Cryptomelane（KxMn8-xO16）： Natural active octahedral molecular sieve（OMS-2）

The Xiangtan manganese deposit (XTM) used to be considered a supergene oxide manganese ore in South China. We reported a new identification of the naturally outcropping cryptomelane by examining the physical, chemical and structural features of the XTM supergene oxide manganese ore. The MnO2 content was over 90%, K2O more than 3%, and water from 2.2%-3.1% which is similar to one in zeolite. The cell parameters of the cryptomelane were given as a0 = 0.9974 nm, b0 = 0.2863 nm, c0 = 0.9693 nm and β= 91.47°. There was a larger pseduotetragonal tunnel in the natural cryptomelane that was formed by [MnO6] octahedral double chains with aperture of 0.462×0.466 nm2, filled with K cations resulting in some Mn3+ substituting for Mn4+ to balance the negative charges of structure. The finding is important not only for prospecting manganese resources in South China, but also in application of octahedral molecular sieve of natural cryptomelane as that developed in the tetragonal molecular sieve of natural zeolite o     

A complete sequence and comparative analysis of a SARS-associated virus(Isolate BJ01)

Severe Acute Respiratory Syndrome (SARS) is a newly identified infectious disease[1—5]. The global outbreak of SARS has been threatening the health of people worldwide and has killed 353 people and infected more than 5462 in 27 countries, as reported by WHO on April 29, 2003 (http://www.who.int/csr/sarscountry/en). Although it has been recognized that a variant of virus from the family of coronavirus might be the candidate pathogen of SARS[1—5], its identity as the unique pathogen sti…     

Preparation of (R)-and (S)-2-Allyl-1,3,2-Dinaphtho(α,β)[d.f]dioxaborepin and Their Reactions with Aldehydes

0　IntroductionEnantiopure 1,1′ bi 2 naphtholspossessingC2 chiralityhaveprovedtobeversatilechiralauxiliariesinanumberofasym metricreactions[1 \|6] .Althoughsomeboroncompoundsofthemhavebeenprepared[7 1 6] ,chemistryoftheirallylboranederivativeshasneverbeenreported .Toexplorepossibilityofapplyingseven memberedcyclicchrialallylboronateesterstoasymmetricsynthesisofchiralβ alkenylalcohols,whichareimportantintermediateinthepreparationofopticallyactivenaturalproducts,werecentlyat temptedtosynthesi…     

东营凹陷胜坨地区沙三-沙四段扇体特征与岩性油气藏

东营凹陷胜坨地区沙四段、沙三段沉积时期 ,发育了洪积扇、近岸水下扇和浊积扇 3种扇体沉积 ,根据其沉积、成藏特征分析了 3种扇体的成藏规律和分布特点。研究结果表明 ,沙四段沉积期主要发育洪积扇 ,岩性以砾岩、含砾砂岩为主 ,断层附近砂体的储集性能好 ,多形成背斜和断块油气藏 ;沙三段下部沉积期发育近岸水下扇 ,岩性以砾岩、含砾砂岩为主 ,扇中储集物性最好 ,多形成构造岩性油气藏 ;沙三段中部沉积期发育浊积扇 ,岩性以砂岩为主 ,储集性能好 ,但砂体薄 ,多形成透镜体和上倾尖灭油气藏     

舟桥丙丁接头接触分析的计算机模拟

深入考察接触行为的特点，并以舟桥纵向连接件丙丁接头为例，建立了两种接触计算模型。采用大型通用有限元程序进行分析，模拟丙丁接头受力时的应力应变。与经验合成计算结果和常规有限元分析的结果进行对比，证明接触分析方法对连接件塑性变形、疲劳分析和优化设计有重要的指导意义。     

基于极大似然的智能地雷被动声阵列测向

被动声定位是智能地雷的关键技术之一，其中声传感器阵列测向确定了目标的方位角信息。通过Cramer—Rao下界分析了影响测向精度的因素，并将极大似然估计应用于智能地雷均匀圆阵的测向技术中，通过外场测试对坦克目标进行了相关的测向分析，结果表明精度满足智能地雷的系统要求。     

[(n-C4H9)2Sn(2-PyCO2)2(H2O)] 的合成、晶体结构

利用三丁基氯化锡和2-吡啶甲酸在三乙胺存在下以1:1摩尔比反应,合成了非预期有机锡配合物[(n-C4H9)2Sn(2-PyCO2)2(H2O)].通过元素分析、红外光谱、核磁共振氢谱和X-射线单晶衍射对其结构进行了表征.测试结果表明,该配合物为单体结构,锡原子呈七配位畸变五角双锥构型.通过配位水分子和游离羰基氧原子的氢键作用,形成了二维网状结构.     

高科技企业竞争的网络特征及其对策

本文从提高我国高科技企业持续创新能力的现实需要出发 ,在对高科技产业核心资源和市场特性分析的基础上 ,从网络效应角度具体分析了其竞争的网络特征 ,最后从培育核心能力 ,实施网络作战等方面提出了在网络竞争环境下 ,提升高科技企业竞争优势的具体对策。     

非线性尘埃声波在含有2种不同温度离子的尘埃等离子体中的稳定性问题

在无磁场的尘埃等离子体中 ,由冷的尘埃颗粒和热的电子和离子组成的尘埃等离子体 ,对于有限的小振幅的非线性波的运动可以用KdV方程描述 .对由 2种不同温度离子的尘埃等离子体中的弱二维尘埃声波 ,得到了它所满足的KP方程 .并且发现 ,在横向扰动下 ,弱的非线性孤立波在尘埃等离子体中是稳定的 .在这个系统中既存在压缩孤立波又存在稀疏孤立波     

小波变换在检测粘接件信号特征中的应用

在对金属与非金属粘接件性能检测的分析处理中，应用小波变换的方法对这种非平稳过程的信号进行分析，有效提取了性能检测所需要的特征参数，为提高金属与非金属粘接件性能检测的准确率和效率奠定了基础。