基于树状分子及炭黑复合纳米材料修饰电极的Cr(VI)电化学检测

用树状分子及炭黑纳米复合材料修饰玻碳电极,并对六价铬Cr(VI)进行电化学测定.采用X射线光电子能谱(XPS)、循环伏安法(CV)、交流阻抗法(EIS)、方波溶出伏安法(SWSV)等方法对修饰电极进行了表征.研究发现多种其他离子如Ni~(2+)、Co~(2+)、Pb~(2+)、Cu~(2+)、Cd~(2+)、NO_3~-、SO_4~(2-)、Cl~-等对六价铬离子的测定没有明显干扰,且Cr(VI)的还原峰电流与Cr(VI)的物质的量浓度在4~60 nmol/L和0.06~500μmol/L范围内呈线性关系,检测限达1 nmol/L.该法具有简便快速,选择性好,线性范围宽,灵敏度高等优点.     

Cobalt doped titanate nanotubes: Synthesis and properties

Cobalt oxide doped titanate nanotubes are synthesized with a simple hydrothermal treatment of mixed Co_3O_4 and TiO_2 powders. The formed tubular nanostructure, chemical composition,and the elemental distribution are analyzed using TEM, BET, FTIR, XRD, and XPS. The electrocatalytic activity towards oxygen evolution reactions and photodegradation against Rhodamine B are investigated. It has been found out that the oxygen evolutions starts at 0.8 V and reaches 0.98 mA ·cm~(–1) at 1.4 V vs. SCE. For photodegradation of Rhodamine B, the concentration decreased to 24% after 1 h irradiation using the sample with a mass percentage of 5% cobalt. The results demonstrate that the cobalt oxide doped titanate nanotubes are good candidates as electrocatalysts and photocatalytic materials.     

罩式退火炉热过程数学模型与实验验证

考虑对流板复杂的几何结构,建立三维模型,采用正交试验法模拟获得流量、外径和炉内温度对炉内各处努塞尔数Nu分布的影响,得到流量在考察的3种因素内流量的影响作用最强的结论。接着进一步分析Nu随流量的变化,并拟合得到各处Nu与流量的关系式;为了解决炉内复杂几何形状条件下的辐射换热角系数求解问题,采用Monte Carlo方法建立炉内辐射换热角系数求解模型,并最终采用热辐射网络图法求解炉内辐射换热。通过现场进行热电偶插片实验验证本文所建立模型的准确性。研究结果表明:模拟计算得到的温度与现场实测值基本一致,证明了模型的准确可靠性。     

C3N4/ZnO复合材料可见光下的甲醛光电气敏性能

以水热法合成的ZnO纳米棒花为载体,将C_3N_4定量负载在其表面,制备C_3N_4/ZnO复合材料.由于C_3N_4与ZnO的能级匹配,可有效促进其光生电荷的分离,降低光生电荷复合率,显著提高载流子浓度,使其光电流明显增加.C_3N_4与ZnO质量比为2%的样品(2%C_3N_4/ZnO)性能最佳,其光电流在370 nm处可达120μA,为纯ZnO的2.4倍.在室温可见光下,2%C_3N_4/ZnO样品对HCHO的光电气敏响应值可达122%,比纯ZnO高4倍左右.结果表明,适量C_3N_4的负载有效延长了光生电荷的寿命,使ZnO材料在可见光区对HCHO气体表现出高效的光电气敏性能.     

基于动态阈值的混凝土裂缝高抗噪提取及识别方法

针对表面布有蜂窝麻面等复杂噪声的混凝土裂缝,提出了一种基于动态阈值的混凝土裂缝高抗噪提取方法.首先,通过灰度变换、高斯滤波、信息增强等技术弱化、去除噪声,增强图像中裂缝的亮度,提高裂缝与背景的对比度;然后,采用OTSU阈值分割算法去除伪裂缝,基于裂缝与干扰噪声面积的差异,引入动态阈值,实现各类型裂缝的提取;最后,基于边缘检测和裂缝骨架细化处理,计算裂缝的长度、宽度和面积3项特征参数.基于室内实验和室外实际桥梁拍摄的4组裂缝图像结果表明,4组裂缝的平均宽度分别为2.01、1.07、1.34、0.97 mm,说明该方法适用于不同背景下各类型裂缝的提取,具有较强的鲁棒性.     

