溶胶-凝胶法制备纳米SiO2包覆的铝颜料

铝颜料是重要的金属颜料之一,当其用于水性涂料时,易被腐蚀而逐渐失去金属光泽,为了提高铝颜料的耐碱性,在乙醇/水体系中,采用溶胶-凝胶法制备了纳米SiO2包覆的铝颜料,利用SEM、XRD和FTIR分析手段对其进行了表征,并考察了其耐碱性.结果表明:当体系原料H2O/NH3/TEOS的摩尔比为32.7∶4.4∶1时,SiO2可以在铝颜料表面形成致密的保护膜;铝颜料经SiO2包覆处理后,其耐碱性大大提高,在pH=11的溶液中放置60天后,没有任何H2产生,表明经SiO2包覆处理的铝颜料具有优异的耐碱性.     

胰岛素抵抗及高血糖对GFAT活性的影响

分别观察了胰岛素抵抗和高血糖水平对己糖胺途径限速酶GFAT活性的影响.在alloxan高血糖小鼠模型中,与正常对照组比较,血清果糖胺水平升高了15.9%,肾组织GFAT活性升高了32.8%;经胰岛素治疗后,血清果糖胺水平降低了9.7%,其肾组织GFAT活性也降低了l9.4%.在高糖高脂饲料诱导的胰岛素抵抗的IR小鼠中,与同批正常对照组比较,正糖钳实验中稳态时葡萄糖输注率G IR值降低了69.3%,胰岛素耐量实验中的AUC值升高了38.1%,其肾脏组织GFAT活性也增加了26.6%.在胰岛素诱导的具有胰岛素抵抗的IR-H IR c细胞模型中,与正常H IR c细胞比较,其10、25 nmol/L胰岛素诱导的葡萄糖摄取能力分别降低了25.3%、21.1%,而GFAT活性分别增加了29.7%、46.5%.可见,GFAT活性与一段时间的平均血糖水平和胰岛素抵抗状态密切正相关.     

含乙烯基基团的聚硅烷的合成与表征

以甲基乙烯基二氯硅烷为单体,采用超声钠缩合法合成聚(甲基-乙烯基)硅烷;在此基础上,采用相同的方法,变化单体以甲基乙烯基二氯硅烷和甲基苯基二氯硅烷为原料,合成了共聚硅烷和有一定程度交联的聚甲基乙烯基硅烷,并对它们用FT-IR,1HNMR,UV,TGA进行了表征.结果表明,聚(甲基-乙烯基)硅烷产物产率从2%提高到了28%;各种产物聚硅烷中均含有大量乙烯基基团,有利于进一步进行其他官能化反应.     

Lipids of sulfate-reducing bacteria and sulfur-oxidizing bacteria found in the Dongsheng uranium deposit

U-bearing sandstones from the Dongsheng deposit in Ordos Basin contain abundant C15-C18 fatty acids. The fatty acids may have been derived from modern and ancient organisms including organisms from the intervals of U mineralization. A certain amount of i15:0, a15:0, a17:0 fatty acids coexist with small amounts of i17:1ω7c and 10me16:0, characteristic biomarkers of Desulfovibrio and Desulfobacter sp., respectively. This indicates the existence of sulfate-reducing bacteria (SRB) in the sandstones. The presence of sulfur-oxidizing bacteria (SOB), such as Beggiatoa and Thioploca, is indicated by significant amounts of 16:1ω7c and 18:1ω7c fatty acids. The existence of the SRB in the deposit, as inferred from the fatty acids, is consistent with results from fossilized microorganisms and isotopic compositions of ore-stage pyrite. This suggests that the environment may have been favorable for the SRB to grow since ore formation (9.8-22 Ma). The bacteria may have degraded hydrocarbons directly, or indirectly utilized hydrocarbons degraded by oxic microbes in the deposits. This process may have produced 12C-rich calcite and prominent baseline humps of unresolved complex mixtures (UCM), and 25-demethylated hopanes and tricyclic terpanes. The existence of sulfur-oxidizing bacteria and sulfate-reducing bacteria in the deposit may have resulted in bacterial sulfate reduction to sulfide, re-oxidization of the sulfide to sulfate and subsequent reduction of the sulfate to sulfide. This assertion is supported by ore-stage pyrite with δ34S values as low as-39.2‰, and the lightest sulfate (about 11‰) measured during the Phanerozoic, a difference of more than 46‰.     

