现场红外透射方法研究甲醇水溶液体系在Pt-Ru上的电催化氧化过程

用电化学方法制备了Pt Ru催化剂,并对甲醇电氧化的催化效果进行了电化学测试;着重利用现场红外透射光谱方法研究了甲醇在Pt Ru电极上的电催化氧化过程以及催化剂中Ru组分的含量对甲醇电氧化的影响.发现当w(Ru)=13%时未测到有害中间产物CO,但w(Ru)=9%时则出现线性吸附CO的红外吸收峰,从而影响其催化活性.进一步认识了Pt Ru催化剂对甲醇电氧化的催化机理.     

硫酸化的SBA-15负载Cr2O3催化剂上丙烷CO2氧化脱氢

合成了一系列表面经硫酸铵处理的SBA-15负载Cr2O3催化剂,研究了这些催化剂对于丙烷CO2氧化脱氢反应的活性．结果发现,载体表面硫酸化后催化剂的活性大大增加．表征结果表明催化剂活性的提高与硫酸化后催化剂表面含有较多量的Cr^6 有关,而与表面酸性的增强无关．但载体表面硫酸化后由于积碳严重,催化剂的失活也随之加快．     

沙博理翻译成就与翻译思想研究

沙博理在翻译中国文学作品、传播中国优秀文化方面取得了令人瞩目的成就。结合沙先生的生平和历史背景,梳理其翻译成果,分析其翻译风格和翻译思想,阐述其英译作品在中西方文化交流中的现实意义和学术意义,以深切纪念这位翻译名家,并引起翻译界对我国现当代文学作品英译的重视。     

铜在鸭跖草细胞内的分布和化学形态研究

运用差速离心法和化学试剂逐步提取法分析了Cu在鸭跖草Commelina communis根、茎、叶的亚细胞分布及贮存形态.结果表明,细胞壁是鸭跖草根中Cu结合的主要位点,其次为含核糖核蛋白体的细胞溶质部分,而在叶中,Cu主要分布在含核糖核蛋白体的细胞溶质部分中,其次分布在含细胞壁部分;茎中,随着外界Cu浓度的提高,Cu向细胞壁部分的分配减少,而向含核糖核蛋白体的细胞溶质部分的分配增加.根、茎、叶中细胞核、叶绿体和线粒体等细胞器结合Cu量较少.在各种形态铜中,根部以去离子水提取态占优势,茎部和叶部,以去离子水和乙醇两种提取态占优势,其它结合形态的Cu在根中比例较低,在茎、叶中所占的比例有所增加,显示鸭跖草体内Cu的分布特征和形态特征与其耐性和富集Cu有密切联系.     

修饰剂对Ru/ZrO2·x H2O催化剂苯选择加氢反应的影响

采用共沉淀法制备了Ru/ZrO2·x H2O催化剂,研究了几种修饰剂对Ru/ZrO2·x H2O催化剂苯选择加氢反应性能的影响.结果表明在催化剂前驱体还原过程中,加入适量的硫酸锌可使环己烯得率达到43.4%;在苯-水反应液中加入适量的甲醇,能够使环己烯得率与未加入时相比增加3%;而一些助催化剂对Ru/ZrO2·x H2O催化剂的选择性影响各不相同.     

Deletion of an electron donor-binding subunit of the NDH-1 complex,NdhS, results in a heat-sensitive growth phenotype in Synechocystis sp. PCC 6803

In cyanobacteria and higher plants, NdhS is suggested to be an electron donor-binding subunit of NADPH dehydrogenase （NDH-1） complexes and its absence impairs NDH-l-dependent cyclic electron trans- port around photosystem I （NDH-CET）. Despite significant advances in the study of NdhS during recent years, its functional role in resisting heat stress is poorly understood. Here, our results revealed that the absence of NdhS resulted in a serious heat-sensitive growth phenotype in the uni- cellular cyanobacterium Synechocystis sp. strain PCC 6803. Furthermore, the rapid and significant increase in NDH-CET caused by heat treatment was completely abolished, and the repair of photosystem II under heat stress conditions was greatly impaired when compared to that of other photosynthetic apparatus in the thylakoid membrane. We therefore conclude that NdhS plays an important role in resistance to heat stress, possibly by stabilizing the electron input module of cyanobacterial NDH-1 complexes.     

First Best Efficiency in Group Incentives

1　IntroductionItiswellknownthatmoralhazardproblemoccursinsingle-agentcasewithuncertaintyinproduction,whereastherewouldbefree-riderinmultiple-agentscaseevenifthereisnouncertaintyinoutput,becauseagentswhocheatcannotbeidentifiedifjointoutputistheonlyobservableindicatorofinputs.Thedifficultyofcalculatingindividualcontributiontojoinedoutputmakesitmorecomplicatedtodesignefficientincentivemechanismsforagroupthanforasingleagent.AgencyTheoryindicatesthatwhenasingleagentisriskneutral,acontractthatgives…     

关于抛物型方程的一种线条法

本文对于热传方程运用线条法形成常微分方程系统:就空间变量的离散化,二阶偏导数项在邻接左、右边界的两根线条上采用三点对称格式〔截断误差为O(h~2)〕,在中间其余线条上采用五点对称格式〔截断误差为O(h~4)〕,注意到常微分方程组的系数阵具有全为负的本征值,本文应用A_0一稳定的P阶线性方法,证明数值解与偏微分方程精确解之间整体误差可达O(h~(4p)/(p+1)),接近O(h~4)。这表明,在有局部的低阶离散化误差的情况下仍可获得高阶的整体误差。     

完全广义强非线性拟补问题的逼近解

研究并构造了Ｈｉｌｂｅｒｔ空间中完全广义强的非线性拟补问题的逼近解的新的迭代算法．作为特例，概括了解补问题的许多熟知的算法．进一步地，证明了新的算法产生的迭代序列的收敛性．     

Superconducting Properties and Microstructure in MgB2 Bulks, Wires and Tapes

We prepared a series of MgB2 bulk samples under different temperatures, holding time and increasing rates in temperature by the solid state reaction. The thermodynamic behavior and phase formation in the Mg-B system were studied by using DTA, XRD and SEM. The results indicate that the formation of the MgB2 phase is very fast and the high increasing rate in temperature is necessary to obtain high quality MgB2. In addition, the effects of the Zr-doping in Mg1-xZrxB2 bulk samples fabricated by the solid state reaction at ambient pressure on phase compositions, microstructure and flux pinning behavior were investigated by using XRD, SQUID magnetometer, SEM and TEM. Critical current density Jc can be significantly enhanced by the Zr-doping and the best data are achieved in Mg0.9Zr0.1B2. For this sample, Jc values are remarkably improved to 1. 83 × 106 A/cm2 in self-field and 5. 51 × 105 A/cm2in 1T at 20K. Also, high quality MgB2/Ta/Cu wires and tapes with and without Ti-doping, MgB2/Fe wires and 18 filamen