HPLC Determination of Ascorbic Acid Using Luminol-Cu(Ⅱ) Chemiluminescence-Application to the Analysis of Juice Beverage

The chemiluminescence (CL) of luminol-Cu(Ⅱ) was applied to HPLC determination of ascorbic acid, which was separated by a C18 reverse-phase column with a mobile phase of 0.25 mol/L HAc. The eluted ascorbic acid was mixed with 0.3 mmol/L luminol and 0.05 mol/L CuSO4. The light emission from the reaction of Cu(Ⅱ) oxidized ascorbic acid and luminol was detected by a modified luminometer. The detection limit was 3.6×10-6 mol/L for ascorbic acid at a S/N ratio of 3, and the linear calibration range was 2×10-4- 2×10-3 mol/L. The relative standard deviation for 5 replicate injections of 1×10-3 mol/L ascorbic acid was calculated as 4.3 %. The method was successfully applied to determination of ascorbic acid in juice beverage.     

关于水利工程钢筋混凝土施工技术的探讨

水工混凝土建筑物因所受水荷载及温度变化等条件的不利影响,建成后往往带病运行,运行后又有一个老化过程,因此需要精心地检查、维护和修理才能保证其安全运行.否则,一定期限后就会发生严重事故,许多预防老化病害的措施,在规划设计和施工阶段就应认真考虑并实施.笔者就钢筋混凝土施工中的技术工作进行了探讨.     

Simulation study of SVM-based approach in extracting parameters for electromagnetic detection of buried object

In this paper, a new method for extracting the parameters of buried object is proposed. The center position and dielectric properties of 2-D buried object are estimated by means of a regression technique based on support vector machine (SVM). The proposed method, after a proper training procedure, is able to reconstruct the center position and dielectric properties of a buried object inside a given investigation domain. Numerical simulation results indicate that SVM-based approach shows higher accuracy than the back-propagation neural networks (BPNN) algorithm.     

Synthesis and characterization of bifunctional terbium complex-based nanoparticles

Novel bifunctional terbium complex-based nanoparticles were developed using a modified Stber method and a layer-by-layer assembly process. A magnetic core of Fe3O4 nanoparticles was coated with a silica shell to form the first layer. Then a ternary Tb3+ complex (TESPPA-Tb), which acted as a luminescent marker, was covalently bound to the silica surface by stable Si-O-Si bonds. The TESPPA monomer was synthesized by binding pyridine 2,6-dicarboxylic acid to 3-aminopropyltriethoxysilane, which was used as a ligand for coordination with the Tb3+ ions. An outer shell of silica was applied to the nanoparticles to allow for versatility with surface functionalization. The nanoparticles were characterized by X-ray powder diffraction, transmission electron microscopy, Fourier transform infrared spectroscopy, ultravioletvisible spectroscopy, vibration sample magnetometer, and photoluminescence spectroscopy. The bifunctional nanoparticles exhibited favorable superparamagnetic behavior and photoluminescence properties of Tb3+. These nanoparticles have potential applications in biolabeling, bioseparation, immunoassays, and pathogenic diagnosis.     

扬弃·改造·复兴──兼评《出路在于向西方乞灵》

中国传统音乐文化与西方音乐文化存在着相对性差距与绝对性差距。清醒地认识到这个事实，在坚持发挥本民族音乐的内在神韵与气质的同时，认真学习西方音乐文化中更丰富地展示人类灵魂的表现体制，才能为中国音乐的发展确定正确的方向，实现民族音乐的全面复兴。     

电镀铬生产中三价铬行为分析及控制

本介绍了电镀铬生产中三价铬所起的作用，分析其在溶液中含量变化给生产带来的影响，提出了正确控制三价铬的方法，对解决由于三价铬变化赞成的电镀铬质量问题具有一定的参考价值。     

数学教学中培养学生思维能力的途径

思维能力是认识能力的核心,它受诸多因素的影响,而且因人而异,客观上存在着差异.优秀的思维品质不是与生俱来的,而是在解决问题的实践中逐步形成的.因此,在数学教学中应不失时机地培养学生的思维能力.     

催化剂电梯抱闸控制系统的改进

通过对实际现场中电梯抱闸控制系统的调查与研究,发现目前此控制系统存在较大的问题,经常引发控制系统故障的产生,导致电梯不能正常运行,维修成本居高不下、严重影响了装置的正常生产。因此对此控制系统做出改进。     

Synthesis of novel superhard materials under ultrahigh pressure

Superhard materials are solids whose Vickers hardness is beyond 40 GPa. They have wide applications in industry such as cutting and polishing tools, wear-resistant coatings. Most preparations of superhard materials are conducted under extreme pressure and temperature conditions, not only for scientific investigations, but also for the practical applications. In this paper, we would introduce the recent progress on the design and preparations of novel superhard materials, mainly on nanopolycrystalline diamond, B–C–N superhard solid solutions, and cubic-Si3N4/diamond nanocomposites prepared under ultrahigh pressure and high temperature（HPHT）, using multi-anvil apparatus based on the hinged-type cubic press. Bulk materials of all these superhard phases have been successfully synthesized and are systematically tested. We emphasize that ultra-HPHT method plays an important role in the scientific research and industrial production of superhard materials. It provides the driving forces for the light elements forming novel superhard phases as well as the way for sintering high-density nanosuperhard materials.     

从天时地利人和谈篮球比赛的主场优势

中国传统文化的成功论讲究天时、地利、人和,我国古代战争中常指占有这几种优势的一方,其胜算就大.现在在世界顶级篮球联赛的NBA、我国的CBA及欧洲的各种篮球联赛,组织者都是从这几方面着手,来激发主场运动员的潜能,发挥球队的主场优势,从而夺取比赛的胜利.本文运用文献资料法,通过分析天时、地利、人和在篮球主场比赛中的具体体现,旨在进一步提高我们对主场优势的认识.