交联壳聚糖的合成和非等温热分解动力学

利用TG—DTG技术研究了合成的5种交联壳聚糖的热分解历程．通过对比Coats—Redfern积分法和Achar微分法对31种机理函数求得的动力学参数，推断出各步的可能热分解反应机理．5种交联壳聚糖发生第l步热降解的动力学机理函数相同，都为简单三级反应，遵循f(α)＝0．5(1-α)^3，g(α)＝(1-α)^-1/2-1；第2步均为壳聚糖的分解，其热分解的机理函数均为简单的二级反应；5种壳聚糖的稳定性为：CCTS—B—15—C—5＞CCTS＞CCTS—2≈CCTS—B—18—C—6＞CCTS—1．     

导电高分子在光电材料领域中的研究进展

综述了近年来国内外导电高分子材料在光电材料领域中研究进展情况．论述了聚乙炔、聚苯胺、聚噻吩、聚对苯乙烯撑(PPV)及其衍生物等导电高分子材料作为非线性光学材料所具有的优良性能，介绍了导电高分子电致发光材料和发光材料在实际领域中的应用．     

Robot Calibration Using Active Vision-based Measurement

This paper presents an efficient robot calibration method with non-contact vision metrology. Using the coplanar pattern to calibrate camera made the active-vision-based end-effector pose measurement be a feasible and cost-effective way. Kinematic parameter errors were linearized and identified through two-step procedure, thus the singular and non-linear condition was overcome. These errors were then compensated using inverse model method. The whole calibration process is flexible, easy to implement and prevents the error propagation from the earlier stages to the later ones. Calibration was performed on MOTOMAN SV3 industrial robot. Experiment results show that the proposed method is easy to setup and with satisfactory accuracy.     

A Study on the Surface Structures of Viscose-based Activated Carbon Fiber by FT-IR Spectroscopy and XPS

Using viscose fiber (VF) as starting material and common steam as activating agent, formation of oxygen structures in activated carbon fiber is investigated. In the preparation of samples, VF was first heated at temperatures between 450℃ and 900℃ in N_2 artmosphere. Then, in a successive activation stage, the product carbonized at 600℃ was activated in steam at 450-900℃ for 30 min, and at 600℃ for 5-30 min. The other carbonization products were activated at 600 and 900℃ for 30 min respectively. The products activated at 900℃ were then activated at 450℃ for 30 min again. The starting materiah carbonized products and all activation products were examined by FT-IR spectroscopy and some products were examined by X-ray photoelectron spectroscope (XPS). And the yields of the carbonized and activated products were calculated. By analysing these spectra, the amount of oxygen-containing functional groups of the activated products attained under various activation time, various activation temperature and     

Switched Capacitor Network Analysis by Means of TCM

The totally coded method (TCM) reveals the same objective law, which governs the gain calculating for signal flow graph as Mason formula does. This algorithm is carried out merely in the domain of code operation. Based on pure code algorithm, it is more efficient because figure searching is no longer necessary. The code-series (CS), which are organized from node association table, have the holoinformation nature, so that both the content and the sign of each gain-term can be determined via the coded method. The principle of this method is obvious and it is suited for computer programming. The capability of the computeraided analysis for Switched Capacitor (SCN) can be enhanced.     

Kinetics of Chlorine Decay in Water Distribution Systems

A combined first and second-order model, which includes bulk decay and wall decay, was developed to describe chlorine decay in water distribution systems. In the model the bulk decay has complex relationships with total organic carbon (TOC), the initial chlorine concentration and the temperature. Except for the initial stages they can be simplified into a linear increase with TOC, a linear decrease with initial chlorine concentration and an exponential relationship with the temperature. The model also explains why chlorine decays rapidly in the initial stages. The parameters of model are determined by deriving the best fitness with experimental data. And the accuracy of model has been verified by using the experimental data and the monitoring data in a distribution system.     

Haptic Evaluation of the Prickle of Fabrics: Axial Compression Bending Tests On Ramie Fibers

IntroductionThehandleoffabricshasbeenthesubjectofaverylargenumberofstudiesformorethan30years.FromthepioneeringworkofPierceinthe1930stomorerecenttechniques[1],manystudieshavesoughttorelatehandletospecificfabricmechanicalpropertiesandthroughthemtofiberproperties.Althoughsmoothness,softness,andstiffnessdeterminethephysicalandmechanicalbehaviorofafabricandthesubjectiveassessmentofqualitywhenitishandled,thesensationsperceivedfromthecontactofclothingwiththeskincangreatlyinfluenceouroverallstateofcom…     

一水合草酸铵脱水的热分析动力学

利用2步法研究了一水合草酸铵脱水的热分析动力学三因子: (1) 通过迭代的方法或KAS法求出较为准确的反应的活化能Ea;(2) 结合Coats-Redfern 法与 Achar 法与所得活化能值比较进一步得出反应的最概然机理函数和指前因子A. 研究发现该反应的最概然机理函数为:f(α)=1或g(α)=α,此法所得的计算结果合理且具有很好的重现性.     

An extended nonlinear state predictor for a class of nonlinear time delay systems

An extended nonlinear state predictor (ENSP) for a class of nonlinear systems with input time delay is proposed. Based on the extended Kalman filter (EKF), the ENSP first estimates the current states according to the previous estimations and estimation errors, next calculates the future state values via the system model, and then adjusts the values based on the current errors. After a state predictive algorithm for a class of linear systems is presented, it is extended to a class of nonlinear time delay systems and the detailed ENSP algorithm is further proposed. Finally, computer simulations with the nonlinear example are presented, which demonstrates that the proposed ENSP can effectively and accurately predict the future states for a class of nonlinear time-delay systems no matter whether the state variables change quickly or slowly.     

秦淮河水质改善现场调水试验

为了探究不同水闸调度方案对秦淮河水质改善的效果,进行了洪水期、丰水期调度、枯水期调度和降雨初期雨水污染调度等典型时段调水试验。结果表明:通过合理调控闸泵可对秦淮河水质产生积极效果,上游来水、引水的质量和调度时段对于调度效果具有明显影响。