Topography,structure, and formation kinetic mechanism of carbon deposited onto nickel in the temperature range from 400 to 850℃

The carbon deposition behavior on nickel particles was observed within the temperature range from 400 to 800℃ in a pure methane atmosphere. The topography, properties, and molecular structure of the deposited carbon were investigated using field-emission scanning electron microscopy (FESEM), temperature-programmed oxidation (TPO) technology, X-ray diffraction (XRD), and Raman spectroscopy. The deposited carbon is present in the form of a film at 400-450℃, as fibers at 500-600℃, and as particles at 650-800℃. In addition, the structure of the deposited carbon becomes more ordered at higher temperatures because both the TPO peak temperature of deposited carbon and the Raman shift of the G band increase with the increase in experimental temperature, whereas the intensity ratio between the D bands and the G band decreases. An interesting observation is that the carbon deposition rate is suppressed in the medium-temperature range (M-T range) and the corresponding kinetic mechanism changes. Correspondingly, the FWHM of the G and D1 bands in the Raman spectrum reaches a maximum and the intensities of the D2, D3, and D4 bands decrease to low limits in the M-T range. These results indicate that carbon structure parameters exhibit two different tendencies with respect to varying temperature. Both of the two group parameters change dramatically as a peak function with increasing reaction temperature within the M-T range.     

Nomex蜂窝夹芯板冲击损伤试验研究

针对某型飞机上应用的Nomex蜂窝夹芯板,通过冲击损伤试验,研究了蜂窝夹芯板厚度对其抗冲击损伤能力的影响、试件损伤面积与冲击能量之间的关系以及穿透损伤对夹芯板轴压承载性能的影响。结果表明:20 mm与8 mm厚度板在分别承受40 J与25 J冲击能量时出现穿透损伤,厚板比薄板具有更高的抗冲击损伤能力;相同冲击能量时,20 mm厚板损伤面积比8 mm板的小;随冲击能量的增大,两种板的损伤面积逐渐增大;当冲击能量超过一定值时,8 mm板损伤面积增速明显加快;20 mm蜂窝夹芯板冲击后的剩余强度为完好件的56.7%,8 mm蜂窝夹芯板冲击后的剩余强度为完好件的67.5%。     

乙酰丙酮缩-N，N-二甲基乙二胺铜配合物Cu（AE）（BA）的合成、晶体结构及其对DNA的切割作用

合成了一种新的乙酰丙酮缩-N,N-二甲基乙二胺铜配合物Cu(AE)(BA)(AE为乙酰丙酮缩-N,N-二甲基乙二胺,BA为苯甲酸),并通过X一射线衍射测得其晶体结构.晶体属单斜晶系,空间群为C2/c,晶胞参数a=1.434 0(11)nm,b=1.352 7(10)nm,c=1.824 6(13)nm,β=108.766(12)°,Z=8,R1=0.041 4,wR2= 0.095 0.测定了配合物的光谱性质,并进行了切割DNA实验研究.     

耐盐活性剂水溶液微观状态与耐盐性能的关系

实验发现改性α-烯基聚醚磺酸铵不仅能使油分散在高矿化度水中,而且其耐盐性能与耐盐活性剂水溶液的微观状态存在一定的相依性:能使高矿化度水的结晶和缔合态的立体结构转变为片状结构;并能脱出由于高矿化度水中高盐份而生成的结晶水和缔合水.实验在各种矿化度条件下进行,加入改性的α-烯基聚醚磺酸铵,能使矿化度高达1.5×105 mg·L-1的水溶液的表面张力从80 mN·m -1左右降到35 mN·m -1左右,并且能使粘度为1.0×105 mPa·s左右的稠油乳化降粘,使粘度降到30 mPa·s左右(约30 ℃),还能使脱水后的原油本体粘度降低一半以上.耐盐活性剂的活性并不受高浓度盐类影响,特别是Ca2+、Mg2+高达1.0×104 mg·L-1以上时,其表面活性剂水溶液也是无色透明的,这与普通表面活性剂表现出来的盐析作用和普通活性剂在Ca2+、Mg2+离子存在时易于沉淀有所不同.就以上实验所得结果研究其耐盐体系的微观状态、耐盐机理及耐盐性能.     

