Improved dehydriding property of polyvinylpyrrolidone coated Mg-Ni hydrogen storage nano-composite prepared by hydriding combustion synthesis and wet mechanical milling

In this work, polyvinylpyrrolidone(PVP) coated Mg_(95)Ni_5 nano-composites were prepared by hydriding combustion synthesis(HCS) plus wet mechanical milling(WM) with tetrahydrofuran(THF) and donated as WM-x wt% PVP(x = 1, 3, 5 and 7) respectively. The phase compositions, microstructures and dehydriding property, as well as the co-effect of PVP and THF were investigated in detail. XRD results showed that the average crystal size of MgH_2 in the milled Mg_(95)Ni_5 decreased from 23 nm without PVP to 18 nm with 1 wt% PVP. The peak temperature of dehydrogenation of MgH_2 in the milled Mg_(95)Ni_5 decreased from 293.0 ℃ without THF to 250.4 ℃ with THF. The apparent activation energy for decomposition of MgH_2 in WM-7 wt% PVP was estimated to be 66.94 kJ/mol, which is 37.70 kJ/mol lower than that of milled Mg_(95)Ni_5 without THF and PVP. PVP and THF can facilitate the refinement of particle size during mechanical milling process. Attributed to small particle sizes and synergistic effect of PVP and THF, the composites exhibit markedly improved dehydriding properties.     

Effect of minor Sc on the microstructure and mechanical properties of AZ91 Magnesium Alloy

The as-cast and heat-treated microstructures and mechanical properties of the AZ91 magnesium alloys with and without minor Sc addition were investigated and compared in this paper. The results indicated that adding0.15–0.45 wt% Sc to the as-cast AZ91 alloy not only could modify and refine the Mg_(17)Al_(12) phase but also suppress the formation of the Mg_(17)Al_(12) phase. At the same time, the grains of the Sc-containing as-cast AZ91 alloys were also effectively refined. As a result, the mechanical properties at room temperature(RT) for the Sccontaining as-cast AZ91 alloys were effectively improved. In addition, adding 0.15–0.45 wt%Sc to the AZ91 alloy promoted the formation of the continuous precipitates(CP) during the aging treatment in spite of that the formation of the discontinuous precipitates(DP) was simultaneously suppressed. Accordingly, the Sc-containing as-aged AZ91 alloys obtained the relatively higher mechanical properties at RT than the as-aged AZ91 alloy.     

钢渣吸附去除水中亚甲基蓝

通过静态批式实验研究钢渣对亚甲基蓝吸附行为的影响.结果表明:亚甲基蓝去除率随钢渣投加量的增加而增大,随初始浓度的升高而降低,而单位钢渣质量下亚甲基蓝的吸附量呈相反趋势.溶液初始pH值为4时最有利于钢渣吸附亚甲基蓝.钢渣吸附亚甲基蓝符合Lagergren准一级动力学方程,平衡吸附量随亚甲基蓝初始质量浓度的增加而增大,随钢渣投加量增加而减小.结合Freundlich等温吸附方程发现,钢渣对亚甲基蓝的吸附是以离子交换作用为主的优惠型吸附.亚甲基蓝阳离子在静电力作用下吸附在钢渣表面,并与CaO等反应形成聚合物,增强吸附效能.     

基于脉搏波数学模型的运动员运动状态判别方法

针对利用运动员脉搏波信息对其运动状态(高强度运动、平静)进行判别,并减少身体状态的随机性对脉搏波特征信息的影响问题,提出了一种对原始脉搏波信号进行建模进而提取特征信息进行状态判别的方法.利用训练-测试的二分类分析方式,对运动员的心率状态进行判别,以分析运动员的运动状态,辅助其进行运动训练工作.实验通过对10名运动员志愿者在不同状态下进行脉搏波采集,对预处理后的原始信号进行函数建模并提取生理信息,利用SVM进行监督训练和测试.结果表明,该方法能够对运动员心率状态进行有效判别,得到运动员的运动状态.     

基于专利分析的中国海洋生物肥料发展现状与发展建议

【目的】为了解国内海洋生物肥料的知识产权现状,明确海洋生物肥料的研究热点及其发展趋势。【方法】对国内有关海洋生物肥料的公开专利进行检索分析,主要从年度专利申请量、区域分布、技术领域、申请机构类型和词频分析进行数据整理。【结果】海洋生物肥料专利申请数量增长迅速,其中山东省在海洋生物资源农业应用领域领先全国,广西位于全国前列。企业在专利申请数量上远高于科研院所和高校。62%专利涉及的相关工艺为海洋原材料简单物化处理技术,其他的则为采用微生物发酵或酶解技术。专利词频分析表明,海藻是海洋生物肥料领域使用最普遍的原材料。【结论】海洋生物肥料市场潜力巨大,但其在应用上仍处于原材料收集利用的初级阶段,深入挖掘利用海洋微生物资源能够促进生物肥料产业的升级换代。广西拥有丰富的海洋生物资源,也有微生物工业应用的经验和基础,研发人员应在原有海洋生物利用的基础上,充分利用海洋微生物资源提升产品功效,促进广西农业绿色发展。     

珍珠岩矿床地质背景研究进展

从矿床地质特征、成矿时代、岩石地球化学、大地构造背景、火山喷发模式及岩浆来源、水的赋存形式及来源、水化蚀变、矿床成因等方面对世界珍珠岩地质背景进行了综述.结果表明珍珠岩的形成过程和成矿物化条件方面尚有许多具体问题未进行合理的解释,限制了珍珠岩成岩-成矿理论和找矿实践的深入研究.最后,对今后珍珠岩研究中存在问题和发展趋势给出了具体建议.     

基于语料库的虚拟语气研究简

基于语料库的虚拟语气研究表明：中国英语学习者在使用虚拟语气方面并不理想,不同水平学习者在使用上存在差异,学习者的英语水平与误用的频率正相关,产生误用的原因主要是语际迁移,语内迁移、教学失误等.     

A Hyper-Erlang Jump-Diffusion Process and Applications in Finance

This paper studies the first passage time problem for a reflected two-sided jump-diffusion risk model with the jumps having a hyper-Erlang distribution. The authors give the explicit closed-form expression for the joint Laplace transform of the first passage time and the overshoot for the reflected process. Finally, the formula is applied to the ruin problem under the barrier dividend strategy and the pricing of the Russian option.     

区域创新方法应用推广体系建设研究——以宁夏为例

创新方法应用推广体系建设是创新方法工作开展的基础,文章总结了创新方法工作的总体要求,分析了创新方法应用推广体系建设的目标与要求,以宁夏为例提出了从组织管理、工作推进、推广服务、培训、专家咨询、宣传传播、政策保障、对外交流合作等体系建设方面如何构建区域创新方法应用推广体系,并详细阐述了各体系的构成与内容,为各省区创新方法工作的深入开展提供参考和支撑。     

基于顾客偏好的瓶装水外观感性质量评价

从感性质量评价的角度提取13个感性质量评价词对,用于全面且针对性地评价顾客对瓶装水的偏好.以"想购买"为综合感性提取瓶装水的感性质量评价要素,结合聚类分析等方法确定7种代表性样本.基于语义差异法构建瓶装水感性质量评价量表,运用多元回归模型分析建立顾客偏好与感性评价词对之间的关系模型.关系模型解决了如何识别顾客偏好和感性质量需求,以及如何将这些偏好和需求整合到产品设计过程中的问题.