Effect of particle size distribution on the microstructure,texture,and mechanical properties of Al–Mg–Si–Cu alloy

The effect of particle size distribution on the microstructure,texture,and mechanical properties of Al–Mg–Si–Cu alloy was investigated on the basis of the mechanical properties,microstructure,and texture of the alloy.The results show that the particle size distribution influences the microstructure and the final mechanical properties but only slightly influences the recrystallization texture.After the pre-aging treatment and natural aging treatment(T4 P treatment),in contrast to the sheet with a uniform particle size distribution,the sheet with a bimodal particle size distribution of large constituent particles and small dispersoids exhibits higher strength and a somewhat lower plastic strain ratio(r) and strain hardening exponent(n).After solution treatment,the sheet with a bimodal particle size distribution of large constituent particles and small dispersoids possesses a finer and slightly elongated grain structure compared with the sheet with a uniform particle size distribution.Additionally,they possess almost identical weak recrystallization textures,and their textures are dominated by CubeND {001}310 and P {011}122 orientations.     

Experimental investigation and thermodynamic assessment of the yttriumhydrogen binary system

A coupled experimental investigation and thermodynamic study of the yttrium-hydrogen(Y-H) binary system were carried out to provide more comprehensive and quantitative insights into the key thermodynamic properties of this system. Y-H system in the full range of H/Y = 0–3.0 was investigated by accurate pressure composition isotherm(PCI) measurement to provide credible phase equilibria information and thermodynamic data.The phase boundaries obtained were in agreement with previous experimental data but with improved accuracy.With the guide of the crystal structures, all the solid phases were modelled using the three sublattice model. The Y-H phase diagram and thermodynamic parameters were calculated and assessed with the CALPHAD technique.The obtained results are in very good agreement with our experimental data and the published data reported in literature. The obtained thermodynamic database of Y-H system can be used to predict the hydrogenation behavior and decomposition temperatures of hydrides.     

Influence of minor boron on the microstructures of a second generation Nibased single crystal superalloy

Boron is added into single crystal superalloys as a micro-alloying element to strengthen low angle grain boundaries.However,systematic investigations on the effect of boron on microstructures of single crystal superalloys are limitedly reported.The effect of boron on as-cast and heat-treated microstructures was investigated in two experimental Ni-based single crystal superalloys containing 3 wt% Re.The current results indicated that the volume fraction of(γ+γ′)eutectic and M_3B_2 borides was evidently increased,while the number of micropores was evidently decreased with the addition of 0.02 wt% boron.The(γ+γ′)eutectic could not be dissolved completely due to the lower incipient melting temperature caused by the formation of M_3B_2 borides.Meanwhile,the M_3B_2 borides were found to be enriched with indispensable strengthening elements Cr,Mo,W and Re,and this may lower the strengthening effect and cause stress concentration during high temperature creep.     

胶束增敏法测定乳酸环丙沙星的含量

研究了乳酸环丙沙星(CFLX)在胶束体系中的荧光特性,发现十二烷基硫酸钠(SDS)对CFLX有较强的增敏作用,据此建立了胶束增敏荧光光谱法测定环丙沙星的新方法。其线性范围为0~2.00μg/mL,检出限为1.32 ng/mL。     

植物吸收铁营养元素的分子机制研究进展

铁是植物生长必需的矿质元素,高等植物通过铁素吸收的机制I、机制II和可能的机制III--吞噬系统来适应缺铁胁迫.本文对植物吸收铁营养元素的分子机制及其相关基因的研究进展进行了综述.     

芳胺类光敏材料光谱性质的理论研究

了解芳胺类分子电子性质是理解其作为光敏材料、发光材料应用和进行分子设计的起点.采用DFT方法研究了3个芳胺类光敏剂的分子结构和光谱性质.B3LYP/6-311G**方法的频率计算表明,这些结构处于势能面的极小值点,是热力学稳定结构.在TD-DFT(Time-de-pendent DensiIy Funetional Theory)方法和PCM(Polarized Continuum Model)模型理论级别下计算了分子在CH2Cl2 溶液中的电子吸收光谱.计算揭示化合物中N原子以p(π)电子与苯环形成共轭关系,从而有利于电子在整个分子范围内的移动;通过激发态波函数分析,把最低能吸收谱带归属为霄π→π*电子跃迁性质.     

A hybrid hydrogel/textile composite as flame-resistant dress

Currently, the functional and cost-effective flame-resistant textiles(FRTs) are on high demand. However, such FRTs based on general polymer fabrics are always expensive, readily decompose, and their temperatures quickly rise once exposed to thermal environments. Inspired by the large specific heat of water and high decomposition temperature of inorganic substances like SiO₂, this study establishes a simple casting strategy for preparing flameresistant gel/textiles(FR-GTs). The finding...     

复合桩墙支护结构关键参数的灵敏度分析

通过有限元数值分析方法,利用全局有限差分法建立了灵敏度分析模型,并对诸多设计参数进行了计算分析,讨论了设计参数对复合桩墙支护结构的受力和变形影响,计算出设计参数的灵敏度因子,得到一些有参考价值的分析结果,为优化设计和施工提供一定的参考.     

硝酸铈铵在催化碳氮键形成上的应用研究

详细探讨硝酸铈铵作为催化剂在氮杂环类化合物的合成、氮杂Diels-Alder反应、氮杂Michael加成等碳氮键生成反应中的应用.     

基于模糊熵和结构特征的边缘检测方法

为了使检测的图像边缘结核定位好,并且产生边续的精细边缘,同时能有效滤除边缘图像中的噪声,提出一种基于模糊熵与边缘结构特征相结合的新的图像边缘检测方法。该方法首先将图像的灰度值特征空间转换为模糊熵特征空间,计算出每个像素在模糊熵特征空间的相异测度,结合3×3 邻域内的12种有效的边缘结构,提取图像中每个像素的结构信息测度图像阵列和方向信息测度图像阵列,然后对结构信息测度图像阵列和方向信息测度图像阵列实施非极大抑制,确定最终的边缘像素图像。实验结果表明该方法所检测出的图像边缘细节丰富,单像素宽,定位准确,有较好的抗噪性。