中间相沥青基介孔炭的表征及其用作锂离子电池负极材料的电化学性能

以中间相沥青为碳源、CaCO_3为模板,制备中间相沥青基介孔炭(MPMC)。采用XRD、SEM、TEM等手段表征所制介孔炭的结构和形貌,并将其用作锂离子电池的负极材料,测试电化学性能。结果表明,所制MPMC具有丰富的介孔结构和较大的比表面积及孔体积,随着CaCO_3质量分数的增加,MPMC的比表面积和孔体积先增加后减小,当CaCO_3的质量分数为70%时,所制MPMC的比表面积和孔体积最大;MPMC用作锂离子电池负极材料具有良好的电化学性能,能有效提高锂离子电池的可逆比容量,具有良好的循环稳定性和倍率性能。     

Novel multiferroicity in orthorhombic SmCrO3

This paper reports the ferroelectricity in antiferromagnetic SmCrO_3 with a reasonably large value of spontaneous electric polarization(70μC/cm~2mC cm~(-2)at 50 K)based on the measurement of pyroelectric current.The experimental results showed that the temperature of the onset of polar order was evidently higher(about220 K)than the Neel temperature(T_N=197 K)in the magnetodielectric studies.The calculated magnetodielectric effect(MDE)value was explicitly negative with maximum|MDE|values of about 3.6%around 230 K.The absence of a convincing signature in MDE at antiferromagnetic ordering temperature T_Nindicated the absence of magnetoelectric coupling around this temperature regime.The results further confirmed that the onset of polar order can be attributed to the structural distortion,rather than the canted noncollinear magnetic structure.     

UHPLC-MS/MS法同时测定大鼠血浆中汉黄芩素、隐绿原酸和白杨素-7-O-葡萄糖醛酸苷含量

建立了UHPLC-MS/MS同时测定大鼠血浆中的汉黄芩素、隐绿原酸和白杨素-7-O-葡萄糖醛酸苷含量的方法。以芹菜苷为内标,采用ACQUITY UPLC HSS T3色谱柱(2.1 mm×100 mm, 1.8 μm),乙腈和0.1％甲酸溶液为流动相,流速为0.2 mL·min^-1。结果表明,汉黄芩素、隐绿原酸和白杨素-7-O-葡萄糖醛酸苷线性范围为1～1 000 ng·mL^-1(R2>0.99),最低定量浓度为1 ng·mL^-1,提取回收率、基质效应均符合生物样品分析要求。建立的方法灵敏、准确,可用于大鼠血浆中汉黄芩素、隐绿原酸和白杨素-7-O-葡萄糖醛酸苷的测定及其药代动力学研究。     

Effect of cold rolling process on microstructure and mechanical properties of high strength β titanium alloy thin sheets

The microstructure and mechanical properties of Ti-3.5Al-5Mo-6V-3Cr-2Sn-0.5Fe high strength titanium alloy sheets prepared by unidirectional cold rolling and two-step cross cold rolling were investigated. Results showed that the β phase grains were refined significantly by cold rolling followed by solution treatment for a short time.Compared to unidirectional cold rolling, the short time solution treatment after two-step cross rolling could significantly reduce the non-uniformity of the microstructure of the alloy sheets. After aging treatment at 550 ℃,the anisotropy of the mechanical properties still existed in the unidirectional rolled sheets, and the tensile strength was highest along the rolling direction. After solution and aging treatment, the anisotropy of the mechanical properties of the two-step cross rolling process sheet was not obvious than unidirectional cold rolling,and alloy had good strength and plasticity matching.     

毛百合的核型分析

采用常规压片法对产于黑龙江省的帽儿山和吉林省的长白山的毛百合进行核型研究,结果表明:帽儿山和长白山毛百合的染色体数目均为2n=24.长白山的核型为2B型,帽儿山的核型为3B型,核型公式为:长白山的为2n=2x=24=2m 10sm 12T.核型不对称系数为82.08%,帽儿山的为2n=2x=24=2m 10sm (2SAT) 6st 6T,核型不对称系数为78.54%,通过比较发现二者的核型差异甚大,结构变异明显,主要表现在染色体相对长度、臂比、次缢痕数目及分布.     

基于特征选择和支持向量机的异常检测

为在提高检测率的同时保持较低的虚警率,提出一种不同于单一算法的基于特征选择和支持向量机的异常检测技术.首先用一个数据子集进行特征选择,通过构造函数来计算特征间的相似度,并在不失样本信息的前提下,完成会话样本的特征选择;然后对用于训练和测试的数据执行特征选择,剔除不必要的数据特征;最后利用支持向量机来判断入侵.仿真实验表明:与基于标准的支持向量机、基于tf×idf的支持向量机、基于tf×idf的神经网络及基于数据挖掘等的异常检测相比较,该方法具有更高检测率,同时其虚警率也更低.     

考虑上部管柱变形影响的减震器动力学分析

针对在冲击载荷下长测试管柱的减震问题,利用行波法建立了减震系统动力学模型,与以往研究模型进行了比较,分析了减震器在冲击载荷下的动力学特性.结果表明:上部测试管柱的变形将增大减震器系统的阻尼系数,同时减小减震器系统的固有频率,从而增强减震效果;测试管柱材料系数和减震器参数比值影响减震效果,比值愈大,减震效果愈好.     

真菌吸附重金属离子的研究

利用黑曲霉和简青霉制备生物吸附剂,研究了它们对重金属Pb2 离子和Cd2 离子的吸附、解吸行为以及实验条件对吸附的影响,包括吸附剂用量、溶液pH值、吸附时间以及共存离子等因素.结果表明,黑曲霉和简青霉吸附Pb2 离子的最适pH值均为5,吸附Cd2 离子时均为3.二者对Pb2 离子的吸附均在4 h达到平衡,吸附量分别为29.07 mg·g-1和36.65 mg·g-1.Cd2 离子吸附也在约4 h达到最大吸附量,分别为26 mg·g-1和26.5mg·g-1.溶液中Zn2 离子和Cd2 离子的存在都会降低Pb2 离子的吸附量.2种吸附剂对Pb2 离子的吸附都符合Langmuir等温线模型,而对Cd2 离子的吸附都较为符合Freundlich等温线模型.1 mol/L HNO3对吸附有Pb2 离子的黑曲霉和简青霉进行解吸,解吸率分别可达77.4%和92.3%.     

Performance Analysis of Post-Detection Combining for NFSK and DPSK Systems over Arbitrarily Correlated Nakagami Channels with Distinct Fading Parameters

Introduction Diversity reception, which counters fading and inter- ference in the physical layer and improves system per- formance, is a design methodology used to overcome multipath fading on wireless channels. Various com- bining schemes have been studi…     

大物质分选机在餐厨垃圾预处理中的应用

餐厨垃圾预处理阶段物质分选对整体处理工艺影响较大,如果分选不到位,浆料中杂物多,会导致管道磨损严重、设备故障率高等问题。通过调节进料频率及大物质分选机的运行频率,探究大物质分选机较优的运行参数范围,使分选工作更加有效。试验结果表明：大物质分选机运行频率为70 Hz,进料频率小于17 Hz为较优运行参数,此时设备电流值较低且波动曲线较为平稳,分选料中有机质质量占比在33%~37%,与其他工况相比,有机质质量占比至少低了3%;运行工况的变化不会对浆料的组成成分造成影响,其中剩余物、果皮和骨头质量占比较大,三者占比总和在98%以上,其他杂物质量占比不超过2%。