Boosting photocatalytic Suzuki coupling reaction over Pd nanoparticles by regulating Pd/MOF interfacial electron transfer

Palladium-catalyzed C-C coupling reactions are of significant importance, but they often require harsh conditions. Herein, we report an interface-regulated photocatalytic Suzuki coupling reaction over Pd nanoparticles supported on a metal-organic framework (MOF), ZIF-8. Two Pd/MOFs were synthesized, Pd_PVP/ZIF-8 and Pd/ZIF-8, which have similar Pd sizes and loading amounts, except that the former contains poly(vinylpyrrolidone) (PVP) as a surfactant. The diffuse-reflectance infrared Fourier transform of CO adsorption (CO-DRIFT) indicates that Pd/ZIF-8 represents a more negative electronic state of Pd than Pd_PVP/ZIF-8. In the photocatalytic Suzuki coupling reaction between iodobenzene and phenylboronic acid, Pd/ZIF-8 exhibits excellent performance (99.1% yield), much better than that of Pd_PVP/ZIF-8 (57.9% yield). Moreover, Pd/ZIF-8 is highly stable and shows broad substrate scope for this reaction. The superior activity of Pd/ZIF-8 can be attributed to sufficient electron transfer between the MOFs and Pd nanoparticles in the absence of an interfacial surfactant. This work provides new insights into a Pd-catalyzed C-C coupling reaction involving photocatalysis and interfacial electron transfer.     

基于响应面和NSGA-II的AGV系统多目标优化配置

AGV（automated guided vehicle）系统对于制造系统的生产柔性和生产效率具有重要作用,由于AGV系统具有许多的变量且有动态性、随机性特点,其优化配置比较复杂。提出了一种将系统仿真、数学解析和多目标优化相结合的方法,对AGV系统进行了优化配置;运用离散事件仿真模拟AGV系统运行,利用敏感性分析分离设计变量,采用析因试验和响应面方法拟合多目标优化数学模型,基于非支配解排序多目标遗传算法求解多目标优化解。通过AGV系统实例,证明了该方法的有效性,可为制造系统和物流仓储领域中AGV系统的优化配置提供一种有效的系统性分析方法。     

Long-Time Behavior and Density Function of a Stochastic Chemostat Model with Degenerate Diffusion

This paper considers a stochastic chemostat model with degenerate diffusion. Firstly, the Markov semigroup theory is used to establish sufficient criteria for the existence of a unique stable stationary distribution. The authors show that the densities of the distributions of the solutions can converge in L¹ to an invariant density. Then, conditions are obtained to guarantee the washout of the microorganism. Furthermore, through solving the corresponding Fokker-Planck equation, the authors give the exact expression of density function around the positive equilibrium of deterministic system. Finally, numerical simulations are performed to illustrate the theoretical results.

     

武器装备体系组合规划的高维多目标优化决策

针对武器装备体系组合规划问题中存在多类相互冲突的高维多目标问题(目标数 ≥ 5),提出了一种三阶段的集成优化决策方法. 首先运用目的规划技术将高维多目标问题转换为一般多目标优化模型(目标数 ≤ 3); 然后提出一种多目标差分进化算法,用于搜索属于决策者关心区间的非劣解集; 最后提出基于预测优化的理想点算法,可生成精确满足决策者偏好的最佳折衷解. 通过某侦察装备体系组合规划示例,证明了各算法模块的优势和该方法的整体有效性,可为武器装备发展和顶层规划提供决策支持.     

Discovering non-terminating inputs for multi-path polynomial programs

This paper investigates the termination problems of multi-path polynomial programs （MPPs） with equational loop guards. To establish sufficient conditions for termination and nontermination simultaneously, the authors propose the notion of strong/weak non-termination which under/over- approximates non-termination. Based on polynomial ideal theory, the authors show that the set of all strong non-terminating inputs （SNTI） and weak non-terminating inputs （WNTI） both correspond to tile real varieties of certain polynomial ideals. Furthermore, the authors prove that the variety of SNTI is computable, and under some sufficient conditions the variety of WNTI is also computable. Then by checking the computed SNTI and WNTI varieties in parallel, termination properties of a consid- ered MPP can be asserted. As a consequence, the authors establish a new framework for termination analysis of MPPs.     

2018年1月河南省暴雪寒潮天气对设施农业的影响评估

2018年1月上旬河南省出现了两次大范围降雪、寒潮天气过程,对设施农业生产造成一定不利影响。选取1月上旬河南省的两次降雪、寒潮天气过程气象资料,以及设施农业气象灾害调查资料,进行统计分析,做出了此次灾害过程对河南省设施农业生产的影响评估。根据分析,暴雪致全省90%以上市（县）设施农业气象灾害等级达到中度以上,50%以上市（县）达特重级别;大风对日光温室影响不大,对部分塑料大棚有轻度灾害;低温致全省日光温室蔬菜均达到不同程度气象灾害等级。同时对主要致灾原因进行了分析,提出了暴雪、寒潮天气设施农业防御对策。     

低碳低硫钢中MnS析出行为分析

本文研究铝含量、硫含量、冷却速率等对低碳低硫钢中MnS夹杂物的成分、形貌和析出量的影响,并利用Scheil凝固方程及FactSage 6.1软件对MnS析出行为进行了理论计算。结果表明,冷却速率较低(5K/min)时,钢中夹杂物为双层结构,核心氧化物为Al2O3-SiO2和Al2O3-SiO2-MnO,MnS在氧化物表面局部或包裹析出;冷却速率较高(900K/min)时,钢中夹杂物主要为Al2O3-SiO2-MnO,高铝钢样中没有MnS析出,而低铝钢样中有极少量MnS析出;MnS在夹杂物上的析出率随着冷却速率的降低、钢中铝含量的减少(硫含量随之增加)而提高;复合氧化夹杂中的MnO+SiO2对MnS的析出影响较大,MnO+SiO2含量越高,MnS越容易在氧化物上析出;在低硫(w[S]0.0050%)条件下,MnS不能在液相中单独析出,但能在夹杂物上复合析出。     

葛属植物基因组DNA的提取和纯化

采用SDS裂解法提取了葛属植物成熟叶片的基因组DNA,并利用凝胶纯化试剂盒进行了纯化。结果表明,该纯化方法有效,所获得的DNA可用于PCR反应。     

二十五味珊瑚丸中西红花苷I＆Ⅱ的含量测定研究

目的：建立高效液相色谱法测定二十五味珊瑚丸中西红花苷含量的方法。方法：采用HPLC法,色谱柱：DionexC18柱（250ram×4．60mm,5um）;流动相为甲醇-水（52：48）,流速为0．8ml／min,检测波长为440nm,柱温为250C;进样量10μl;用标准曲线法定量,测定二十五味珊瑚丸中西红花苷含量。结果：西红花苷I在33μg-330μg范围内与峰面积呈良好的线性关系（r=0．9999）,西红花苷Ⅱ在62μg-310μg范围内与峰面积呈良好的线性关系（r=0．9998）,平均回收率为103．73％,RSD为1．68％（n=6）。结论：本方法操作简单、重现性好,可用于测定二十五味珊瑚丸中西红花苷I＆Ⅱ含量。