PI/TiO2纳米复合膜的H2/CH4和H2/N2分离性能

以可溶性聚酰亚胺为基质 ,经乙酸修饰后的钛酸丁酯为TiO2 溶胶前体 ,NMP为共溶剂 ,采用溶胶凝胶法可制得PI/TiO2 纳米复合膜。采用XPS、TEM和气体透气性能测试等手段 ,对复合膜的结构和H2 分离性能进行了表征。结果表明 ,复合膜中钛酸丁酯已转化为TiO2 ,PI与TiO2 两相结合完好。TiO2 以颗粒状均匀分布在PI基质中 ,其颗粒粒径约为 1 0nm。复合膜的H2 ,N2 和CH4 透气系数随着TiO2 含量的增加而明显增加。当TiO2 含量为2 2 3 %时 ,对H2 的透气系数为 1 4 .1Barrer,对H2 /N2 和H2 /CH4 的分离系数分别为 1 87.5和 1 4 3 .2 ,因此 ,该复合膜是一种较为理想的H2 分离和回收膜材料     

Structural and Chemical Diversity of TI-Based Cuprate Superconductors

The first TI一based euprate supereonduetor,TI一Ba-Cu一(),was diseovered by 2.2.Sheng and A.M.Hermann仁1〕. TI beeomes supereondueting at 2.38 K.NumerousTI eompounds and alloys are supereondueting.TIMo6Ses has the highest transition temperature of1 2.2 K among all non一euprate Tl eontaining alloyand eompound supereonduetors.Before thediseovery of the euprate supereonduetors,some TIeontaining oxide supereonduetors were found,among whieh TI。.3W()3 has the highest transitiontemPerature,2.14 K. Sinee the diseovery of TI euPratesuPereonduetors,two distinet families have beenidentified.Soon after the diseovery of TI一Ba一Cu-(),supereonduetivity was eonfirmed in TI一Ba一Ca-Cu一()samples.The ehemieal eompositions anderystal struetures of those eompounds were workedout as T12BaZCu()6,T12BaZCaCuZ()。,andT12BaZCaZCu3OI。[2〕.This 15 the first family of TIeuPrate supereonduetors,whieh features two TIatoms in eaeh ehemieal formula.     

大学预科化学课程教学探讨

本针对大学预科班学生的特点，从大学预科化学课程的基本目的和要求出发，讨论大学预科化学课程教学中应注意的问题．     

Land vehicle positioning using GPS and dead reckoning

To ensure reliable land vehicle positioning, the Global Positioning System (GPS) is one of the best techniques commonly used in present-day positioning systems. However, GPS signals are not available if line of sight with the satellites is lost. In this respect, the addition of the Dead Reckoning (DR) method to complement the GPS unit would enhance the reliability of land vehicle positioning system. For implementing the DR method, the magnetic sensor and accelerometer are used for obtaining heading and velocity or distance information. Calibration of two sensors' dynamic model and DR algorithm are also introduced in this paper. The test result utilizing the GPS and DR methods is analyzed in this paper. It utilize spositioning information from GPS receiver when GPSsignal is available, otherwise DR is started to compensate GPS outage with the GPS output as the original point. The results showed that the error in east and north produced by the DR algorithm for a short time interval can be limitedwithin an acceptable range.     

A preliminary study of crassulacean acid metabolism (CAM) in the endangered aquatic quillwortIsoetes sinensis Palmer in China

Isoetes sinensis Palmer (Isoetaceae) is an aquatic or amphibious plant that is critically endangered in China. Previous studies have revealed the crassulacean acid metabolism (CAM)-like photosynthetic pathway occurs commonly in submerged leaves in genusIsoetes. Water chemistry parameters and the titratable acidity content of the plant extract were measured from samples obtained in the early morning (7∶00) and late afternoon (15∶00) from twoI. sinensis populations in China. One population occurs in the eulittoral zone of a freshwater tidal river at low elevation (134 m) and another occurs in a densely vegetated, high elevation (1 100 m) alpine shallow pool. Significant differences in pH and titratable acidity of the plant extract were detected between the morning and afternoon samples. These changes are associated with diurnal changes in water chemistry. Our results provide the first evidence for the existence of the CAM pathway in the East Asian endemicIsoetes sinensis Palmer. The magnitude of fluctuations in the titratable acidity of the plant extract may be correlated with the severe carbon limitation imposed on the plants by its aquatic habitat. Foundation item: Supported by the State Key Basic Research and Development Plan (G2000046805) Biography:Pang Xin-an (1974-), male, Master candidate, research direction: conservation biology.     

南澳岛及其附近岛屿夏季鸟类的初步调查

作者一行于 2 0 0 1年夏季对南澳及其附近岛屿的鸟类资源状况进行了调查研究 .结果发现 ,南澳及其附近岛屿有鸟类 51种 ,隶属 1 3目 2 8科 ,其中雀形目 2 3种 ,占所发现种类的 45% ,非雀形目 2 8种 ,占 55% ;国家一、二级保护动物各一种 ,分别为 :白腹军舰鸟 (F regataandrewsi)和岩鹭 (Egretta sacra) .按鸟类的栖息和迁徙习惯划分 ,有海鸟 8种 ,湿地候鸟 2种 ,湿地留鸟 9种 ,陆地候鸟 4种 ,陆地留鸟 2 8种 .在所有鸟类中以褐翅燕鸥 (Sterna anae-thetus)为优势种 ,数量最大 ,分布最广 .     

关于非线性方程x+tx=f解的具误差项的Ishikawa迭代过程的稳定性

在一般的Banach空间中证明了非线性方程x tx=f的解的具误差的Ishikawa迭代过程的新的稳定性定理，推广和改进了近期的一系列相关结果．     

关于蕴涵BCK-代数的半群刻划

给出了蕴涵BCK-代数的伴随半群作为剩余半群时的若干特征，并从剩余半群的角度对蕴涵BCK-代数进行了刻划．     

基于B/S模式网络存储的软件实现研究

对目前主要的数据存储方式进行了介绍，针对网络中单个应用系统存储需求紧张而同时网络中存在存储资源浪费、闲置等情况，提出了用软件实现基于B／S模式的网络存储系统BSMSM(B／S Model based Shared Memory)，从而实现了跨平台的网络存储．