L——鼠李糖的变温远红外光谱研究

用付立叶变换红外光谱研究了L—鼠李糖的变温远红外光谱,发现糖类分子在远红外区有许多特征吸收峰.当温度低到60℃时,光谱几乎无变化;65℃时,各峰强度大大减弱,但没有峰消失;75℃时,有7个峰消失.这些消失的峰与体系中氢键振动和晶格振动有关,反映了体系中分子的构象变化.     

云南禄丰、贵州桐梓、陕西富县的鱼粪化石

粪化石是所有脊椎动物的排泻物。文中建议建立粪石科代替粪化石,把不同类动物的粪石均按生物命名法给以属种的名称。文内提出了5个属名,鱼粪石建立5个种。     

具有两个称量台面的动态轨道衡的软件

本文介绍了一种双台面微机动态轨道衡的新型软件。当油罐车通过秤台时,计算机能自动地以整车计量方式计算出车重,从而消除罐中液体晃动对计量精确度的影响。当固态货车通过秤台时,计算机自动地以转向架计量方式计算出车重。因为有两个秤台,每个转向架被计量两次,这样,称量精确度比单秤台高。     

几种桥环化合物Retro-Diels-Aleder反应的活化熵及A因子估算

用简化的过渡态理论(STST),按协同机制,对几种桥环化合物裂解反应的活化熵、A因子作了首次估算.并和实验结果作比较讨论了反应可能进行的机理:解释了反应的A因子递变现象.     

The effect of metal electron cloud on the luminescence characteristics of organic ligands: An experimental and theoretical investigation

The luminescence processes of metal complexes are complicated by intramolecular charge (energy) transfer from the metal to the ligand or from the ligand to the metal. The charge transfer strongly influences the excited state of the ligand and its luminescence characteristics. The luminescence characteristics of tris(8-hydroxyquinoline) aluminum (Alq3) and tris(8-hydroxyquinoline) gallium (Gaq3) are investigated to reveal the effect of the metal ion on the ligand. Emission from the complexes shows a signific...     

A high-performance narrowband high temperature superconducting filter

Recent development of a high-performance narrowband high-temperature superconducting (HTS) filter is presented. A 10-pole quasi-elliptic function response filter with two pairs of transmission zeros (for high selectivity), which has a center frequency of 2.185 GHz and a 3 dB bandwidth of 10 MHz (a fractional bandwidth of 0.45%), is introduced. The filter was fabricated on a 40 mm×16 mm×0.5 mm MgO wafer with double-sided YBCO films. The measured results show that the filter has 0.15 dB insertion loss at the ...     

谈现代城市轨道交通的设备管理分类及编码

结合资产密集型的城市轨道交通的行业特点,以设备的全寿命周期管理为线索,对为设备管理服务的几种设备分类方式与编码方式进行尝试性分析,并为信息化管理提供参考思路。     

Synthesis of Mg2B2O5 whiskers via coprecipitation and sintering process

Mg₂B₂O₅ whiskers with high aspect ratio were synthesized by coprecipitation and sintering process using MgCl₂·6H₂O, H₃BO₃, and NaOH as raw materials and KCl as a flux. Their formation process was investigated by thermogravimetry and differential scanning calorimetry (TG-DSC), X-ray diffraction (XRD), and scanning electron microcopy (SEM). It is found that the products synthesized at 832°C are monoclinic Mg₂B₂O₅ whiskers with a diameter of 200?C400 nm and a length of 50?C80 ??m. Transmission electron microscopy (TEM) and selected area electron diffraction (SAED) analyses show that the whiskers obtained at 832°C are single crystalline and grow along with the [010] direction. The growth mechanism of Mg₂B₂O₅ whiskers was also presented.     

Effect of TMGa flux on GaN films deposited on Ti coated on glass substrates at low temperature

Highly c-axis-oriented GaN films were deposited on Ti coated glass substrates using low temperature electron cyclotron resonance plasma enhanced metal organic chemical vapor deposition system(ECR-PEMOCVD)with trimethyl gallium(TMGa)as gallium source.The influence of TMGa flux on the properties of GaN films were systematically investigated by reflection high energy electron diffraction(RHEED),X-ray diffraction analysis(XRD),atomic force microscopy(AFM)and Raman scattering.The GaN film with small surface roughness and high c-axis preferred orientation was successfully achieved at the optimized TMGa flux of 1.0 sccm.The ohmic contact characteristic between GaN and Ti layer was clearly demonstrated by the near-linear current-voltage(I-V)curve.The GaN/Ti/glass structure has great potential to dramatically improve the scalability and reduce the cost of solid-state lighting light emitting diodes.