山西省2007年PM10气溶胶变化特征分析

通过计算并分析大同、榆社两地PM10日际平均值、日平均值、月平均值、季平均值，详细解释了不同时间段和时期PM10质量浓度变化的规律和原因，为开展对气溶胶粒子的影响要素分析提供了依据。     

当前西藏产业结构存在的问题及原因分析

西藏和平解放六十年来,经济发展成效显著,产业结构不断得以优化,但各产业之间以及产业内部各部门、各层次之间还存在诸多问题,在一定程度上制约了西藏经济的跨越式发展。西藏三次产业结构的主要问题是结构偏离度大而产业高度化程度低,各次产业内的问题则主要表现为各子产业发展失衡和不均衡现象突出,产业发展尚处于低级阶段。文章认为社会经济体制发展基础薄弱而市场化程度低下;高原地理特征、气候条件和资源禀赋制约;人口相对稀少、分散加上受教育程度相对低,是产业发展相对滞缓的原因。     

论创业设计师的商业素质构成——以创业设计师成立小型设计公司为例

现代设计是商业化设计,设计活动和设计产品面向市场,具有很强的商业特性.设计从最初的动机到最后价值的实现,都离不开商业因素的影响.设计的商业性质决定了创业设计师必须具备一定的商业素质.     

Comparison of reduction disintegration characteristics of TiO2-rich burdens prepared with sintering process and composite agglomeration process

To reveal the impact of the composite agglomeration process (CAP) on the reduction disintegration properties of TiO₂-rich ironmaking burden for a blast furnace, the reduction disintegration indices (RDIs), mineral constituents, and microstructure of the products prepared by the CAP and the traditional sintering process (TSP) were investigated. The results showed that, compared to the sinter with a basicity of 2.0 prepared by the TSP, the RDI_+6.3 and the RDI_+3.15 of the CAP product with the same basicity increased by 28.2wt% and 13.7wt%, respectively, whereas the RDI_-0.5 decreased by 2.7wt%. The analysis of the mineral constituents and microstructure of the products indicated that the decreasing titanohematite content decreased the volume expansion during reduction. Meanwhile, the decreasing perovskite content decreased its detrimental effect on the reduction disintegration properties. In addition, the higher silicoferrite of calcium and aluminum (SFCA) content improved the strength of the CAP product. Together, these factors result in an improvement of the RDI of the CAP products. In addition, compared to the sinter, the reduced CAP products clearly contained fewer cracks, which also led to mitigation of reduction disintegration.     

基于价值的实验室评估体系构建

现代化实验室的价值取向在于能更好地为教学、科研、生产服务。实验室在长期的教学、科研、生产活动中是否体现了其应有的价值，是衡量实验室建设、管理成败的关键。文中构建了一种基于价值的实验室评估体系模型，以对实验室的价值进行科学的评判。     

一种新型的空调系统空气处理方法及其节能分析

针对现有空调系统空气处理方法存在的不足,提出一种热湿分段的空调系统空气处理方法.分析了热湿分段处理方法的原理和过程,通过建立热湿分段处理方法的节能数学模型,研究并得出了表冷器结构、空调回风状态对热湿分段处理方法节能效果的影响规律.结果表明:相对于常规空气处理方法,热湿分段处理方法在表冷器设计换热温差7 ℃、出风温度为16 ℃时,冷水机组COP提高达9.14%以上;在回风干球温度为25 ℃、湿球温度为21 ℃时,冷水机组COP提高达8%以上.