玉米芯吸附协同低温等离子体对H2S的去除作用研究

为解决低温等离子体高压放电后产生的副产物排放问题,采用玉米芯吸附协同低温等离子体系统来降解硫化氢恶臭气体。确定了电极放电特性参数,考察NTP中的极间电压、H2S初始浓度和CA协同对H2S降解的影响,并分析H2S降解机理。研究表明,CA协同NTP系统能显著提高H2S去除效率,当采用负极放电,极板间距40mm,极间电压15KV,H2S初始浓度为500ppb,吸附时间60min时,CA协同NTP去除H2S的去除率可达到90%以上。     

线接触副球墨铸铁表面激光织构对摩擦学特性的影响

为研究线接触情况下激光表面织构对球墨铸铁摩擦学特性的影响,采用调Q半导体泵浦YAG激光器,利用单脉冲同点间隔多次激光加工工艺,对球墨铸铁试样端面进行表面织构化处理.制备出4种不同深度、不同面积占有率的环形阵列分布微凹腔,并在滚滑复合运动的圆柱销与圆盘端面线接触式摩擦磨损试验机上,进行摩擦学试验.结果表明:在相同试验条件下,与光滑试样进行对比,微凹腔试样表面具有较好的减摩效果;对不同深度及面积占有率的微凹腔试样进行摩擦性能试验,结果显示:均存在优化设计值使得织构化表面的摩擦因数最小,并表现出良好的抗擦伤性能.     

激光毛化及该区域材料的力学性能试验

为揭示激光参数及辅助工艺参数对毛化形貌的影响规律,研究毛化点区域材料的力学性能,对激光脉冲参数进行系统匹配试验.在Cr12试样上获得了火山口状、球冠状和W状毛化形貌;采用单因素轮换法,研究了辅助气体的类型、压力、角度及脉冲频率对球冠状形貌区域尺寸的影响;同时对火山口形貌区域材料的金相组织和显微硬度进行了观测和测量.结果表明:通过对激光参数和辅助工艺参数进行优化匹配,可以比较精确地控制毛化形貌的形状及其尺寸;氧气不利于球冠状形貌的形成,氮气不利于火山口状形貌的形成;毛化点材料组织为致密的针状马氏体,与基材相比,硬度提高了近3倍.     

基质对周丛生物的影响研究进展

基质被认为是周丛生物变异的主要来源之一.基质在自然水体中多样性造成周丛微生境的多样性.不同天然基质上的周丛群落对水体营养变化的反应存在基质依赖现象,造成生产力贡献的差异.人工基质可统一放置时间、基质材料、结构以及尺寸,从而简化影响因子,用在分析营养、光和其他因子效应的周丛生物受控实验中.利用30篇文献综述了天然基质的多样性及其对周丛生物的影响,比较了不同人工基质在周丛生物研究中的作用,展望了人工基质的应用前景.     

水热温度和pH值对合成纳米结构γ-AlOOH形态的影响

1mol/L的AlCl₃溶液为铝源,1mol/L的NaOH溶液为沉淀剂,在水热法反应体系中研究了温度和pH值对合成纳米结构γ-AlOOH形态的影响。利用X射线衍射仪(XRD)和热场发射透射电子显微镜(FETEM)对合成的样品进行表征。XRD分析表明不同水热条件下获得样品的物相为γ-AlOOH。FETEM分析显示在时间为48h和pH值为5时水热法合成γ-AlOOH时,在120℃下合成了径向分布不均匀的棒状γ-AlOOH;在150℃下获得了径向尺寸趋于均匀的棒状γ-AlOOH;在180℃下制备出了径向分布较均匀的约20nm的γ-AlOOH。但是,在210℃下合成的薄片状的γ-AlOOH。在温度为180℃和时间为48h时水热法合成γ-AlOOH时,当pH值由5增加到7时,合成γ-AlOOH的径向尺寸变小得不太明显;当pH值由7增加到9时,获得γ-AlOOH的径向尺寸显著的变小,其径向尺寸约为10nm。但是,当pH值为11时,制备出了细小薄片状的γ-AlOOH。最后,对水热法体系中温度和pH值对合成γ-AlOOH形态影响的机理进行了讨论。     

