氢型丝光沸石催化剂上的烷基芳烃同时转化反应

用脉冲气相色谱法研究了烷基芳烃的转化反应。发观以浙江缙云产的丝光沸石作成氢型丝光沸石催化剂时,只能活性较低发生二甲苯异构化反应。合成的氢型丝光沸石催化剂可以同时催化甲苯歧化和二甲苯异构化反应。当间二甲苯溶液浓度为17.7摩尔％时,苯的收率下降不大,而邻、对位二甲苯收率明显地提高。实验结果可由氢型丝光沸石催化剂的酸强度、酸量、酸中心类型以及沸石晶体孔结构的空间效应与反应机理予以说明。     

Sample maturation calculated using Raman spectroscopic parameters for solid organics: Methodology and geological applications

The shape and shift of Raman peak of solid organics prove to be capable of revealing atomic and molecular level vibration information of aromatic ring structure and its relationship with sample maturation. Raman "D" peaks and "G" peaks of a series of continuously maturated coal samples were measured, and the inter-peak intervals (G-D) and peak height ratios (Dh/Gh) were derived and correlated with the vitrinite reflectance (vRo%) of standard coal samples. As a result, two formulae were established by using the two Raman indices for calculation of Raman reflectance (RmcRo%), which is equivalent to vitrinite reflectance. The formula for calculating Raman reflectance indicative of organic maturation using Raman shift inter-peak interval (G-D) is RmcRo%=0.0537d(G-D)-11.21, which is mainly applicable to matured to highly matured carbonized samples of solid organics; The formula for calculating Raman reflectance indicative of organic maturation using Raman peak height ratio (Dh/Gh) is RmcRo%=1.1659h (Dh/Gh)+2.7588, which is mainly applicable to carbonized samples of solid organics that are over matured or going to be turned into granulated graphite. Preliminary applications indicate that Raman reflectance "RmcRo%" calculated based on results of Raman spectral analysis of solid organics can be used to characterize sample maturation at molecular level, so enjoying extensive prospects in geological applications.     

一种紊流油膜雾化燃烧系统的试验研究

利用螺旋进气道和非圆形燃烧室相配合，形成进气涡流，挤流，紊流及微波流等多种流动状态，实现以空间雾化为主，油膜蒸发燃烧为辅的燃烧过程，取得了提高功率，降低燃油消耗率，减小最高燃烧压力和压升率及改善ＮＯｘ排放的效果。     

矿焦混装对软熔带透气性影响的研究

用熔滴实验装置研究了矿、焦层装及混装时矿石软熔层的透气性,发现混装时软熔层的透气性获得大幅度改善。获得改善的原因在于混装时软溶层的结构发生了质的变化。     

关于Green定理的向量形式

通过引入梯度、旋度和散度,得到Green定理的向量形式.     

功能梯度复合靶冲击毁伤研究进展

综述了以金属复合靶板、陶瓷/金属复合靶板为代表的功能梯度复合靶在弹丸撞击作用下的抗侵彻性能、破坏模式和毁伤机理等的国内外研究现状。分理论研究、实验研究和数值模拟三方面,重点讨论了靶板材料、靶板层数、组合方式及弹头形状等因素对靶板抗侵彻性能的影响。同时,结合作者前期相关工作,指出了当前研究工作中存在的不足,并提出了有待进一步研究的问题。     

界限含水量试验的探讨

对采用液、塑限联合测定法测定土的液、塑限试验的有关问题进行探讨;并通过玉树隆宝湖地区粘土的实测分析,说明选用适当的试验标准对减少误差,提高试验的准确性尤为重要。     

肉毒碱对不同蛋白质水平饲料脂肪消化率的影响

用在3个(28%,32%,36%)蛋白质水平上分别添加了10-4纯肉毒碱的饲料喂养相同的鲤鱼春片鱼种,分别以空白为对照组,比较添加肉毒碱对饲料的脂肪消化率的影响.结果表明,肉毒碱具有明显的促进鲤鱼饲料脂肪消化的作用,同时蛋白质含量越低的饲料,其添加的效果越好.当添加量为10-4时,饲料脂肪的消化率由大到小的顺序为蛋白质量分数分别为28%,32%,36%.     

一种考虑杆件初始弯曲的非线性杆单元

在假定杆件初始弯曲为半波正弦曲线的基础上,提出考虑初始弯曲的非线性杆单元,推导了轴力与轴向变形的关系和轴向切线刚度的表达式,得到了初始弯曲对轴向刚度的影响系数.分析表明,初始弯曲影响与刚度比、初始弯曲幅值、轴力大小以及杆单元长度有关.结合某索拱结构工程实例,研究不同初始预应力取值下,杆件初始弯曲对结构非线性稳定性能的影响程度和影响规律,结果表明:杆件初始弯曲对结构屈曲前的整体刚度影响很小,但对结构的极限荷载与屈曲后性能影响较大;初始预应力取值的增加对结构的位移控制非常有效,但是对结构的刚度影响却很小;在不同初始预应力取值下,极限荷载随杆件初始弯曲变化的规律相似,并且都接近于线性.非线性杆单元能够广泛应用于桁架结构和网格结构的设计与分析,在考虑杆件初始弯曲后,将使结构的设计与分析更加合理、更加科学.