风险后果，以便采取必要的防范措施。     

40-Gb/s all-optical digital 4-bit priority encoder employing cross-gain modulation in semiconductor optical amplifiers

High-speed all-optical logic circuits have attracted much attention because of their important roles in signal processing in next-generation optical networks.The digital encoder is widely used in binary calculation,multiplexing,demultiplexing,address recognition and data encryption.A priority encoder allows the existence of multiple valid inputs simultaneously,identifies the priority of the request signals and encodes the priority.We propose and experimentally demonstrate an all-optical 4-bit priority encoder for return-to-zero signals at 40 Gbit/s based on cross-gain modulation in semiconductor optical amplifiers.Detuning fil-ters after semiconductor optical amplifiers are employed to improve the output performance.Correct logic bit sequences and clear open eye patterns with extinction ratios exceeding 10 dB are achieved.