Simultaneous mineralization of CO2 and recovery of soluble potassium using earth-abundant potassium feldspar

CO2 capture and storage(CCS) is an important strategy in combatting anthropogenic climate change.However,commercial application of the CCS technique is currently hampered by its high energy expenditure and costs.To overcome this issue,CO2 capture and utilization(CCU) is a promising CO2 disposal method.We,for the first time,developed a promising method to mineralize CO2 using earth-abundant potassium feldspar in order to effectively reduce CO2 emissions.Our experiments demonstrate that,after adding calcium chloride hexahydrate as an additive,the K-feldspar can be transformed to Ca-silicates at 800 C,which can easily mineralize CO2 to form stable calcium carbonate and recover soluble potassium.The conversion of this process reached 84.7%.With further study,the pretreatment temperature can be reduced to 250 C using hydrothermal method by adding the solution of triethanolamine(TEA).The highest conversion can be reached 40.1%.The process of simultaneous mineralization of CO2 and recovery of soluble potassium can be easily implemented in practice and may provide an economically feasible way to tackle global anthropogenic climate change.     

高校辅导员要注重人文关怀

高校辅导员作为高校一线学生管理人员，注重人文关怀是做好工作的有效途径．人文关怀也成为高校实施有效管理的新理念．应用好这一新理念，对高校思想政治工作的顺利开展，促进大学生健康全面的成长有着重要的作用．     

民族教育资源本体构建方法及应用

在分析本体构建方法的基础上，利用软件工程思想，提出了一种民族教育资源本体构建方法，并以傣族教育资源本体构建及实现为例，详细阐述了傣族教育资源概念的获取、层次结构的划分、概念的属性和关系的确定以及实例的创建，最后基于Protege实现了该本体。     

单分散寡聚乙二醇的合成与表征

寡聚乙二醇由于其独特的结构灵活性、化学稳定性、水溶性、无毒和生物兼容性,作为合成模块化合物被广泛使用.以简单的商业低聚乙二醇为原料,采用威廉姆森醚合成法,通过4步反应合成了具有不同链长的单分散五聚、六聚和七聚乙二醇,并通过1H NMR和13C NMR对其进行了表征.该方法原料廉价易得,操作简单,收率高,纯度好,并可进行大量合成.     

关于Endocrine Disruptors的译名

一、Endocrine Disruptors一词的由来 科学家发现某些化学物质能够干扰人体和野生动物内分泌功能的研究始于20世纪60年代,在1962年出版的<寂静的春天>(Si-lent Spring)一书中正式提出了农药可能引起内分泌紊乱的观点,1968年发现农药DDT对哺乳动物和鸟类产生雌性化影响.进一步的研究发现这些化合物产生的负面影响非常严重,如导致生物体生殖功能和免疫力下降,诱发肿瘤,损害神经系统,出现行为异常等.人们把这些化学物质称为"endocrine disruptors"(缩写为Eds),也就是我们通常所翻译的"内分泌干扰物(质)"或者"内分泌干扰剂"、"内分泌干扰素".     

聚硫聚氨酯的合成及其热力学性能

以聚硫橡胶(PS)、聚四氢呋喃(PTMG)、二苯基甲烷二异氰酸酯(DPMDI)为原料,制备聚硫聚氨酯(PS/PU)复合材料。研究了G4、G112、G21C不同型号聚硫橡胶及其质量分数对聚硫聚氨酯复合材料结构和热力学性能的影响,进行了红外分析、差示扫描热分析(DSC),通过TGA确立了热降解活化能。结果表明:G4和G21C型聚硫橡胶改性的聚氨酯具有更好的热稳定性能,其降解活化能可达171.36kJ/mol。     

QGrid:一种空间移动对象并行索引结构

为提高空间移动对象数据更新效率和查询准确率,提出了一种空间移动对象并行索引结构.利用主索引和辅助索引支持对空间对象进行基于范围的查询和基于对象标识的查询,还通过查询索引将更新操作和可能受其影响的查询操作相连接,在满足并行操作时间片语义的同时,避免了传统方法进行范围查询时对查询范围内相关对象及相关索引结构全部进行锁定的需求.实验结果表明:高负载环境下,该索引结构不但能保证查询准确率,其处理能力也明显优于传统索引结构.该索引通过提高系统并行度,使同一范围内的更新和查询操作可以并行执行,提升了系统整体运行效率.     

车削颤振稳定性预测软件研究与开发

针对金属加工过程中颤振预测软件实现的工程需求,设计了车削加工颤振稳定性叶瓣图实验测试软硬件系统,研究了软件实现算法中的关键问题.首先,搭建了由采集卡、加速度传感器、模态力锤组成的硬件系统,开发了具有频响函数测试和稳定性叶瓣图生成功能的系统软件.其次,设计了交互式软件采集及分析界面,研究了基于C#编程语言频响函数测试过程中多通道高速同步触发采集的实现算法,开发了具有由频域分析方法获得颤振稳定性叶瓣图功能的C#类.最后,对CJ0625车床加工系统进行稳定性预测,结果表明软件预测结果与实验结果相吻合.     

Atomic layer deposition on Pd nanocrystals for forming Pd-TiO2 interface toward enhanced CO oxidation

Pd typically exhibits relatively low catalytic activity in CO oxidation, as CO is apt to be adsorbed on Pd to poison the surface for O2 activation. In this Letter, we report that this limitation can be overcome by integrating Pd with TiO2. The TiO2 was coated on Pd nanocubes with a controllable thickness using atomic layer deposition (ALD) method. Given the different work functions of TiO2 and Pd, the electrons in TiO2 semiconductor will flow toward Pd. With the electron density increased on Pd, the adsorption of CO to Pd will be weakened while the oxygen activation can be facilitated. Meanwhile, the interface-confined sites at Pd-TiO2 may further enhance the oxygen activation. As the species adsorption and activation are strongly correlated with electron density, the performance of Pd-TiO2 in CO oxidation turns out to depend on the TiO2 thickness, which determines the number of transferred electrons, within a certain range (<1.8 nm). This work provides a new strategy for enhancing catalytic performance through tailoring charge densities in hybrid catalysts.     

Influences of ultrasonic irradiation on the morphology and structure of nanoporous Co nanoparticles during chemical dealloying

The Co-61.8 wt% Al nanoparticles of 45 nm were prepared by hydrogen plasma-metal reaction (HPMR) method. The nanoparticles display core shell structure with Al13Co4 and CoAl core and aluminum oxide shell (about 2 nm). Under ultrasonic irradiation, nanoporous fcc-Co nanoparticles were produced successfully by chemically dealloying the Co-Al nanoparticles at room temperature, whereas, without ultrasonic irradiation CoAl phase could hardly react with sodium hydroxide solution. At 323 K the Co-Al nanoparticles could be dealloyed to fcc-Co and hcp-Co phases even without ultrasonic irradiation. The surface area of the dealloyed nanoparticles under ultrasonic irradiation was larger than that of the dealloyed sample without ultrasonic irradiation at the same temperature. It is believed that the microjet and shock-wave induced by ultrasonic irradiation give rise to particles size reduction, interparticle collision and surface cleaning, and accelerate the dealloying process and the phase transformation.