钢渣中游离氧化钙和氧化镁碳酸化反应

在CO2含量为99.9%,压力为0.2 MPa条件下,对钢渣粉进行碳酸化处理,并作为水泥混合材料制成净浆试件,对试件进行压蒸,研究碳酸化反应时间对试件体积安定性的影响．结果表明,随着碳酸化反应时间的延长,钢渣中的硅酸盐、游离CaO、Ca(OH)2和游离MgO等物质与CO2气体进行反应,主要生成CaxMg1-xCO3．掺加未经碳酸化处理钢渣的试件,压蒸后破坏严重;掺加碳酸化反应10 min钢渣的试件膨胀率为1.03%,试件有明显裂纹;掺加碳酸化反应20 min钢渣的试件膨胀率为0.29%,符合国家标准,体积安定性合格．碳酸化处理20 min后,钢渣中游离CaO含量由2.54%降至0.84%,游离MgO含量由3.8%降至2.4%,试块压蒸后未出现Mg(OH)2,镁离子以水化硅酸镁形式存在于无定形物中．     

高速大功率车用永磁同步电机电磁诱发转子横向振动特性

高速大功率车用永磁同步电机的转子轴系是一个涉及电磁、机械高度耦合的非线性系统,因此转子动力学性能是高速车用永磁同步电机设计必须关注的问题.建立了电机中由于转子偏心引起的电磁激励解析模型,以转子动力学和非线性动力学为基础,建立永磁电动机转子系统的非线性模型,用解析法计算得到转子横向振动的幅频特性,结果表明转子横向振动具有负刚度和失稳幅值跳跃现象.最后通过数值计算对等效解析计算的结果进行了验证.     

宽裕润滑参数下滚动轴承润滑特性研究

滚动轴承是精密机床、特种车辆等重大装备的关键支撑零部件,其润滑性能直接决定了轴承的稳定服役性能,进而影响到重大装备的工作性能指标.基于理论仿真及实验研究,开展了油气润滑滚动轴承宽域润滑参数下的运行特性研究.结合多相流动分析技术,研究了高速角接触球轴承内部油气的流动状态,揭示了轴承内部油气流动基本规律.在此基础上,设计了滚动轴承润滑性能试验验证平台,实验分析了不同润滑参数对轴承温度的影响规律,获取了特定转速下温升最小的轴承润滑参数,证实了滚动轴承不同润滑参数对其服役性能的影响程度.研究工作对于滚动轴承宽域润滑状态下的服役性能分析提供基础依据.     

Nanoindentation response analysis of TiN-Cu coating deposited by magnetron sputtering

To investigate the change of the mechanical properties of soft metals doped PVD(Physical Vapor Deposition)coatings after the migration of soft metal to the surface, TiN-Cu coating was deposited on Si(100) by magnetron sputtering. The microstructure and mechanical properties at room temperature and after vacuum heat treatment at 300 ℃ were investigated. The results showed that the grains were clustered and the microstructure was porous for TiN-Cu coating at room temperature, while many micro-and nano-sized Cu particles were observed on the surface after vacuum heat treatment at 300 ℃. The elastic properties of the TiN-Cu coating after vacuum heat treatment at 300℃ degraded compared with that at room temperature. The hardness and elasticity modulus of TiN-Cu coating kept constant(3.7 GPa and 125.0 GPa, respectively) with the increase of nano-indentation depth, while the hardness and elasticity modulus of TiN-Cu coating after vacuum heat treatment at 300 ℃ increased gradually.     

Study on the hydrogen storage property of (TiZr0.1)xCr1.7-yFeyMn0.3 (1.05

Jigang Li  Li Xu  Xiaojing Jiang  Xingguo Li 《自然科学进展(英文版)》2018,28(4):470-477

Novel multiferroicity in orthorhombic SmCrO3

This paper reports the ferroelectricity in antiferromagnetic SmCrO_3 with a reasonably large value of spontaneous electric polarization(70μC/cm~2mC cm~(-2)at 50 K)based on the measurement of pyroelectric current.The experimental results showed that the temperature of the onset of polar order was evidently higher(about220 K)than the Neel temperature(T_N=197 K)in the magnetodielectric studies.The calculated magnetodielectric effect(MDE)value was explicitly negative with maximum|MDE|values of about 3.6%around 230 K.The absence of a convincing signature in MDE at antiferromagnetic ordering temperature T_Nindicated the absence of magnetoelectric coupling around this temperature regime.The results further confirmed that the onset of polar order can be attributed to the structural distortion,rather than the canted noncollinear magnetic structure.     

Effect of cold rolling process on microstructure and mechanical properties of high strength β titanium alloy thin sheets

The microstructure and mechanical properties of Ti-3.5Al-5Mo-6V-3Cr-2Sn-0.5Fe high strength titanium alloy sheets prepared by unidirectional cold rolling and two-step cross cold rolling were investigated. Results showed that the β phase grains were refined significantly by cold rolling followed by solution treatment for a short time.Compared to unidirectional cold rolling, the short time solution treatment after two-step cross rolling could significantly reduce the non-uniformity of the microstructure of the alloy sheets. After aging treatment at 550 ℃,the anisotropy of the mechanical properties still existed in the unidirectional rolled sheets, and the tensile strength was highest along the rolling direction. After solution and aging treatment, the anisotropy of the mechanical properties of the two-step cross rolling process sheet was not obvious than unidirectional cold rolling,and alloy had good strength and plasticity matching.     

呼叫中心人力资源配置鲁棒规划模型

针对现实呼叫中心中顾客到达不确定的问题,建立了基于排队论的离散流体模型,解决了考虑鲁棒性呼叫中心的人力资源配置问题.通过区间数据来表示顾客到达的不确定集,利用可调整鲁棒优化方法的思想,分析了鲁棒优化模型与确定性优化模型的关系.数值试验表明,使用可调整鲁棒参数的鲁棒优化方法减小了呼叫中心到达率不确定性给呼叫中心系统带来的影响;到达率越大,对应的最优的鲁棒参数越大,模型越保守.     

基于碳量子点的TiO2改性及降解污染物性能

采用溶胶-凝胶法合成掺入碳量子点(CQDs)的TiO₂纳米复合光催化剂,通过荧光光谱、紫外-可见吸收光谱、X射线衍射、扫描电镜等进行表征,并在可见光下降解亚甲基蓝(MB)染料溶液以评价其光催化性能.研究表明,CQDs具备上转换荧光特性,掺入CQDs的TiO₂样品可见光响应明显提升.水热法180℃下反应6h制备的CQDs,其溶液加入量为10mL时TiO₂/CQDs样品光催化活性最高,115min后MB的降解率达80%.TiO₂/CQDs样品主要以锐钛矿相存在,颗粒呈球形,比表面积高达200m³·g^-1.     

制造商资金约束下的双渠道供应链协调

考虑由单一零售商和受资金约束的单一制造商组成的双渠道供应链,在引入带有价格折扣因子的零售商提前付款融资模式时,如何实现协调的问题.在制造商主导的Stackelberg博弈下,研究了制造商和零售商之间的库存协调问题,并建立了使得双渠道供应链实现协调的收入共享契约模型.给出了供应链协调时契约参数满足的表达式,并分析了价格折扣因子、初始资金对供应链及其成员的影响.最后,通过算例验证了契约对双渠道供应链协调的有效性及相关参数的作用.