Research on catalysis of sodium-metallochlorophylls in Ni/MH battery

The effects of sodium-metallochlorophylls including sodium-iron chlorophyllin, sodium-copper chlorophyllin and sodium-magnesium chlorophyllin on performance of Ni/MH battery were investigated. The results show that sodium-iron chlorophyllin can effectively activate the gases produced during charge in Ni/MH battery, therefore reducing the reduction potential of oxygen and the oxidation potential of hydrogen, and the increased speed of inner pressure of battery is decreased significantly. With the aid of DMol3 software, the activation process of oxygen and hydrogen by sodiummetallochlorophylls was simulated and analyzed. It was found that the catalysis behavior is in agreement with the experimental results, and the activation process also gets a reasonable explanation from the calculated results.     

无侧移失稳模式下框架的稳定方程及框架柱的计算长度系数

对无侧移框架结构进行了弹性稳定分析，得到了理想状态下无侧移框架结构的稳定方程，并对r=0.6-1.0的理想情况下框架柱的计算长度系数计算的结果表明：在r=1.0时计算值与规范值符合非常好，虽然方程的成立依赖于较为理想的假定条件，不适于对实际结构进行计算，但仍可做为实际稳定分析的参考。     

龙须草稀酸预水解过程中糖类组分的溶出规律

研究了龙须草稀酸预水解过程中温度、时间、稀酸初始质量浓度与戊糖、己糖溶出率之间的关系.结果表明:高温有助于糖类组分的溶出;在不同温度下,戊糖和己糖的溶出率均随水解反应时间的延长而增大;戊糖、己糖的溶出率与预水解因子呈良好的函数关系;随着稀酸初始质量浓度的增大,戊糖和己糖的溶出率增加;拟合发现,戊糖、己糖的溶出率和稀酸初始质量浓度也存在着良好的函数关系.据此总结出了龙须草稀酸预水解过程中戊糖和己糖溶出规律的经验模型,经验证发现,该模型是准确的和有效的.     

Fe3O4表面逆水煤气反应的DFT研究

采用密度泛函理论（DFT）研究了Fe3O4（111）表面逆水煤气反应的机理（氧化还原机理和中间产物分解机理）。通过优化初始构型,得到了最稳定的吸附构型。对两种机理主要的基元反应活化能进行了比较,结果表明：氧化还原机理是主要的反应机理,中间产物分解机理较难发生。计算结果还表明八面体Fe原子在吸附和活化过程中起着重要作用。     

基于OBB层次结构碰撞检测的改进算法

方向包围盒（Oriented bounding box：OBB）的构造以及包围盒的相交测试的计算量都比较大，严重影响了在模拟、仿真的应用，尤其是有变形物体的场景。引入近似凸包的思想提出一种快速构造方向包围盒算法，很大程度上减少了构造方向包围盒（0BB）层次结构的顶点数，改进后的算法在降低构造层次结构时间的同时，对方向包围盒的紧密性代价几乎没有影响，在有些时候还提高了包围盒的紧密性。在包围盒相交测试方面，提留了一种基于筒单羽以爱的相交须刿方击，该算法在检测过程中省去了大量包围盒的相交测试计算，提高了相交测试的速度。最后将两种改进算法联合的碰撞检测框架与常用的基于均值和协方差矩阵的包围盒构造和基于分裂轴的算法进行比较，证明了算法具有高效性。     

PMMA添加量对PVDF-HFP聚合物电解质结构及性能的影响

采用溶剂挥发法,以丙酮和DMF做混合溶剂制备PVDF-HFP/PMMA聚合物电解质,通过X射线衍射、热失重分析、交流阻抗、恒流充放电循环及倍率充放电等测试手段,考察了PMMA的添加量对聚合物电解质性能的影响.研究发现当PMMA的添加量为50%时,聚合物电解质表现出最佳性能,室温离子电导率从0.26 m S/cm提升到1.35 m S/cm,以Li Co O2作正极材料,锂片作负极材料组装的聚合物锂离子电池初始容量从80.1 m Ah/g提升到143.6 m Ah/g,在0.2 C倍率条件下,50个循环后容量保持率还能达到80%,表现出优异的锂离子电池性能.     

Electrodeposited synthesis of self-supported Ni-P cathode for efficient electrocatalytic hydrogen generation

One of the key challenges for electrochemical water splitting is the development of low-cost and efficient hydrogen evolution cathode. In this work, a self-supported Ni-P cathode was synthesized by a facile electrodeposition method. The composition and morphology were characterized by X-ray diffraction, X-ray photoelectron spectroscopy, scanning electron microscopy and transmission electron microscopy. The Ni-P cathode performed low onset over-potential, good catalytic activity and long-term stability under neutral and alkaline conditions. The mechanism of Ni-P electrode for hydrogen production was discussed by electrochemical impedance spectroscopy. The excellent performance of Ni-P cathode was mainly attributed to the synergistic effect of phosphate anions and the self-supported feature.     

Microstructure and properties of in-situ synthesized Cu-1 wt%TiC alloy followed by ECAP and post-annealing

A dispersion-strengthened copper alloy with 1 wt% TiC for commercial electrical-contact wires was prepared by in-situ reaction casting, grain-ultrafining by equal-channel angular pressing (ECAP) and subsequent annealing with aim to obtain excellent comprehensive performance. The results showed that fine TiC particles were in-situ synthesized in the as-cast Cu matrix and aggregated in clusters, and thus mechanical properties of the as-cast alloy deemed insufficient. Continued ECAP at 473 K significantly refined the grains of the as-cast alloy and improved the distribution of TiC particles. Due to multiple strengthening mechanisms, the ECAP-processed alloys maintained good conductivity with obviously enhanced tensile strength and hardness values. After post-ECAP annealing, the elongation and conductivity of the fine-grained copper alloy increased with the adequate tensile strength. The novel combined process endows the alloy appropriate performance to serve current high-frequency electrification railway systems.     

双层异构网络下多用户干扰对齐算法

针对多个毫微微蜂窝网络与宏蜂窝网络共存的网络环境,基于干扰对齐技术,提出了一种双层预编码方案,首先定义宏蜂窝网络对毫微微蜂窝网络造成的干扰为跨层干扰,毫微微蜂窝网络之间的干扰为同层干扰,分别对毫微微蜂窝用户和宏蜂窝用户进行预编码,宏蜂窝用户的预编码使得跨层干扰最小,使之可比拟于背景噪声,毫微微蜂窝用户的预编码与毫微微蜂窝基站的后置编码进行迭代,以最小均方误差(MMSE)准则输出,仿真结果表明所提算法使得毫微微蜂窝网络的吞吐量相较于单层MMSE算法在信噪比为0~30 d B区间内平均提高了3 bps/Hz.     

难加工合金材料复杂曲面磁性磨料光整加工技术

磁性磨料光整加工技术是一种非常重要的光整加工技术,与低频振动和超声振动相结合,可实现高精度、高质量和高效率的光整加工。介绍了磁性磨料光整加工、振动辅助磁性磨料光整加工及超声辅助磁性磨料光整加工技术的原理和特点及相关的国内外研究现状。根据难加工合金材料复杂曲面的特点,提出实现复杂曲面磁性磨料光整加工,需要就以下问题开展进一步研究和探索:通过提高加工间隙的磁通量密度及磁能与其他能量复合来提高光整加工效率;建立复杂曲面磁性磨粒光整加工过程控制函数;探讨在磁极工具的空间几何约束作用下复杂曲面磁性磨料光整加工工艺的规划方法等。