拟塑性流体理论中一类奇异非线性边界值问题

研究了起源于拟塑性流体理论中的一类奇异非线性两点边界值问题正确的存在性和唯一性。     

高氯氧化锌烟尘浓硫酸脱氯的影响因素

研究了浓硫酸用量、固化反应时间、物料粒度对浓硫酸法脱氯的影响。结果表明,随着浓硫酸用量增加脱氯率增大,当烟尘酸量达到０．５２ｍｌ／ｇ时,再继续增加酸量,脱氯率反而下降;固化反应时间与脱氯率呈线性关系,随着固化反应时间的延长,脱氯率增大;氯化锌烟尘粒度在６０￣１７５μｍ范围内,对脱氯率影响不大。     

结晶器内连铸坯热弹塑性应力的有限元分析

建立了结晶器内连铸坯热弹塑性应力有限元分析模型,在推导的热弹塑性本构方程中考虑了材料力学性能,屈服函数随温度和应变速率的变化,模拟计算了结晶器内连铸坏应力分布。模拟结果表明,在铸坯的热节约内,高温坯壳受到拉应力的作用,易于产生裂纹,从而说明铸坯偏角区形成的热节约是连铸坯裂纹缺陷乃至漏钢事故发生的诱因。     

阳离子交换树脂催化合成1—萘乙酸甲酯的研究

本文研究了用强酸性阳离子交换树脂作催化剂,１—萘乙酸和甲醇直接酯化合成１—萘乙酸甲酯的反应。考察了催化剂用量,反应物料配比,反应时间等因素对产率的影响,通过正交实验,找到了较佳反应条件：当催化剂用量为反应液的３％,醇酸摩尔比为２０～３０,在回流温度下反应４小时,酯的收率＞９２％,纯度＞９９％。该法工艺简单,操作方便,无三废污染,适合工业化生产。     

一维双向耦合映象网络及其应用

全局耦合映象具有硬件集成化实现不便的缺点,为此本文研究了各混沌神经元之间局部耦全的一维双向耦合混沌神经网络,发现它同样具有全局耦合映象的分类功能,对一维双向耦合网络的动态特性进行了分析,提出了利用网络的时空特性对信息进行存储的思想,并提出了将其应用到保密通信的初步设想。     

甲氰菊酯与单甲脒复配对桔全爪螨Pnonychus citri的增效作用研究

将甲氰菊酯和单甲脒通过复配对桔全爪螨进行室内毒力测定,表明两种药剂的各种配比均对桔全爪螨存在着不同程度的增效作用,其中以甲氰菊酯与单甲脒按1:4的比例复配增效作用最为明显,共毒系数达到373。田间药效试验也表明,20％的混剂乳油(4％甲氰菊酯 16％单甲脒)的药效明显高于20％的甲氰菊酯乳油和25％的单甲脒乳油。     

The v-v energy transfer of highly vibrationally excited states (I)

The relaxation of the highly vibrationally excited CO (v = 1–8) by CO₂ is studied by timeresolved Fourier transform infrared emission spectroscopy (TR FTIR). 193 nm laser photolysis of the mixture of CHBr₃ with O₂ generates the highly vibrationally excited CO(v) molecules. TR FTIR records the intense infrared emission of CO(v→v-1). The vibrational populations of each level of CO(v) have been determined by the method of spectral simulation. Based on the evolution of the time resolved populations and the differential method, 8 energy transfer rate constants of CO(v = 1–8) to CO₂ molecules areobtained: (5.7±0.1), (5.9±0.1), (5.2±0.2), (3.4±0.2), (2.4±0.3), (2.2±0.4), (2.0±0.4) and (1.8±0.6) (10¹⁴ cm³ · molecule⁻¹ · s⁻¹), respectively. A two-channel energy transfer model can explain the feature of the quenching of CO(v) by CO². For the lower vibrational states of CO, the vibrational energy transfers preferentially to the u³ mode of CO² For the higher levels, the major quenching channel changes to the vibrational energy exchange between CO(v→v-1) and the u¹ mode of CO².     

Neuropeptide Y receptors in a protozoaStylonychia mytilus

Radio ligand binding assays(RLBA) were used to study neuropeptide Y (NPY) receptors in a protozoa Stylonychia mytilus. The experimental results showed that 2-3×10+3/mL Stylonychia cells incubated in Pringsheim solution which contained 3H-NPY could specifically bind 3H-NPY and concomitantly present saturable characteristic. This suggested that Stylonychia possessed some specific binding sites for NPY. Scatchard transformations of binding assay for the NPY receptors at 25℃ are compatible with the specific activity of 42.47 fmol/10+3 cells and the binding equilibrium constant of 0.113 nmol/L. The data of 125I-NPY binding assay to the membrane protein extract of Stylonychia indicated that there was a significant difference between the amount of total bound and nonspecific bound of 125I-NPY. This result indicated that NPY receptors were probably localized mainly on the cell membrane.     

补偿扰动的PWM逆变器无差拍控制

提出了两种ＰＷＭ逆变器的改进无差拍控制算法．这两种算法根据ＰＷＭ逆变器的状态方程,分别采用直接补偿扰动和最优预见控制技术,利用未来信息决定当前的控制输入．使用ＭＡＴＬＡＢ软件对这两种算法进行了仿真．结果表明,当存在随机扰动及电路参数变化时,所提出的两种算法的控制效果均比不考虑补偿扰动的无差拍算法有较大改善．因此,该两种控制算法能够有效地抑制电路参数变化引起的或来自外部的扰动,使输出电压能很好地跟踪参考电压,控制响应快,鲁棒性好．     

煤中前沥青烯与沥青烯性质的研究

煤的溶剂抽出物中前沥青烯与沥青烯的质量之比随煤化程度增加而增加。原位热解红外光谱研究结果表明,它们的热稳定性与其结构参数有关,芳香度高,甲基取代结构多的前沥青烯比沥青烯的热稳定性好。前沥青烯与沥青烯在溶剂分级过程中表现出的溶解性与其结构参数无必然联系,而与其酸碱组分间的氢键强度有关。前沥青烯中酸碱组分间的氢键强度为５．１５～３０．９ｋＪ／ｍｏｌ;沥青烯为＜５．１５ｋＪ／ｍｏｌ。