Preparation and optical properties of solid solution semiconductor (Zn x Cd1−x S) doped silica glasses

Semiconductor(Zn_xCd_1−x S) doped silica glasses were prepared by Sol-Gel process andin situ growth technique. The structure of the materials was characterized by X-ray diffraction technique, the particle size of semiconductor crystallites from X-ray patterns was estimated less than 10 nm. From absorption spectra, it is obtained that the absorption edges shifted to short wavelength direction when Zn contents increased, and the absorption edge can be adjusted from 2.46 eV to 2.96 eV by controlling Zn contents. The third-order nonlinear optical susceptibility was studied at 532 nm with 8 ns pulse laser by degenerate four wave mixing (DFWM) technique.     

Effect of lanthanum ions on tRNAphe structure: Imino proton NMR spectroscopy

The effect of lanthanum ions on the structural and conformational change of yeast tRNA Phe was studied by 1H NMR. The results suggest that the tertiary base pair (G-15)(C-48), which was located in the terminal in the augmented dihydrouridine helix (D-helix), was markedly affected by adding La 3+ and shifted 0.33 downfield. Based pair (U-8)(A-14), which is associated with a tertiary interaction, links the base of the acceptor stem to the D-stem and anchors the elbow of the L structure, shifted 0.20 upfield. Another imino proton that may be affected by La 3+ in tRNA Phe is the tertiary base pair (G-19)(C-56). The assignment of this resonance is tentative since it is located in the region of highly overlapping resonances between 12.6 and 12.2. This base pair helps to anchor the D-loop to the TΨC loop.     

Calculation method of electronic structure and its application to (I h andI) fullerenes

A new calculation method was discussed to treat the Hückel Hamiltonian of any fullerene with a certain point group symmetry. This method was applied to calculating the electronic energy levels of icosahedral fullerenes C\-n(I\-h: n=60h 2, 0相似文献   

Shear-wave splitting and anisotropy in crust of Dabieshan orogenic belt

The shear-wave splitting was analyzed on the deep seismic sounding profile crossing the Dabieshan area. The direction difference between Sg and SmS fast wave polarization indicates that the modem regional tectonic stress field in the Dabieshan area exists only in uppcr crust, while the crack alignment caused by the Triassic collision between the North China and the Yangtze blocks had been preserved in mid-lower curst.     

Identification and classification of subspecies of Asian cultivated rice and their hybrids

Having reviewed the major classification systems proposed by various scholars across the world, it is found thatindica andjaponica underO. sativa L. are two major directions thoroughly differentiated from the Asian cultivated rice, forming the framework of the classification structure. A system withindica andjaponica as the only two subspecies is therefore reiterated. There are various ways to determine the indica-japonica identity of hybrid rice, but the “combined morphological trait index” (CMT index) method is more efficient and easier to handle, although the isozyme analysis, molecular marker analysis and grain quality assay methods are also feasible.     

Carbon isotope anomaly in marbles associated with eclogites from the Dabie Mountains

This is a report of carbon isotope anomaly in marbles associated with the UHP eclogites from the Dabie Mountains. The results place constraints on the degree of crust-mantle interaction during the UHP metamorphism.     

Preparation of InSb nanocrystals embedded in SiO2 thin films

InSb nanocrystals embedded in SiO₂ thin films were prepared by rf magnetron cosputtering technique. THe observation by transmission electron microscope showed that InSb nanocrystals dispersed uniformly in SiO₂ matrices. InSb nanocrystals with different sizes can be obtained by changing the annealing condition. The average size of InSb nanocrystals depended on annealing temperature and time, but not on the t_1/3 rules. X-ray photoelectron spectroscopy and X-ray diffraction were also applied to the analyses of the composite thin films.     

Diamond synthesis from a system of chromium-carbide and Ni70Mn25Co5 alloy

In order to ascertain the mechanism of interaction between carbide and metallic catalyst and formation of diamond under high pressure and high temperature, and find a new method to synthesize diamond with special properties, it is necessary to investigate the reaction behavior of different carbides and metallic solvent_catalysts under high pressure and high temperature. A system of Cr-3C-2 powder and Ni 70Mn 25Co 5 alloy in weight ratio of 1∶6 was treated under 6 0 GPa and 1 500℃ for 20, 30 or 60 min respectively. X_ray diffraction of the samples indicated the Cr 3C 2 decomposed partially after high pressure and temperature treatment, and Cr 7C 3, Cr and diamond formed respectively. There was not any trace of graphite in the samples. The result suggested that the separated carbon atoms could form diamond directly without conversion process of graphite into diamond. The observation of SEI, WDX and EDX also showed that diamond crystals were synthesized in the system, which have perfect surfaces and shapes, with the average grain size of about 40 μm. The properties of the crystals are being investigated.     

The neodymium isotopic characteristic and geological significance of Kuokesu plagioclase amphibolites from the Kuruktag, Xinjiang, China

The plagioclase amphibolites from Kuokesu area, Kuruktag, Xinjiang occur as enclaves embedded in the granodioritic gneiss. In the light of major elements and REE data, the parent rocks of the plagioclase amphibolites belong to weak_alkaline basalts. Their Nd model ages mainly range from 2 832 to 3 075 Ma. The seven plagioclase amphibolites yield a reasonable good isochron age of (828±86) Ma(2σ) with I Nd =0.510 981±82, ε Nd ( t )=-11.5±1.6. Such a case shows the existence of great proportion of the Archaean mafic crustal basement on the Kuokesu area. The strong tectonic_thermal event at about 820 Ma made the Sm_Nd isotope of the metamorphic rocks homogenization. This event would be associated with the Tarim Movement.