Novel multiferroicity in orthorhombic SmCrO3

This paper reports the ferroelectricity in antiferromagnetic SmCrO_3 with a reasonably large value of spontaneous electric polarization(70μC/cm~2mC cm~(-2)at 50 K)based on the measurement of pyroelectric current.The experimental results showed that the temperature of the onset of polar order was evidently higher(about220 K)than the Neel temperature(T_N=197 K)in the magnetodielectric studies.The calculated magnetodielectric effect(MDE)value was explicitly negative with maximum|MDE|values of about 3.6%around 230 K.The absence of a convincing signature in MDE at antiferromagnetic ordering temperature T_Nindicated the absence of magnetoelectric coupling around this temperature regime.The results further confirmed that the onset of polar order can be attributed to the structural distortion,rather than the canted noncollinear magnetic structure.     

UHPLC-MS/MS法同时测定大鼠血浆中汉黄芩素、隐绿原酸和白杨素-7-O-葡萄糖醛酸苷含量

建立了UHPLC-MS/MS同时测定大鼠血浆中的汉黄芩素、隐绿原酸和白杨素-7-O-葡萄糖醛酸苷含量的方法。以芹菜苷为内标,采用ACQUITY UPLC HSS T3色谱柱(2.1 mm×100 mm, 1.8 μm),乙腈和0.1％甲酸溶液为流动相,流速为0.2 mL·min^-1。结果表明,汉黄芩素、隐绿原酸和白杨素-7-O-葡萄糖醛酸苷线性范围为1～1 000 ng·mL^-1(R2>0.99),最低定量浓度为1 ng·mL^-1,提取回收率、基质效应均符合生物样品分析要求。建立的方法灵敏、准确,可用于大鼠血浆中汉黄芩素、隐绿原酸和白杨素-7-O-葡萄糖醛酸苷的测定及其药代动力学研究。     

Effect of cold rolling process on microstructure and mechanical properties of high strength β titanium alloy thin sheets

The microstructure and mechanical properties of Ti-3.5Al-5Mo-6V-3Cr-2Sn-0.5Fe high strength titanium alloy sheets prepared by unidirectional cold rolling and two-step cross cold rolling were investigated. Results showed that the β phase grains were refined significantly by cold rolling followed by solution treatment for a short time.Compared to unidirectional cold rolling, the short time solution treatment after two-step cross rolling could significantly reduce the non-uniformity of the microstructure of the alloy sheets. After aging treatment at 550 ℃,the anisotropy of the mechanical properties still existed in the unidirectional rolled sheets, and the tensile strength was highest along the rolling direction. After solution and aging treatment, the anisotropy of the mechanical properties of the two-step cross rolling process sheet was not obvious than unidirectional cold rolling,and alloy had good strength and plasticity matching.     

城乡水务一体化管理综合评价与实证分析——以贵州城乡水务一体化为例

城乡水务一体化管理模式是处理涉水事务的行之有效的方式,它实现了由一个部门对地表水与地下水、水量与水质的统一规划与调度.该模式是一种全新的水务管理体制,也是我国管理涉水事务的一种发展趋势.目前我国大部分地区都基本实现了城乡水务一体化管理,但各个地区发展的程度有所不同.以贵州省为例,综合考虑城乡水务一体化管理的基本原则和目标,采用层次分析法对其管理现状进行综合评价研究.     

多维极端Reissner-Nordstrm黑洞的熵量子谱

通过似正规模,采用两种量子化方法计算了多维极端Reissner-Nordstrm黑洞的熵量子谱。结果表明,从两种量子化方法所得的熵谱是一致的,此黑洞的熵量子谱与黑洞的参量及微扰场的参量无关,但与时空的维度有关。对于确定的维度,熵量子谱是等间距的。     

郑洛新国家自主创新示范区人才特区建设研究

以国家自主创新示范区为功能区块建设人才特区,是实现国家自主创新示范区和人才共赢发展最直接、最有效的选择。本文梳理探讨了人才特区的概念、特征及主要实践模式,尝试提出郑洛新国家自主创新示范区建设人才特区的若干思路与对策,以期为郑洛新国家自主创新示范区及类似地区建设人才特区提供决策参考。     

