<Emphasis Type="Italic">In situ</Emphasis> boron isotope measurements of natural geological materials by LA-MC-ICP-MS

There are two main methods to determine boron isotopic composition. One is the solution method, in which boron is purified after the samples are dissolved in solution and the boron isotope ratios are determined by thermal ionization mass spectrometry (P-TIMS and N-TIMS) or multicollector inductively coupled plasma mass spectrometry (MC-ICP-MS). The other is an in-situ analysis method, in which the in-situ boron isotopic ratios in minerals are analyzed directly using secondary ion mass spectrometry (SIMS) or laser ablation multicollector inductively coupled plasma mass spectrometry (LA-MC-ICP-MS). In the in-situ analysis method for boron isotopes, the multifarious chemical purification and separation processes of the solution method are avoided, with increased work efficiency. In addition, the microzones and microbeddings of minerals can be analyzed in-situ to reveal the fine processes and conditions of mineral formation. In this study, using the standard-sample-bracketing (SSB) method, mass bias of the instrument and the fractionation of isotopes were calibrated, and the in-situ determination method of LA-MC-ICP-MS for boron isotopes was established. Through detailed analyses on a series of boron isotope standards and samples, a matrix effect was assessed but not detected, and the analysis results were in accordance with the formerly reported values or P-TIMS determined values, within the error range. The analytical results for IAEA B4 and IMR RB1 with relatively high boron contents were δ¹¹B = –(8.36±0.58)‰ (2σ, n=50) and δ¹¹B = –(12.96±0.97)‰ (2σ, n=57), respectively; the analytical result for IAEA B6 with relatively low boron content was δ¹¹B = –(3.29±1.12)‰ (2σ, n=35). In-situ measurements for B isotopes were performed on geological samples such as tourmaline, ulexite, ludwigite, inyoite and ascharite, with the results consistent with those determined by P-TIMS, within the error range.     

离散脉冲切换系统的H_∞控制

针对一类不确定离散脉冲切换系统,基于线性矩阵不等式、Lyapunov方法和H∞控制理论,给出了一个保证这类系统鲁棒稳定且具有γ鲁棒性能的充分条件.     

用于冷凝热回收的热水循环系统可行性研究

传统的冷凝热回收技术多是对夏季制冷工况的研究,很少涉及到冬季制热工况。研究基于热力学建模机理和冷凝热回收技术设计出一个热水循环辅助系统,它在夏季能够充分回收蒸汽压缩式热泵机组在制冷模式下运行产生的冷凝热,制取温度适中的生活热水储存于保温水箱,满足用户需求;在冬季可以吸收部分冷凝热后在蒸发器中释放热量,使液态制冷剂汽化,满足热泵机组制热模式的运行需求,可以代替传统热泵的地下水源或者土壤源子系统。以兰州市某宾馆的蒸汽压缩式热泵机组作为案例,设计了相应的热水循环辅助系统,并通过热力学仿真加以验证。结果表明,该热水循环辅助系统的实施在理论上是可行的,且在节能和降低系统初始投资方面效果明显。     

悬臂梁双晶压电能量采集装置的实验探究

为提高双晶压电振子的发电能力,探究了一种悬臂梁式双晶压电能量采集装置的发电性能。实验研究了振动台频率、激励位移、负载阻值和悬臂梁自由端质量块对悬臂梁式双晶压电能量采集装置输出电压和负载功率的影响,将两片双晶压电振子并联,探究了它们的发电性能。实验表明,存在谐振频率,使得输出电压最大;输出电压随着激励位移和负载阻值的增大而增大,并与激励位移呈一次函数关系;双晶压电振子外接匹配负载时,负载功率最大;随着质量块的质量在一定程度上的增加,输出电压随频率变化的曲线左移,峰值电压对应的频率变小;两片双晶压电振子并联且带匹配负载时,能有效提高负载功率。     

