羧酸在油水相中的分布

研究了甲酸和乙酸于水中和不同有机介质中的分配系数,重点研究了含21、24和27碳原子的三烷基叔胺对甲酸和乙酸的成盐萃取作用。同时,在不同稀释剂及其用量、温度以及甲酸和乙酸浓度的条件下,确定了小分子羧酸的分配系数及其变化规律,最后,根据有机羧酸叔胺盐的热分解行为获得了纯度达90％的甲酸和乙酸,从而为重有机工业的酸回收提供了工艺技术设计的依据。     

《福建植物志》补遗

本文介绍了顺昌县生物多样性科学考察队于1995—1996年间在顺昌调查采集中发现有的种类在《福建植物志》尚未收载。本文将其归入21科28属,并列出中名、学名、原始文献、异名、主要生境及分布,以供参考。     

A continuous 200-ka palaeoclimatic record from stalagmite in Tangshan Cave, Nanjing

An oxygen isotope temperature record from 381 to 166 kaB. P. (²³⁰Th/²³⁴U dating and tuned ages) has been obtained by combining data on the isotopic composition of calcites with that of fluid inclusions trapped in a stalagmite from a limestone cave in which a fossil cranium deposited. Several laminae in microsequence of the stalagmite represent climatic events or shifts. The Nanjing man fossil was older than 381 kaB. P.     

The Juancheng chondrite──A new meteorite falling recently in China

The Juancheng chondrite, a new meteorite falling recently in Juancheng County, Shandong Province, China, is classified as an H5 (S2) chondrite based on the compositions of olivine (Fa= 19.2, σ Fa=0.46) and low-Ca pyroxene (Fs=16.9, σ Fa=0.4). The plagioclase in the Juancheng chondrite is rich in CaO, indicating a relatively high metamorphic temperature the parent body underwent.     

Discovery of eclogite at northern margin of Qaidam Basin, NW China

Eclogite was first discovered at the northern margin of the Qaidam Basin in this study. It occurs as pods in the gneiss sequence of Middle to Upper Proterozoic age and is mainly composed of garnet, omphacite, phengite and rutile. The garnets contain 44%-62% of almandine, 15%-33% of grossular and 12%-30% of pyrope molecules, and the omphacites contain 40%-46% of jadeite. Applying garnet_clinopyroxene thermometry and jadeite geobarometry, the peak conditions of eclogite facies metamorphism occurred at about (722±123)℃ and at the pressure of up to c. 22 ×10 8 Pa.     

High-precision timing of the Quaternary standard samples with thermal ionization mass spectrometry (TIMS) U-series method

Two national stalagmite standard (GBW04412, GBW04413) and one international coral standard (RKM_4) have been determined by using thermal ionization mass spectrometry (TIMS) method. The values of ( 234 U/ 238 U) act , ( 230 Th/ 234 U) act and age are all consistent in error range with the standard values obtained by using α spectrometry.     

Leakage of mantle helium from the Liaodong Peninsula, China

The isotopic cumpositions of helium have been investigated in hot spring gases sampled from the Liaodong Peninsula. China. The³He/⁴He ratios range from 0.14 Ra (0.14 times the atmospheric³He/⁴He ratio of 1.40 × 10^-6 to 0.72 Ra.³He/⁴He versus⁴He/²⁰Ne ratios and He contents suggest that a small amount of mantle-derived helium reaches the earth’s surface. Helium iwtope ratios of the hot spring gases show a distribution pattern similar to the regional heat flow values, indicating that the positive thermal anomaly occurring in the rtrea is closely associated with the presence of mantle-derived helium. The observations described above provide some significant evidence that the molten magma originating from partial melting of the upper mantle may have intruded into the continental crust along the activity fault. The coupling of the presence of mantle He and heat flow anomalies to seismic activity in studied region seem to imply that there is an internal relationship between mantle degassing and seismic activity.     

Structural OH in mantle-derived clinopyroxene megacrysts from Nushan

Thirteen clinopyroxene megacrysts from Nushan Cenozoic basalts have been investigated by Fourier transform infrared spectrometer(FTIR). The results demonstrate that all samples contain trace amount of structural OH. Clinopyroxenes from Nushan show four groups of absorption bands, in which, 3 472–3 506 cm⁻¹ is the major characteristic one. It is suggested that the position of major band is probably related to AI content: the position of major characteristic band for high-AI samples is around 3 470 cm⁻¹, whereas that for low-AI samples around 3 620 cm⁻¹.