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101.
Antioxidant activity of fresh apples 总被引:23,自引:0,他引:23
102.
103.
A homochiral metal-organic porous material for enantioselective separation and catalysis 总被引:4,自引:0,他引:4
Inorganic zeolites are used for many practical applications that exploit the microporosity intrinsic to their crystal structures. Organic analogues, which are assembled from modular organic building blocks linked through non-covalent interactions, are of interest for similar applications. These range from catalysis, separation and sensor technology to optoelectronics, with enantioselective separation and catalysis being especially important for the chemical and pharmaceutical industries. The modular construction of these analogues allows flexible and rational design, as both the architecture and chemical functionality of the micropores can, in principle, be precisely controlled. Porous organic solids with large voids and high framework stability have been produced, and investigations into the range of accessible pore functionalities have been initiated. For example, catalytically active organic zeolite analogues are known, as are chiral metal-organic open-framework materials. However, the latter are only available as racemic mixtures, or lack the degree of framework stability or void space that is required for practical applications. Here we report the synthesis of a homochiral metal-organic porous material that allows the enantioselective inclusion of metal complexes in its pores and catalyses a transesterification reaction in an enantioselective manner. Our synthesis strategy, which uses enantiopure metal-organic clusters as secondary building blocks, should be readily applicable to chemically modified cluster components and thus provide access to a wide range of porous organic materials suitable for enantioselective separation and catalysis. 相似文献
104.
Digital city, a large complex system, is comprised many subsystem of different fields. It involves common field data, flexible field processes, seamless intra-organization and inter-organization collaborations, and increasing connectivity and interoperability between distributed or decentralized systems. All above these are involved Foundation Data of Digital city. To promote the sustainable development of Digital City, this paper investigates to the construction of Foundation Data Platform (FDP) from the view of the architecture. The paper introduces the conceptions, characteristics and underlying problems of the FDP, and discusses the key issues of the architecture paradigms what FDP might adopted via comparing Object-Oriented Architecture (OOA), Component-Based Architecture (CBA), and Service-based Architecture (SBA). The Process Embedded Service-Oriented Architecture (SOA), one of the recent SOA Application Architecture is introduced. The results indicate that the Process Embedded SOA could promote the sustainable development of Digital City and accommodate the dynamic development environments of different fields which constantly changes requirements. 相似文献
105.
As ubiquitous sensor networks (USN) technologies and its middleware are still at its early stages, the system of the USN relies on the middleware and applications. The past sensor networks are assumed to be designed for specific applications, having data communication protocols tightly coupled to applications. To avoid these problems, several kinds of USN middleware have been researched and developed. However, most middleware of USN are still restricted by its own infrastructure so far. This paper proposes appropriate 3 tier Smart Middleware System (3SMS) for USN. 相似文献
106.
A number of IDSs have been proposed for a networked or distributed environment. A modified D-IDS using federated peer-to-peer architecture, MCR (Multicast Reflector) and modified shaker protocol were proposed. The suggested scheme can be implemented easily and performs the information sharing between low-level IDS agents. As all users within a group monitor each other's, the common control server can perform detect intrusions with less cost and support the detection of the inside intruders. 相似文献
107.
Tool wear, chatter vibration, chip breaking and built-up edge are main phenomena to be monitored in modern manufacturing processes, which are considered as important factors to the quality of products.They are closely related to the cutting parameters, which are to be selected in manufacturing process.However, it is very difficult to measure directly the cutting quality based on on-line monitoring.In this study, the relationship between the cutting parameters and cutting quality is analyzed.A Radical Basis Function (RBF) neural network based on-line quality recognition scheme is also presented, which monitors the level of surface roughness.The experimental results reveal that the RBF neural network has a high prediction success rate. 相似文献
108.
By adopting majority rule within a renormalization group approach, we can show that the strength of inter-group interaction in a social system either grows or shrinks monotonically with increasing group size, depending on the initial coupling strength of individuals in the group. This contrasts with the findings of previous studies in which the strength of the interaction grows with group size regardless of the initial strength. Our approach clearly demonstrates that the phenomena of crowd psychology, such as an extreme anti-reaction between different ethnic or ideological groups, could be a consequence of the many-particle nature of social systems when the initial strength of the interaction is larger than a critical value. The effect of neutral opinion holders is critically examined using the spin-one Ising model. The critical size of the population of neutral opinion holders, that can prevent crowd polarization, depends on the block spin rule. 相似文献
109.
Herbert K.H. Lee 《Journal of Classification》2007,24(1):53-70
Feedforward neural networks are a popular tool for classification, offering a method for fully flexible modeling. This paper
looks at the underlying probability model, so as to understand statistically what is going on in order to facilitate an intelligent
choice of prior for a fully Bayesian analysis. The parameters turn out to be difficult or impossible to interpret, and yet
a coherent prior requires a quantification of this inherent uncertainty. Several approaches are discussed, including flat
priors, Jeffreys priors and reference priors. 相似文献
110.
立成表是古历中推算日、月、五星运动时,为简化计算所造的表.元代<授时历>是中国古代历法的巅峰之作,可惜<元史*历志>中没有收录它的立成表部分.在韩国保存有署名王恂的<授时历立成>奎章阁本1册.该文对这册立成表的内容进行了分析和研究,证明它确是在元代所做,其刊行时间为朝鲜世宗时代,具有珍贵的史料价值;而且,其中出现的四暗星内容对于<授时历>本身的历法内容是一个重要的补充. 相似文献