Improved dehydriding property of polyvinylpyrrolidone coated Mg-Ni hydrogen storage nano-composite prepared by hydriding combustion synthesis and wet mechanical milling

In this work, polyvinylpyrrolidone(PVP) coated Mg_(95)Ni_5 nano-composites were prepared by hydriding combustion synthesis(HCS) plus wet mechanical milling(WM) with tetrahydrofuran(THF) and donated as WM-x wt% PVP(x = 1, 3, 5 and 7) respectively. The phase compositions, microstructures and dehydriding property, as well as the co-effect of PVP and THF were investigated in detail. XRD results showed that the average crystal size of MgH_2 in the milled Mg_(95)Ni_5 decreased from 23 nm without PVP to 18 nm with 1 wt% PVP. The peak temperature of dehydrogenation of MgH_2 in the milled Mg_(95)Ni_5 decreased from 293.0 ℃ without THF to 250.4 ℃ with THF. The apparent activation energy for decomposition of MgH_2 in WM-7 wt% PVP was estimated to be 66.94 kJ/mol, which is 37.70 kJ/mol lower than that of milled Mg_(95)Ni_5 without THF and PVP. PVP and THF can facilitate the refinement of particle size during mechanical milling process. Attributed to small particle sizes and synergistic effect of PVP and THF, the composites exhibit markedly improved dehydriding properties.     

Na0.5Bi0.5TiO3-BaTiO3无铅压电陶瓷制备及性能

研究了不同烧结制度下的NBBT6陶瓷的致密度、介电和压电性能.870℃左右预烧,可以得到致密且压电和介电性能较好的陶瓷(d33=107 pC/N.∈r=750,tanδ为3.23%).通过相应的粒度分析可知,提高预烧温度对粒度的影响不太大,但可用于湿法制备工艺中的原材料制备,解决湿法工艺中材料易被极性水分子解离而影响材料组分的问题.加入少量的BaTiO3到NBT中形成NBT-BT的固溶体,通过对压电介电性能及XRD的分析可知.当质量分数x=0.06时.(1-x)Na0.5Bi0.5TiO3-xBaTiO3晶体结构出现由三方相到四方相的转变,此时的性能达到最大值(d33=114 pC/N,∈r=1 173.tanδ为3.4%).     

相空间重构中嵌入维和时间延迟的选择

提出了一种用于相空间重构的嵌入维和时间延迟自动算法，它利用混沌时间序列的去偏复自相关函数的零点来确定时间延迟，有效地降低了平均位移法跟踪平均位移量斜率变化的随意性所造成的计算误差，并借助于复自相关法和Г-test的迭代计算求得准最佳的嵌入维和时间延迟参数．该算法具有较充分的理论依据，其计算复杂度不大，对数据长度的依赖性不强．仿真实验结果表明，用该算法计算标准混沌时间序列关联维的相对误差由传统算法的4．4％降低到1．06％，有效地提高了计算相空间重构中不变量的精度．     

几个广义Apostol-Bernoulli、Apostol-Euler多项式之间的关系式

利用发生函数理论结合某些运算技巧,推出了几个广义Apostol-Bernoulli多项式、广义Apostol-Euler多项式之间的关系式.多个参数出现在等式中,非常工整.在关系式中选取适当的参数,就可以得到已有的著名的关于广义Bernoulli多项式、广义Euler多项式之间的关系式,从而深化和推广了对Bernoulli数、Euler数、Bernoulli多项式、Euler多项式的相关研究结果.     

不同条件下钙基固硫剂的固硫机理

为了探求煤燃烧过程中传统钙基固硫剂固硫率低下的原因,本实验选用有代表性的含硫为2．92％的国家标准煤样,在不同条件下系统的研究了钙基固硫剂的固硫特性和固硫产物CaSO4的分解率;并分析了其固硫机理．实验结果表明:传统钙基固硫剂固硫效率低下的原因为高温下CaO化学结构的变化和固硫产物CaSO4的分解。该研究对改进传统钙基固硫剂的固硫效果有一定的理论指导意义。     

基于位置的参与式感知服务

以共享为核心理念,探索一种新型的可扩展的LBS——基于位置的参与式感知服务(LBPSS),用于解决当前LBS系统POI更新缓慢、数据采集困难以及用户黏性小等问题。详细设计了LBPSS系统的架构,并分析LBPSS相比于LBS的优势及特点。针对LBPSS的具体实现问题,提出隐私保护、参与激励机制、数据可信验证、数据挖掘和数据可视化五项关键技术。LBPSS用户能够基于位置提供数据同时获取数据及服务,实现更多类型数据的采集与数据共享利用。最后结合ArcGIS Server和Android平台实现LBPSS在空气质量监控中的应用,验证LBPSS的可行性和有效性。     

兰州黄河岸边卵石层大吨位桩基自平衡法试验研究

对兰州深安黄河大桥进行桩基自平衡法试验。在对黄河岸边的岩土层进行桩基试验时,对桩基的极限侧阻力和端阻力标准值的取值提出建议,并在兰州地区进行自平衡法桩基试验时,对桩基侧摩阻力的取值提出建议。     

Design and fabrication of 1-D semiconductor nanomaterials for high-performance photovoltaics

To date, the cost-effective utilization of solar energy by photovoltaics for large-scale deployment remains challenging. Further cost minimization and efficiency maximization, through reduction of material consumption, simplification of device fabrication as well as optimization of device structure and geometry, are required. The usage of 1D nanomaterials is attractive due to the outstanding light coupling effect, the ease of fabrication, and integration with one-dimensional(1-D) semiconductor materials. The light absorption efficiency can be enhanced significantly, and the corresponding light-toelectricity conversion efficiency can be as high as their bulk counterparts. Also, the amount of active materials used can be reduced. This review summarizes the recent development of 1-D nanomaterials for photovoltaic applications, including the anti-reflection, the light absorption,the minority diffusion, and the semiconductor junction properties. With solid progress and prospect shown in the past 10 years, 1-D semiconductor nanomaterials are attractive and promising for the realization of high-efficiency and low-cost solar cells.     

一种新的数字调速器的设计及实验

目的研制用于柴油发电机组的数字调速系统。方法采用单片机技术,用值流永磁伺服电机作为执行器组成新的调速系统。使用变速积分ＰＩＤ算法。合理选择控制周期,达到了速控制,可在７００－１５００ｒ．ｍｉｎ＾－１范围内取得较好的主财速指标。