Ni-Si合金材料与Ni-Si/C复合阳极材料的结构和电化学性能研究

采用大气熔炼-机械球磨二步法制备一系列Ni-Si合金材料和Ni-Si/C复合材料,并运用X射线衍射XRD、场发射扫描电子显微镜FE-SEM和恒电流充放电等测试方法对Ni-Si合金材料和Ni-Si/C复合阳极材料的结构和电化学性能进行了研究.结果表明,Ni-Si合金材料的放电比容量随着Si含量的增加呈上升趋势,但第1周材料充放电的库仑效率下降;采用炭包覆法制备的Ni-Si/C复合阳极材料与Ni-Si合金材料相比,其电化学循环性能大幅度提升,Ni-Si/C复合阳极材料第10周放电比容量保持分数是Ni-Si合金材料的6倍左右,这是因为机械球磨使炭粉均匀地分布在合金颗粒之间,提高了复合阳极材料的导电性.     

下水道硫化氢产生的原因及施工中的监测

城市下水道产生大量的有害气体,最常见的是硫化氢气体,本文对下水道中产生硫化氢气体的原因进行了分析并提出了减少硫化氢产生的措施和在下水道施工作业中硫化氢气体监测的方法。     

220kV升压站隔离开关动静触头过热原因分析及处理

文章介绍了220 kV的隔离开关211-1,222-2A的红外成像异常事件,为计划检修提供了可靠的依据。通过定期的远红外检测,使工作人员积累了远红外热成像判断故障的经验,并可以及时处理隔离开关故障。     

Photocatalytic activity of TiO<Subscript>2</Subscript> sensitized by CdS quantum dots under visible-light irradiation

In this paper, CdS quantum dots sensitized TiO2 composite powders (QD-CdS/TiO2) were synthesized by impregnating TiO2 powder into CdS sol with different concentrations. X-ray diffraction pattern (XRD) shows the crystal structures of CdS and TiO2 are cubic phase and anatase phase separately in QD- CdS/TiO2 powder samples; the crystal size of CdS in QD- CdS/TiO2 is about 3-7 nm, while TiO2 crystal size is about 20 nm. With increasing CdS content in QD-CdS/TiO2 composite, the UV-Vis absorption spectrum shifted to the longer wavelength lines, exhibiting obvious quantum size effect. The fluorescence intensity of QD-CdS/TiO2 irradiated by blue light is weaker than that of pure CdS. When the molar ratio of CdS and TiO2 is about 1∶2, the QD-CdS/TiO2 powder has the best catalytic properties under visible-light irradiation, and the degradation rate of rhodamine B (RhB) is up to 92.2% within 60 min.     

假颗粒现象及其对再生铝镁碳制品性能的影响

对用后铝镁碳砖再生颗粒料的组成和结构特点进行显微分析,并通过改变混料方式以及不同粒度再生料的加入量研究假颗粒对再生铝镁碳制品结构与性能的影响.结果表明:用后铝镁碳砖再生料中含有约40%与废砖相组成和结构相似、骨料与基质并存于同一颗粒的二次颗粒,即所谓的"假颗粒",假颗粒的组成、结构及外形的均匀程度均远不如一次骨料颗粒;混碾可使用后铝镁碳砖再生料中假颗粒发生二次破碎,且粒度越大,发生二次破碎的颗粒数量越多;假颗粒二次破碎导致再生制品的粒度组成发生改变,进而影响其密度和耐压强度.     

Hydrothermal synthesis and photoluminescence behavior of CeO<Subscript>2</Subscript> nanowires with the aid of surfactant PVP

Well-crystalline CeO₂ nanowires were prepared via a surfactant-assisted hydrothermal process. Reaction temperature and reaction time were changed for the determination of optimal synthesis parameters. The as-obtained products were characterized by X-ray diffraction (XRD), high-resolution transmission electron microscopy (HRTEM), and field emission scanning electron microscopy (FESEM). The results show that single crystal CeO₂ nanowires with high yield and good uniformity can be obtained hydrothermally at 180°C for 12 h with the aid of 2.0 g surfactant (polyvinyl pyrrolidone, PVP). The role of PVP was then discussed and a possible growth mechanism was proposed. Moreover, room temperature photoluminescence (PL) spectra were obtained for these CeO₂ nanowires, which are believed to be related to the abundant defects in these nanostructures.     

汽车制动性系统检测常见问题及解决措施

汽车制动性能的好坏,直接关系到行车安全,它是汽车安全行驶中的重点项目之一.对其进行及时准确的检测是保证道路交通安全的必要手段.文章针对路试检验汽车制动性能的常见问题进行了探讨.     

地源热泵系统的推广优势及存在的问题

地源热泵系统为一种能提供新型的清洁可再生能源的环保系统.简要介绍了地源热泵系统的定义、类型、组成及工作原理,对比传统的空气源热泵的优缺点,详细阐述了地源热泵系统的众多优势,并指出了其在发展和推广应用中所面临的多方面问题,对地源热泵系统的推广应用提出了一些建议.随着技术的不断完善,地源热泵系统必然有着很好的发展前景.     

Improved spectrum sharing algorithm based on feedback control information in cognitive radio networks

In order to avoid the system performance deterioration caused by the wireless fading channel and imperfect channel estimation in cognitive radio networks, the spectrum sharing problem with the consideration of feedback control information from the primary user is analyzed. An improved spectrum sharing algorithm based on the combination of the feedback control information and the optimization algorithm is proposed. The relaxation method is used to achieve the approximate spectrum sharing model, and the spectrum sharing strategy that satisfies the individual outage probability constraints can be obtained iteratively with the observed outage probability. Simulation results show that the proposed spectrum sharing algorithm can achieve the spectrum sharing strategy that satisfies the outage probability constraints and reduce the average outage probability without causing maximum transmission rate reduction of the secondary user.     

浅谈沥青路面常见病害成因及防治对策

文章介绍了沥青路面常见病害的形式及其成因,并简要探讨了病害防治的对策。