Effect of Graphene Nanoplatelets addition on mechanical properties of pure aluminum using a semi-powder method

In recent years, graphene has attracted considerable research interest in all fields of science due to its unique properties. Its excellent mechanical properties lead it to be used in nano-composites for strength enhancement. This paper reports an Aluminum–Graphene Nanoplatelets(Al/GNPs)composite using a semi-powder method followed by hot extrusion. The effect of GNP nano-particle integration on tensile, compressive and hardness response of Al is investigated in this paper. It is demonstrated that 0.3 wt% Graphene Nanoplatelets distributed homogeneously in the matrix aluminum act as an effective reinforcing filler to prevent deformation. Compared to monolithic aluminum(in tension), Al–0.3 wt% GNPs composite exhibited higher 0.2% yield strength(+14.7%), ultimate tensile strength(+11.1%) and lower failure strain( -40.6%). Surprisingly, compared to monolithic Al(in compression), Al–0.3 wt% GNPs composite exhibited same 0.2% compressive yield strength and lower ultimate compression strength(- 7.8%),and lower failure strain(- 20.2%). The Al–0.3 wt% GNPs composite exhibited higher Vickers hardness compared to monolithic aluminum(+11.8%).Scanning electron microscopy(SEM), Energy-Dispersive X-ray Spectroscopy(EDS) and X-ray diffraction(XRD) were used to investigate the surface morphology, elemental percentage composition, and phase analysis, respectively.     

基于供应链业务流程改造的模块化设计

首先通过对A公司供应链业务流程现状进行分析,发现存在的问题,然后从模块化的角度对业务流程进行改造,并进一步对改造后的业务流程所涉及的4个模块进行了设计.所提出的供应链模块化设计,可将复杂流程简单化,使供应链管理更加明确、清晰,对于提高供应链的运作效率,缩短对需求响应时间具有重要作用.     

图书馆编目数据外包问题的探讨——以西安图书馆为例

对图书馆编目数据外包工作中产生的数据错误的原因进行了分析,并提出了防范数据错误的措施,以完善和促进编目数据外包工作。     

Optimal bundling and pricing decisions for complementary products in a two-layer supply chain

This article explores bundling and pricing decisions for two complementary products in a two-layer supply chain consisting of a multi-product manufacturer and a retailer. We establish four different pricing models under cases of decentralized decision, while considering different portfolio-bundling strategies of the manufacturer and the retailer. A game-theoretical method is used to characterize the corresponding equilibrium outcomes in each scenario. By further analyzing and comparing the maximum profits of all four possible scenarios, optimal bundling and pricing decisions for the manufacturer and the retailer are obtained, respectively. Model extensions and numerical examples are enriched to highlight the factors affecting optimal decision-making. Finally, valuable and interesting managerial insights are summarized. Results show that the upstream manufacturer always profits more when he sells complementary products separately. However, the optimal bundling decision of the downstream retailer is jointly determined by product complementarity (as a major factor) and the difference of product profitability (as a secondary factor). Market power cannot exert an influence on both optimal bundling decisions, but it can partly affect pricing decisions.     

对加强高校网络廉政舆情处置的思考

网络廉政舆情是把双刃剑,有利有弊,对网络廉政舆情及时搜集、科学研判、处置得当,将有利于推进高校的纪检监察工作。当前存在诸多高校负面网络廉政舆情,高校纪检监察部门在处置负面网络廉政舆情方面存在诸多误区,要有效处置负面网络廉政舆情,高校纪检监察部门应确立正确的原则,构建相应的机制。