Preparation and performance of a cold gas dynamic sprayed high-aluminum bronze coating

By mixing preheated high-aluminum bronze powders with different amounts of Al₂O₃ powder, a low-pressure cold-sprayed coating was prepared and sprayed onto a Cr12MoV steel substrate. The hardness of the coating and the bonding strength between the coating and the substrate were tested with a HV-1000 microhardness tester and a mechanical universal testing machine. The surface microstructure, cross-section and tensile fracture surface of the coating were observed with a scanning electron microscope (SEM). Correspondingly, the influences of the preheat treatment temperature of the bronze powder and the Al₂O₃ content on the coating performance were investigated. The results indicate that the hardness of bronze powders decreased and the coating deposition rate increased after the preheating treatment of the bronze powder. The Al₂O₃ content in the mixed powders contributed to the deformation of bronze powders during the spraying process. This trend resulted in varied performance of the coating.     

辫状河储层内部建筑结构及剩余油分布研究

储层内部建筑结构是影响开发效果的决定性因素,对剩余油分布具有控制作用。基于河流相建筑结构分析理论,在辫状河沉积模式指导下,采用层次分析法,从开发角度对砂体内部结构进行精细解剖,识别和确定出辫状河道、心滩坝、废弃河道和落淤层等结构要素,弄清各级次、各期次结构要素的接触关系,完成辫状河储层内部结构的精细表征;基于内部结构表征成果,结合不同时期水淹层测井解释结果和生产动态资料,恢复不同开发调整时期的水淹特征,动态表征辫状河储层内部结构控制下的水淹过程,并依据小井距密闭取芯井精细水洗结果验证,总结不同储层结构控制下的剩余油分布模式。结果表明,辫状河储层整体以高含水为主,水淹呈不均匀立体式、随机式特征,不具有分段水淹的特点,未水淹部位分布非常零散,局部物性变差部位、落淤层和低渗屏障遮挡部位直接控制了剩余油的分布。     

基于相互隶属度的云模型相似性度量方法

针对现有云模型相似性度量方法计算复杂度高、结果不稳定、适用性有限等问题,提出了一种基于相互隶属度的云模型相似性度量方法.依据云模型期望曲线以公共面积与自身面积之比定义云模型之间的隶属度,进而利用相互隶属度计算云模型之间的相似度.讨论了不同交点及半云情形下相应面积的计算方法,并给出了相似度的计算公式及性质证明.仿真实验表明,该方法能够在多种情形下合理地度量云模型的相似性,并且具有较高的结果准确度和较低的计算复杂度,基于云模型的评估实例进一步验证了该方法的有效性.      

Experimental investigation and thermodynamic assessment of the yttriumhydrogen binary system

A coupled experimental investigation and thermodynamic study of the yttrium-hydrogen(Y-H) binary system were carried out to provide more comprehensive and quantitative insights into the key thermodynamic properties of this system. Y-H system in the full range of H/Y = 0–3.0 was investigated by accurate pressure composition isotherm(PCI) measurement to provide credible phase equilibria information and thermodynamic data.The phase boundaries obtained were in agreement with previous experimental data but with improved accuracy.With the guide of the crystal structures, all the solid phases were modelled using the three sublattice model. The Y-H phase diagram and thermodynamic parameters were calculated and assessed with the CALPHAD technique.The obtained results are in very good agreement with our experimental data and the published data reported in literature. The obtained thermodynamic database of Y-H system can be used to predict the hydrogenation behavior and decomposition temperatures of hydrides.     

Nanoengineering of amino - functionalized mesoporous silica nanospheres as nanoreactors

Selective functionalization of mesoporous silica nanospheres (MSNs) is crucial for nanoengineering of MSNs. Herein, we have combined “surface-protected etching strategy” and “cationic surfactant assisted etching strategy” to prepare functionalized MSNs with externally attached amino groups. The externally attached NH2 groups endow the catalysts with excellent catalytic performance for nitroaldol reaction between nitromethane and benzaldehyde. In addition, those NH2-MSNs can also be used to support gold nanoparticles, which display very good catalytic performance for reduction of 4-nitrophenol. It can be envisioned that the synthesis protocol developed in this work could also be extended to nanoengineered MSNs, which provides opportunities for nanoreactors design.     