Optimization of web search engine and its application to web mining

With the explosive growth of information sources available on the World Wide Web, how to combine the results of multiple search engines has become a valuable problem. In this paper, a search strategy based on genetic simulated annealing for search engines in Web mining is proposed. According to the proposed strategy, there exists some important relationship among Web statistical studies, search engines and optimization techniques. We have proven experimentally the relevance of our approach to the presented queries by comparing the qualities of output pages with those of the original downloaded pages, as the number of iterations increases better results are obtained with reasonable execution time.      

Discovery of Ordovician acritarchs in Buqingshan ophiolite complex, East Kunlun Mountains and its significance

This note reports the first discovery of Middle-Late Ordovician acritarchs from the Buqingshan ophiolite complex of the southern ophiolite zone of East Kunlun. The acritarch assemblage is dominated with acanthomorphids (approx. 32%) and sphaeromorphds (approx. 63%) and contains more characteristic forms, such as Lophosphaeridium edenense, L. varum, Nothooidium sp.,? Buedingiisphaaeridium sp., Visbysphaera sp., Strophomorpha sp., etc. In addition, some tube-like fragments and tetrads, which are recognized as affinity to terrestrial plants and usual occurrence in Late Ordovician-Early Silurian strata, are preserved together with acritarchs. All the known fossil evidence indicates that the strata should be Middle-Late Ordovician in age. It not only provides paleontological proof for the existence of Ordovician ophiolite, but also challenges the usual ideas on strata composition of the studied area and the southern ophiolite zone of East Kunlun, and the models on tectonic framework and evolution of this area and the northern part of the Qinghai-Tibetan Plateau.     

A kind of coccoid dinoflagellates-like fossils gives a new explanation of source of dinosterane in the Early-Middle Cambrian

The coccoid fossils covered with thick gelatinous envelop containing several gametes are discovered in gyps and salt deposits of Cambrian, H₄ well and chert bed of the base of Yuertus Formation (∈¹₁) of Xiaoerbulake Section. The fossils are described and compared with coccoid dinoflagellates. These fossils may be a coccoid life-cycle stage (vegetative cyst) of coccoid dinoflagellates. If this identification is correct, the coccoid dinoflagellates-like fossils could give a reasonable explanation of the dinoflagellate-specific biomarkers from Cambrian, H₄ well, Tarim Basin.     

椭圆曲线密码体制基点选取算法的设计与实现

在有限素整数域Ｅｐ上定义了一条椭圆曲线及点群运算规则,并由此构造出一种椭圆曲线密友体制。结合椭圆曲线域参数属性,讨论了平方剩余的定义、性质,完整地设计出选取基点Ｇ的Ｘ坐标的算法,根据Ｆｐ上素数Ｐ的不同性质,提出２种基点Ｇ的Ｙ坐标的计算方法,并给出了其数学证明。在ＰＣ机上用汇编语言实现的结果表明,该基点选取算法适于微机实现且实际可行,从而全面解决了椭工线密码体制中基占选取及如何把数据编码为椭圆曲线上     

采空区温度场模拟及煤自燃状态预测

建立了采空区温度场的数学模型,并用有限差分数值方法进行模拟计算.通过计算得出了煤因氧化放热导致煤温随时间变化呈指数上升的规律以及点热源附近温度场随时间的变化规律.提出采用测量煤层中两点间温差的变化来预报高温点温度的方法,此法由于消除了矿井空气温度波动因素的影响,具有较高的稳定性.     

双酚类化合物对人胚肾细胞HEK293的毒性和氧化应激的研究

双酚类化合物(bisphenols, BPs)是一类新型环境有机污染物,BPs排放到环境介质后经多种途径进入生物体并在体内蓄积,已逐渐成为威胁环境和健康的重要风险因子。为探明BPs对人体健康的潜在毒性效应,本研究选取人胚肾细胞HEK293作为模型,通过测定细胞活力、胞内活性氧含量、氧化应激参数(SOD、GSH、MDA)及细胞内钙离子水平,比较了BPA、BPS、BPF和BPAF对HEK293细胞的毒性影响。结果表明,BPA、BPS、BPF和BPAF能够不同程度的抑制HEK293细胞活力,通过促进氧化应激产生 ROS,降低抗氧化能力,迅速提高细胞内Ca²⁺水平,诱导HEK293细胞损伤。在本研究所选的浓度范围内,BPAF对HEK293细胞的毒性影响最大,BPA和BPF对HEK293细胞的毒性影响次之,BPS对HEK293细胞的毒性影响较小。本研究为深化了解双酚类化合物的毒理学系统研究和风险评估提供参考依据。