玄武岩纤维增强路用混凝土力学与开裂性能

为了提高路用混凝土的韧性和抗裂性能,研究了玄武岩纤维掺量为0,1,3,6和10 kg/m3的碎石稳定基层混凝土和C30混凝土的工作性,抗压强度,断裂能及早期抗裂性能.试验结果表明:玄武岩纤维掺量增加,混凝土工作性下降,但可通过减水剂调整以保证其工作性.玄武岩纤维对混凝土增强效果不明显.混凝土中掺加玄武岩纤维,其峰值荷载和最大变形量均有所提高,当玄武岩纤维掺量大于6 kg/m3时,混凝土断裂能增加30%～100%.当玄武岩纤维掺量大于3kg/m3,混凝土开裂面积降低了30%～70%,混凝土抗裂性能显著提高.此外,SEM表明玄武岩纤维与水泥基体密切结合可以有效吸收混凝土中的拉应力,因而提高了混凝土的阻裂能力.     

基于ARM9微处理器的嵌入式手持无线点菜系统的设计

针对现有点菜系统实时性和移动性差的问题,设计了一个基于ARM9S3C2440的新型嵌入式手持无线点菜系统.该系统在S3C2440内核基础上实现了μC/OSⅡ操作系统的移植,在图形构建软件μC/GUI下构建了整个系统的图形界面,根据设计需求实现了对点菜系统的程序功能.测试结果表明:在实时性和测试距离上效果良好,达到了应用指标.该设计对提高餐饮企业的服务质量,降低费用有积极的推动作用.     

岩体圆形洞室锚杆前后应力位移分析

探讨岩体内圆形洞锚杆支护前后的应力,位移解析解的变化,即围岩特征曲线,结合Ｌａｂｉｏｕｓｅ等的系列文章及其他有关资料,应用位移边理论、Ｌａｍｅ以式及弹塑性理论,编制了ＴＵＲＢＯＰａｓｃａｌ及Ｅｘｃｅｌ计算程序,评价洞室围岩的应力位移特征。     

Distribution and characterization of C31 sterane from cretaceous sediments and oils, Songliao Basin, China

Relatively high abundance of C₃₁ steranes has been identified from cretaceous source rocks and crude oils in the Songliao Basin, China. C₃₁ steranes which occur as ten isomers were tentatively identified as 4, 22, 23, 24-tetrametyhlcholestane based on their retention time and mass spectrum. They bear a lower thermal stability and occur as important components in the immature oils of Chaochang region because they have three-methyl groups in their side chain. The relatively high abundance of C₃₁ steranes in the samples can indicate the source input of some special algae in the brackish and saline environment. Therefore they can be used as very useful bimarkers for organic facies analysis and oil correlation. Their biological source perhaps related to the dinoflagellate such asG. foliaceum andP. foliaceum. The gorgostanol are considered as possible precursors for the putative C₃₁4-methyl sterane which formed in the stage of diagenesis.     

Experimental studies on silicate structures of basaltic glasses quenched at 1 65093 and 1–3.5 GPa

A series of melting experiments was carried cut at 1 650°C and 1.00–3.00 GPa using alkaline basalt as starting material. The cornpitions of quenched basaltic glasses in the products were detected by electron micro probe. Their CIPW norms were calculated and their refractive indices were determined by the oil-infused method. The Raman spectrum of the quenched basaltic glasses indicates that their main structural species are monomer [Si₂O₄]1⁴⁻, chain [Si₂O₆]1^4- and sheet [Si₂O₅]1^2-. The relationship at the same temperature between the proportions of integrated areas of structural species, and compositions and pressures was discussed.     

高效液相色谱手性固定相法直接测定不对称合成药物的光学纯度

在纤维素三（苯基氨基甲酸酯）涂敷的硅基高效液相色谱手性固定相上,以乙腈水为流动相,直接测定了一类不对称合成手性药物———甲砜霉素衍生物的光学纯度,结果比较理想．说明高效液相色谱手性固定相法是测定手性化合物光学纯度的一种简便可靠的方法．