反相高效液相色谱法测定化妆品中的酮麝香

 酮麝香是化妆品中的限用物质,对人体有致癌作用,因此,有必要对其含量进行分析。采用超声辅助提取法对不同基质类型的化妆品样品进行预处理。利用反相高效液相色谱法测定化妆品中的酮麝香。色谱条件为Kromasil C₁₈(250mm×4.6mm i.d.,5μm)色谱柱,流动相V(乙腈):V(水)= 80:20,流速1.0mL/min,检测波长235nm。结果表明,在此条件下,酮麝香在0.5-150 μg/mL范围内与相应的峰面积具有良好的线性关系(相关系数r为0.9998),线性回归方程为A=13500ρ-4829,回收率为90.5%-102.5%,RSD为0.45%-0.98%。因此,研究建立的利用反相高效液相色谱法测定化妆品中的酮麝香的方法准确、可靠、适用性广,可为酮麝香的分析及国家相关法规的制定提供一定的参考。     

浓度对薄凹液层胶体悬浮液干燥花样形成的影响

研究了不同浓度下厚度较薄的凹液层胶体悬浮液干燥过程及花样, 利用照相机实时拍摄不同浓度下胶体悬浮液的干燥过程. 结果表明随着浓度的增加, 最终干燥花样圆环宽度增加, 而数目明显减少; 干燥过程分为5阶段, 其中包含两阶段马兰哥尼对流; 对流能够影响悬浮液内胶体颗粒的自组装和薄膜形貌, 第一阶段对流导致薄膜边缘厚、中心薄, 第二阶段对流伴随接触线的钉轧-滑移运动, 导致多重宽环花样形成.     

Global awareness, future city design and decision making

Our world has been changing at an exponential rate.As a result of this rapid growth,we will be forced to make changes in not only the way we live in the environment but also in the environment itself such as designing the cities of the future to be in greater harmony with the increasing population and growing complexity.The paper contains both reflections on global awareness and comprehensive criteria and their priorities for choosing the most desirable city.     

Faraday反常色散滤光器

介绍了滤光器的作用以及当前各种应用系统对滤光器的性能要求, 原子滤光器与其他传统滤光器的区别, 国内外原子滤光器的研究进展. 特别地, 给出了Faraday反常色散滤光器的重要指标——透过率的普遍计算方法, 此计算方法对被动式和主动式Faraday反常色散滤光器都适用, 并与实验结果符合得很好. 最后对本小组近年来在实验和理论方面的研究成果进行了总结性介绍. 其中, Rb-FADOF的实验结果与理论计算吻合得很好, 而Cs-ESFAD-OF的新方案在理论上得到了比较好的结果.     

Net-shape forming of composite packages with high thermal conductivity

The continuing miniaturization of electronic devices in microelectronics and semiconductors drives the development of new packaging materials with enhanced thermal conductivity to dissipate the heat generated in electronic packages.In recent years,several promising composite materials with high thermal conductivity have been developed successfully for high performance electronic equipment to replace the traditional Kovar and Cu/W or Cu/Mo alloys,such as SiCp/Al,SICp/Cu,diamond/Al and diamond/Cu.However,thes...     

A massive cloud of cold atomic hydrogen in the outer Galaxy.

A large fraction of the mass of the interstellar medium in our Galaxy is in the form of warm (103-104 K) and cool (50-100 K) atomic hydrogen (H i) gas. Cold (10-30 K) regions are thought to be dominated by dense clouds of molecular hydrogen. Cold H i is difficult to observe, and therefore our knowledge of its abundance and distribution in the interstellar medium is poor. The few known clouds of cold H i are much smaller in size and mass than typical molecular clouds. Here we report the discovery that the H i supershell GSH139-03-69 is very cold (10 K). It is about 2 kiloparsecs in size and as massive as the largest molecular complexes. The existence of such an immense structure composed of cold atomic hydrogen in the interstellar medium runs counter to the prevailing view that cold gas resides almost exclusively in clouds dominated by molecular hydrogen.     

Rapid Manufacturing of Sand Molds by Direct Milling

Direct milling of sand molds is an important development in rapid manufacturing of sand molds. Direct milling is an effective method for manufacturing single or small batches of cast parts. This paper describes experimental investigations to find sand blocks with the appropriate strength, to describe wear patterns of different tools (high-speed steel (HSS), carbide, and polycrystalline diamond (PCD) tools), and to analyze sand mold cutting mechanisms. The results show that the PCD tool outperformes the other tools in terms of tool life. Average flank wear and micro-tipping are the dominant tool failure modes in the sand mold milling process. With a flank wear limit of 0.3 mm, the PCD tool works continuously for about 70 h under the experimental conditions. The experimental results show that the cutting mechanism for direct milling sand molds differs from metal cutting.     

5-取代1,10-菲咯琳化合物的合成和表征(英文)

合成了二种新的5-取代1,10-菲咯啉化合物phen-NHCO（CH2）nBr（n=9,11）,它们是高效的分析化学试剂、钌（Ⅱ）类电化学发光（ECL）传感器活性材料的配体。利用元素分析、红外光谱、核磁共振氢谱和激光解析电离飞行时间质谱确证了其组成和结构。