LPE法生长GaP/Si材料初探

用普通的液相外延(LPE)方法,在Si衬底上生长了厚约10μm的GaP外延层,并对以Ga,In或Sn为生长熔体进行生长得到的结果做了比较.结果表明,Si在Ga中溶解度很大,Ga不适合做熔体;In为熔体时生长出InGaP合金,Si含量较高,而且出现化学计量比偏离现象;Sn为熔体生长的GaP层中Si含量小于In熔体,而且GaP符合化学计量比.测得GaP外延层带隙波长为540     

固定化酵母乙醇发酵研究

用聚乙烯酸(PVA)作载体,采用“T固化薄片成型”技术包埋酿酒酵母细胞进行乙醇发酵.批式发酵周期4.5h,乙醇浓度9.0%,乙醇产率14.4gL~(-1)h~(-1);连续发酵当稀释率为0.72h~(-1)时,乙醇浓度6.0%,乙醇产率21.6gL~(-1)h~(-1)该PVA固化酵母凝胶至少可重复使用180d以上.表明本研究可大幅度提高乙醇连续发醇效率.     

雌甾衍生物的质谱研究

报道了正6个含羟甲基、甲酰基及咪唑甲基的雌甾化合物的质谱,讨论了主要碎片离子的生成途径及有关的裂解规律.     

发展无梯粉状工业炸药的理论判据

本文根据国内外工业炸药发展状况,提出了发展无梯粉状工业炸药的必要性和可行性问题。文章着重论证了发展该类炸药的理论判据。图5,表1,参2。     

用3^＋网络实现对200MW发电机组的实时监视

3~+网络各站点应用程序是通过服务器硬盘上的共享文件进行通信的,并不支持站点应用程序间实时通信,不支持用户多任务并发处理,也没有提供允许不断刷新信息所需的硬件或软件。因此,不能适应生产现场多批量和连续性生产信息的实时传送和处理。我们采用NETBIOS功能调用方式,实现了站点间实时通信,进而研制出了发电厂生产信息后台实时通信和数据处理系统,有效地监视了来自两台200MW发电机组巡回检测系统的321个测点,78个开关量的生产信息,并广播传送到其它工作站,实现了机组14幅工况图形及实时数据模拟图形的混合显示。     

Crystal structure and mechanism of a bacterial fluorinating enzyme

Fluorine is the thirteenth most abundant element in the earth's crust, but fluoride concentrations in surface water are low and fluorinated metabolites are extremely rare. The fluoride ion is a potent nucleophile in its desolvated state, but is tightly hydrated in water and effectively inert. Low availability and a lack of chemical reactivity have largely excluded fluoride from biochemistry: in particular, fluorine's high redox potential precludes the haloperoxidase-type mechanism used in the metabolic incorporation of chloride and bromide ions. But fluorinated chemicals are growing in industrial importance, with applications in pharmaceuticals, agrochemicals and materials products. Reactive fluorination reagents requiring specialist process technologies are needed in industry and, although biological catalysts for these processes are highly sought after, only one enzyme that can convert fluoride to organic fluorine has been described. Streptomyces cattleya can form carbon-fluorine bonds and must therefore have evolved an enzyme able to overcome the chemical challenges of using aqueous fluoride. Here we report the sequence and three-dimensional structure of the first native fluorination enzyme, 5'-fluoro-5'-deoxyadenosine synthase, from this organism. Both substrate and products have been observed bound to the enzyme, enabling us to propose a nucleophilic substitution mechanism for this biological fluorination reaction.     

微型燃气轮机向心透平导向器的流场分析与设计研究

对微型燃气轮机向心透平导向器叶片型线的设计原则进行了探讨,设计出了5种尾缘厚度的导向器叶片,并分别对其通道流场进行了全三维黏性数值模拟.研究结果表明:以该型线设计原则设计出的高亚音速向心透平导向器叶片具有较高的流动效率,并且可以有效减小向心透平的径向尺寸;尾缘相对厚度对导向器叶片流动特性及效率影响较大,尾缘相对厚度每增加1%.叶轮进口气流角将减小约0.03°,速度系数将降低约0.1%.考虑到目前高温合金精密铸造的工艺水平,导向器叶片尾缘厚度取0.6~1.0 mm、尾缘相对厚度小于15%可以获得较高的气动性能.     

合成孔径雷达的干扰和干扰效能研究

合成孔径雷达通过距离向的脉冲压缩技术和方位向的合成孔径天线实现距离维和方位维的高分辨率。该文将图像处理中的图像相关性和图像等效视数准则应用于对合成孔径雷达压制式干扰的干扰效能评估,通过对合成孔径雷达压制干扰的分析,得出噪声调幅干扰是一种最有效的噪声干扰。