CoPt-Co hybrid supported on amino modified SiO_2 nanospheres as a high performance catalyst for hydrogen generation from ammonia borane

CoPt-Co hybrids were successfully supported on amino modified SiO_2 nanospheres by a chemical reduction method at a temperature of 278 K.The solid carrier i.e.amino modified SiO_2,provides numerous anchoring sites for the metal nanoparticles(NPs)to improve the dispersion while reducing the size of metal NPs.The supported NPs displayed a narrow particle size distribution on the SiO_2 surface with an average diameter of 12 nm.The XRD results alongside with the binary alloy phase diagram suggest that the resulted NPs are bimetallic,composed of CoPt and amorphous Co.Among the prepared materials,the solid with the specific composition of SiO_2@Pt_(0.1)Co_(0.9)was proved to be effective catalyst for ammonia borane(AB)hydrolysis in aqueous solution.The turnover frequency(TOF)value of the supported nanocatalyst was 25.59mol_(H_2)min~(-1)·mol_M~(-1),almost twice as that of unsupported Pt_(0.1)Co_(0.9)NPs while the activation energy was 37.05 kJ mol~(-1).Furthermore,the SiO_2@Pt_(0.1)Co_(0.9)composite manifested high catalytic activity even after five cycles of reuse.     

Test for Heteroscedasticity in Partially Linear Regression Models

Testing heteroscedasticity determines whether the regression model can predict the dependent variable consistently across all values of the explanatory variables. Since the proposed tests could not detect heteroscedasticity in all cases, more precisely in heavy-tailed distributions, the authors established new comprehensive test statistic based on Levene's test. The authors built the asymptotic normality of the test statistic under the null hypothesis of homoscedasticity based on the recent theory of analysis of variance for the infinite factors level. The proposed test uses the residuals from a regression model fit of the mean function with Levene's test to assess homogeneity of variance. Simulation studies show that our test yields better than other methods in almost all cases even if the variance is a nonlinear function. Finally, the proposed method is implemented through a real data-set.     

休闲视角下哈大齐城市群体育社团发展研究

运用文献资料、问卷调查、访谈、数理统计和逻辑分析等调查方法,对哈大齐城市群体育社团的发展概况、形成时间、注册情况、体育社团负责人情况、办公场所及活动场地设施情况、组织活动、经费来源渠道等方面的现状进行了详细的调查研究.在此基础上分析哈大齐城市群体育社团发展的优势以及面临的困难和需要解决的问题,并借鉴国内外社团发展经验,提出相应的意见和建议,为体育社团在黑龙江省更好地发展提供理论参考依据.     

浅谈水泥稳定碎石基层的质量控制

通过对基层的设计、试验、施工等各个环节的控制，提高水泥稳定碎石基层的强度，控制其裂缝的产生，从而保证工程质量。     

瞬变电磁法在一四井煤矿采空区探测中的应用

采用瞬变电磁法(TEM)在河南省新密市境内探查一四井煤矿采空区积水分布情况、断层等构造的含导水性情况及二1煤底板的富水性情况,为矿井防治水工作的合理实施提供依据.     

3类图的优美标号

用构造的方法给出图1-3n-K3,P(n,2,n-1)和I(K_(1,1,n))的优美标号,从而证明了1-3n-K_3,P(n,2,n-1)和I(K_(1,1,n))都是优美图.     

两类图完美匹配的计数公式

利用划分、求和、再递推的方法给出图2-nRO_8和图2-F_(2n+1,4)完美匹配数目的计算公式.进一步,用所给的方法可计算出许多图类的所有完美匹配的数目.     

基于分方向选择搜索的多目标进化算法

Pareto 解空间为分区域连续时,基于极大极小策略和确定权重的多目标进化算法在进化的每一代都会在无最优解的区域搜索解点.为解决此问题,文中提出了一种新的判断机制,根据每个权重在不同方向上选取的解点集来判断权重对应的Pareto有效解区域是否存在最优解点,并以此来调整搜索的区域;为了避免算法陷入局部收敛和种群早熟,提出...