The strong cooperativity of dioxygen binding by dicobalt (II) diporphyrin compounds in nonaqueous solution at room temperature

Thermodynamic data were determined for the reversible binding of O₂ to two compounds of dicobalt(II) di(meso-tetra-phenyl)porphyrin derivatives with different lengths of diamidoaliphatic bridge (abbreviated to Co₂PP₈ and Co₂PP₄) in N,N-dimethylformamide at room temperature. The partial pressure of dioxygen necessary for half-oxygenation (P _1/2) and hill coefficient (n) at 298 K were determined as follows:P _1/2=54.2 kPa,n=2.0 for Co₂PP₈ andP _1/2=6.8 kPa,n=1.8 for Co₂PP₄, respectively. The rate equations of reversible oxygen binding by Co₂PP₈ were determined and the reaction path was proposed. The results of ther-modynamic and kinetic studies indicate that there exists strong cooperative effect during oxygenation of the compounds. The ESR observation reveals that the dioxygen complexes formed in the solutions are of superoxo (Co-O ₂ ⁻ ) type. Supported by the Research Foundation of the State Education Commission of China Zhou Xiaohai: born in 1962, Ph.D. Associate professor     

电力市场中的价格基础

概述了电力市场中的实时电价这一基础问题，具体分析了实时电价的组成成分和进一步的 收益调节方案，并就实行过程中可能出现的一些因素及影响，乃至在我国的实际应用前景及相应措施进行了初步的探讨。     

过渡金属与席夫碱及邻菲罗啉配合物的合成表征

合成了N-亚水杨基丙氨酸席夫碱及其与过渡金属Cu（Ⅱ）、Zn（Ⅱ）、Ni（Ⅱ）和邻菲罗啉的三元混配配合物。用元素分析、摩尔电导、红外光谱、紫外光谱和差热热重分析对其性质进行了表征.     

网络传输中邮件后台接收的研究与实现

介绍了利用ＤＯＳ空闲中继写驻留程序，进行实时数据后台接收的方法，分析了ＩＰＸ协议的基本原理，结构和特点，着重讨论了在后台接收邮件的实现策略。     

对称组合系统的鲁棒输出调节

研究了对称组合系统的鲁棒输出调节问题。结果表明，对称组合系统的鲁棒输出调整问题可以转化为两个修正的低阶子系统的鲁棒输出调节问题。并可通过考察两个低阶矩阵行的线性相关性得到解决。     

LAND SUPPLY AND HOUSING PRICE:THE CASE IN HONG KONG

In this study we examine the relationship between land supply and housing price, percentage of land premium in the total government revenue and housing price, with reference to Hong Kong from 1981 to 1994. To do this we employ the Granger causality method to test the underlying hypothesis whether Hong Kong Government adopt high land-price policy. We use the first difference of data to ensure the stationarity in time series with the help of augmented Dick-Fuller unit root test. The results of the paper suggest no strong evidence to support the view that the land control of the government has caused soaringly rising housing prices. The findings also apparently implicate that the government has the revenue-maximizing behavior which is consistent with efficient allocation of resources.     

纺织品静电场强衰减的数值计算与实验研究

对服从欧姆定律和在高场强下不服从欧姆定律的纺织品利用计算机进行数值计算与模拟并进行实验研究.结果表明无论电流密度与电场强度之间为何关系.不同初始场强的衰减曲线都不会发生交叉(Cross-Over)现象,若电流密度不仅与任意时刻的场强有关而且还与初始电场有关则会发生交叉,计算结果预示在某种特殊电场范围内时可能发生双交叉(Double Cross-Over)现象.数值计算结果与实验结果对比显示两者符合得较好.     

培养基质若干因子对香蕉试管苗生长的影响

采用正交设计研究了培养基中蔗糖浓度、6—苄氨基嘌吟浓度、卡拉胶浓度对不同香蕉品种的芽分化率和生长量的影响,筛选出香蕉试管苗长势良好、分芽率高、芽粗壮的培养基配方:MS+35g·L~(-1)蔗糖+3g·L~(-1)卡拉胶+1mg·L~(-1)6—BA.香蕉不同品种的分芽率差异不显著,但分芽率与芽生长量密切相关.