An effective amperometric biosensor based on graphene modified gold nanowire arrays for glucose detection

A novel glucose biosensor based on graphene nanosheets （GNs） modified gold nanowire arrays （AuN- WAs） electrode was constructed. Highly ordered gold nanowire arrays were prepared by direct electrodeposition in anodic aluminum oxide templates. GNs were synthe- sized through a public route involving graphite oxidation, exfoliation, and chemical reduction. Field emission scan- ning electron microscope and high-resolution transmission electron microscope were employed to characterize the as- prepared AuNWAs and GNs. Glucose oxidase was immobilized on the surface of GNs-AuNWAs modified electrode via a cross-linking method. The cyclic voltam- metry results showed that the GNs-AuNWAs-based glu- cose biosensors have high catalysis activity to hydrogen peroxide （H2O2） than those modified with GNs or AuN- WAs only. Furthermore, amperometric response was employed to detect glucose concentration owing to its simplicity, high selectivity, and relative low cost. Glucose biosensors based on GNs-AuNWAs showed excellent performance with high sen- sitivity of 40.25 μA cm^-2 （mmol/L）^-1, low detection limit of 0.02 mmol/L, and a linear range from 0.02 to 3 mmol/L.     

Single-Chain Fragmented Antibodies Guided SiRNA Delivery in Breast Cancer

Over the past ten years,the enthusiasm to harness small RNA molecules,mainly small interfering RNAs(siRNAs) and microRNA mimics,into therapeutic weapons has never been quenched.However,a major obstacle hindering the clinical application of these small molecules is how to efficiently and precisely deliver siRNAs in vivo into target cells to silence target genes.An international collaborative study led by Song Erwei from the Memorial Hospital of Sun-YatSen University and Wang Jun from Hefei National Laboratory for Physical Sciences at Microscale and School of Life Sciences of University of Science and Tech-     

Graphene-based hybrid materials and their applications in energy storage and conversion

Graphene attracts more and more scientists and researchers owing to its superior electronic,thermal,and mechanical properties.For material scientists,graphene is a kind of versatile building blocks,and considerable progress has been made in recent years.Graphene-based hybrid materials have been prepared by incorporating inorganic species and/or cross-linking of organic species through covalent and/or noncovalent interactions.The graphene-based hybrid materials show improved or excellent performance in various fields.In this review,we summarize the synthesis of graphene and graphene-based hybrid materials,and their applications in energy storage and conversion.     

公路装配式空心板桥加宽预压施工新工艺研究与应用

针对公路装配式空心板桥,在分析影响桥梁加宽效果关键因素的基础上,提出了预压加宽施工新工艺,并在工程实例桥加宽改造施工中进行的应用验证,该施工工艺可用于类似桥梁的加宽改造.     

变动中的人格权

人格权是以权利主体的人格利益为客体的民事权利.对人格利益的认定,随着时代的发展在逐步深入,所以人格利益的范围日益扩大,人格权的内容日益丰富,出现了许多新的人格利益.本文对此做一简单论述.     

小型制冷系统的稳态模拟

所建立的小型制冷系统模型包括压缩机、冷凝器、膨胀阀和蒸发器四个部件模型以及使系统封闭的 充灌量模型,实现了所有相关物性参数计算的程序化以便于模型的数值求解。在蒸发器模型中提出了析湿系数 的新算法,加速了模型的计算。用所建立的模型模拟工作参数的变化对系统性能的影响,其结果与实际规律相 符合,证明了该模型的正确性。根据模型得出的定量结果可分析各性能参数变化的相互影响,并对性能参数的 敏感性进行分析,为系统优化和控制提供理论依据。此外,换热器模型还可独立用于各种换热器性能的分析与 优化。     

油气雾化技术在钛合金加工中应用研究

为了提高金刚石刀具切削钛合金零件的表面加工质量,减轻金刚石刀具的磨损,提出一种以二氧化碳、水及植物油雾化后的雾状混合物作为冷却介质的加工技术.冷却介质经研制的油气雾化装置喷淋到切削区,达到冷却、润滑及保护金刚石刀具的目的.对比实验表明,利用油气雾化技术,二氧化碳气体能够更充分地接触加工表面,使工件加工表面中微量铁原子直...     

钇、镱氯代苯甲酸与1,10-邻菲哕啉三元配合物的合成及抑菌活性

以邻(间、对)氯苯甲酸和1,10-邻菲啰啉为配体,合成了3种钇和3种镱的三元配合物.通过EDTA配位滴定分析和元素分析确定了各配合物的组成,利用红外光谱分析了配合物的结构.采用滤纸片法测试了6种配合物对埃希氏大肠杆菌和金黄色葡萄球菌的抑菌效果.实验表明,6种配合物都表现出较好的抑菌作用,配合物的抑菌作用远大于相应的稀土盐及羧酸配体,抑菌作用随溶液浓度的增大而增强,且它们对大肠杆菌的抑制作用均强于对金黄色葡萄球菌的抑制作用.     

点支式玻璃建筑中铸铝支承件承载性能

为了研究点支式玻璃建筑中铸铝支承件的承载性能,对3种典型铸铝支承件进行了足尺模型试验研究。按照实际工程中支承件的形式与尺寸制造模具,采用ZL105-T1和ZL111-T6这种铝合金材料铸造成足尺模型试件,借助万能试验机对试件进行加载试验,得出了试件的屈服荷载与极限荷载。根据试件的实际几何尺寸与材料属性,建立有限元模型对试验过程进行数值模拟。有限元分析结果与试验数据吻合良好,验证了有限元模型的可靠性。试验研究与有限元分析表明铸铝支承件的承载力较高,可以在实际工程中应用。     

O2流量对O2/C4F8等离子体刻蚀SiCOH低k薄膜的影响

研究了O2/C4F8等离子体刻蚀SiCOH低k薄膜时O2流量对刻蚀率、表面结构的影响,及其放电等离子体特性的关联.发现O2流量的增大可以极大地提高多孔SiCOH薄膜的刻蚀速率,降低表面的粗糙度,减少SiCOH薄膜表面的C:F沉积.等离子体特性的光谱分析表明,O2的添加,增强了C与O之间的反应,从而在Si、F反应刻蚀Si的同时,C、O之间的反应使C消耗,实现Si、C的同步刻蚀,从而获得SiCOH低k薄膜的高刻蚀率和低粗糙度表面.