Tuning the magnetic anisotropy in LSMO manganite films through non-magnetic nanoparticles

We report the observation of anomalous magnetic anisotropy driven by nonmagnetic ZrO2 nanoparticles in epitaxial La2/3Sr1/3MnO (LSMO) films grown on LaAlO3 (LAO) substrates. The compressive epitaxial strain imposed by the lattice mismatch of substrate and film is tuned by the density of ZrO2 nanoparticles embedded in the film matrix and affects the magnetic anisotropy as well as the magnetotransport properties. Epitaxial 54 nm thick LSMO thin films with different concentrations of ZrO2 nanoparticles demonstrate anisotropic hysteresis loops concomitant with anisotropic magnetotresistance behavior. The biaxial epitaxial strain, induced by the substrate/film lattice parameter mismatch is partially relaxed by increasing the density of precipitates and they serve as a tuning parameter for the strain state. We interpret our results by a strain-induced interplay of impurity scattering, weak localization and magnetic domain structure.     

河南省公共服务与经济发展相关性实证分析

通过构建公共服务与经济发展水平综合评价指标体系,综合测度河南省2000—2010年的公共服务与经济发展发展水平,并进行相关和协同性实证分析.结果表明:新世纪以来河南省公共服务与经济发展水平呈持续上升趋势,经济增长与公共服务水平之间呈显著正相关关系,但公共服务水平增速较缓,与经济发展的协同性有待提升.提出了调整公共支出结构,提升公共服务水平,促进经济建设与公共服务持续、协调发展的政策建议.     

Preparation of Chitosan-g-PAMPS in H2O/scCO2 Inverse Emulsion

Chitosan(CS)was successfully modified in supercritical carbon dioxide(scCO2)by grafting method to enhance its water solubility.In this work,a three-arm star-like fluorinated polymer was synthesized by atom transfer radical polymerization(ATRP)method and applied as a surfactant in supercritical carbon dioxide(scCO2).Then 2-acrylamido-2-methyl propane sulfonic acid(AMPS)was grafted onto CS(CS-g-PAMPS)in H2O/scCO2inverse emulsion.The effects of mass ratio of water and surfactants(R w/s)and pressure of scCO2on the grafting reaction were investigated.The grafting rate,particle size,and dispersity in water of CS-g-PAMPS varied greatly as R w/s and pressure of scCO2changed.It could be found that the value of R w/s at 12 and the pressure of scCO2at 30 MPa were the optimum conditions for the grafting reaction.CS-g-PAMPS prepared in this reaction system has higher grafting rate,smaller particle sizes,and better dispersity in water than those prepared via conventional methods.     

Effects of inoculating fungi on agilawood formation in Aquilaria sinensis

Agilawood is a costly heartwood medicine obtained from Aquilaria sinensis with active ingredients mainly composed of volatile and semi-volatile substances. However, the formation time of agilawood is quite long and little is known about its formation mechanism. Two highly active fungi obtained from natural agilawood were inoculated on A. sinensis trees to understand their interaction processes and elucidate the transformation rules of induced chemical compositions within different test periods. The results demonstrated that the fungi could successfully colonize living tissues and cells and activate the host defense system, resulting in agilawood accumulation. With increasing time, the main components of A. sinensis converted into constituents or analogs of agilawood and the host exhibited "self-injury" to prevent fungal intrusion and protect other tissues. The data presented here could provide scientific basis for producing agilawood with the two new fungi in a safe, feasible, and sustainable manner without destroying rare Aquilaria plants.     

Design, synthesis and nonlinear optical properties of “dendronized hyperbranched polymers”

A new type of dendritic polymer, named dendronized hyperbranched polymer (DHP), was prepared successfully by the macro-monomer approach. Thanks to the perfect 3D isolation effects, DHPG1 exhibited good NLO property with d 33 value of 133 pm/V, higher than its analogues of dendronized polymer and dendrimer, and its stability of NLO effect was also enhanced.