电阻绝缘检测中低压脉冲信号注入法的算法改进

在有源式低压脉冲信号注入法的基础上,重新推导了计算电阻值的数学模型,并设计了一种运用该模型的有源式动力电池绝缘电阻监测系统,该系统可以有效地解决部分无源式和有源式绝缘检测法无法有效精确测量同时下降的正负端绝缘电阻与正负端单侧绝缘电阻的问题.此外,通过台架实验验证了该监测系统的有效性,在改进电动汽车动力电池监测系统方面具有一定的应用价值.     

C3N4/ZnO复合材料可见光下的甲醛光电气敏性能

以水热法合成的ZnO纳米棒花为载体,将C_3N_4定量负载在其表面,制备C_3N_4/ZnO复合材料.由于C_3N_4与ZnO的能级匹配,可有效促进其光生电荷的分离,降低光生电荷复合率,显著提高载流子浓度,使其光电流明显增加.C_3N_4与ZnO质量比为2%的样品(2%C_3N_4/ZnO)性能最佳,其光电流在370 nm处可达120μA,为纯ZnO的2.4倍.在室温可见光下,2%C_3N_4/ZnO样品对HCHO的光电气敏响应值可达122%,比纯ZnO高4倍左右.结果表明,适量C_3N_4的负载有效延长了光生电荷的寿命,使ZnO材料在可见光区对HCHO气体表现出高效的光电气敏性能.     

一种基于四叉树划分的改进ORB算法

原ORB （oriented FAST and rotated BRIEF）算法提取的图像特征点经常出现“扎堆重叠”现象，其分布较为密集且缺乏尺度不变性，因而容易造成图像特征点误匹配的问题。为了解决该问题，提出了一种基于四叉树划分的图像特征点提取算法。首先对图像建立尺度金字塔，然后使用四叉树划分图像并限制划分深度。用加速分段测试的特征（features fromaccelerated segment test，FAST）算法通过多个检测阈值对划分后的图像进行特征点检测。检测完毕后，根据划分出的子块总数和提取的特征点总数对划分出来的各个子块设置自适应阈值，提取ORB特征点。操作完成后通过采取非极大值抑制的方法筛选最佳特征点，并使用改良后的二元鲁棒独立基本特征（binary robust independent elementary features，BRIEF）算法计算得出特征点的描述符，最后进行特征点匹配。实验结果表明，本文算法提取的图像特征点较原ORB算法提取的效果在均匀程度上得到了明显地提升，冗余重叠的特征点数量减少，且在特征点提取速度方面较原ORB算法的提取速度提高了30%以上。     

An effective amperometric biosensor based on graphene modified gold nanowire arrays for glucose detection

A novel glucose biosensor based on graphene nanosheets （GNs） modified gold nanowire arrays （AuN- WAs） electrode was constructed. Highly ordered gold nanowire arrays were prepared by direct electrodeposition in anodic aluminum oxide templates. GNs were synthe- sized through a public route involving graphite oxidation, exfoliation, and chemical reduction. Field emission scan- ning electron microscope and high-resolution transmission electron microscope were employed to characterize the as- prepared AuNWAs and GNs. Glucose oxidase was immobilized on the surface of GNs-AuNWAs modified electrode via a cross-linking method. The cyclic voltam- metry results showed that the GNs-AuNWAs-based glu- cose biosensors have high catalysis activity to hydrogen peroxide （H2O2） than those modified with GNs or AuN- WAs only. Furthermore, amperometric response was employed to detect glucose concentration owing to its simplicity, high selectivity, and relative low cost. Glucose biosensors based on GNs-AuNWAs showed excellent performance with high sen- sitivity of 40.25 μA cm^-2 （mmol/L）^-1, low detection limit of 0.02 mmol/L, and a linear range from 0.02 to 3 mmol/L.