头孢孟多酯钠的波谱学特征和结构确证

建立了利用分析仪器确证头孢孟多酯钠化学结构的方法。通过元素分析仪分析头孢孟多酯钠的元素组成,并利用核磁共振（NMR）、质谱（MS）、红外光谱（IR）、紫外光谱（UV）对头孢孟多酯钠进行结构分析。通过解析确证,头孢孟多酯钠的结构为7-D-( 2-甲酰氧苯乙酰胺)-3-［(1-甲基-1H-四唑-5-基)巯甲基］-8-氧代-5-硫杂-1-氮杂双环[4.2.0]辛-2-烯-2-甲酸盐。该方法准确可行,可为头孢孟多酯钠的结构鉴定提供依据。     

近年来CCA在气候分析与气候预测中的应用

详细论述了CCA方法应用于气候分析与预测中所取得的成果。着重分析了CCA方法在理论上和实践上所存在的优缺点。给出了CCA在我国汛期预报中应用的实例。     

Experimental validation of inter-subspecific genetic diversity in rice represented by the differences between the DNA sequences of ‘Nipponbare’ and ‘93-11’

The pedigrees of three sequenced rice cultivars were analyzed to show that a majority of the genetic composition of 'Nipponbare' originates from japonica cultivars while the minority originates from indica cultivars. In contrast, '93-11' is derived mainly from indica cultivars with a smaller contribution from japonica cultivars. All ancestors of 'Guang lu ai 4' appeared to be indica lines. A set of molecular markers (46 InDels and 53 SSRs) polymorphic between 'Nipponbare' and '93-11' were examined in 46 typical indica and 47 typical japonica cultivars selected from 443 accessions according to Cheng's index. All cultivars were divided into indica and japonica groups without overlapping when clustered by Cheng's index, InDels and SSRs. Much higher InDel and SSR diversity between groups than within groups implies that the marker polymorphisms between 'Nipponbare' and '93-11' represent a large proportion of inter-subspecific diversity. About 85% of indica cultivars and more than 90% of japonica cultivars were confirmed to have the same PCR banding patterns as '93-11' and 'Nipponbare', respectively. Some polymorphic loci between 'Nipponbare' and '93-11' cannot be validated in other indica and japonica cultivars, either as subspecies-specific but not predominant alleles, or alleles not specific between the two groups. It was concluded that molecular markers developed from sequence polymorphism between 'Nipponbare' and '93-11' often represent inter-subspecific diversity, although some exceptions were sensitive to either particular marker loci or particular cultivars.     

膨润土对金银花的吸附研究

研究膨润土对金银花水提物和绿原酸纯品的吸附,考察了时间、温度、浓度对吸附的影响.实验表明: 膨润土对金银花水提物中绿原酸有较好的吸附效果,它对绿原酸的吸附符合Langmuir吸附等温模型,且受时间、温度、浓度的影响,可作为一种有发展前景的絮凝中药水提物载体.     

实时施肥灌溉自动控制系统的研制

文中对不同混肥装置进行分析比较 ,据此利用调速电机、隔膜泵、传感器、微机等构成一能够实现施肥与灌溉同步进行的施肥灌溉系统 ,并设计了有关实时监控程序 研制中 ,解决了肥液及酸液倒流 ,调节过程过长 ,灌溉液的浓度与 pH值的调节互相耦合 ,输入信号受干扰较大等问题 实际运行表明该系统能实时调控灌溉液的肥料浓度、pH值 ,其控制精度可达0 .5% ,并能完成报警、应急性自动停机、故障源判断等功能 ,使用方便可靠 ,自动化程度高 该系统除用于施肥灌溉外 ,还可用于喷施农药 ,并在化工、制药等领域具有一定的应用价值